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排序方式: 共有158条查询结果,搜索用时 15 毫秒
31.
Yael Pascal‐Levy Evgeny Shifman Dr. Manish Pal‐Chowdhury Eitan M. Hajaj Oleg Shtempluck Alexey Razin Valeri Kochetkov Prof. Yuval E. Yaish 《Chemphyschem》2012,13(18):4202-4206
Humidity plays an important role in molecular electronics. It facilitates charge movement on top of dielectric layers and modifies the device transfer characteristics. Using two different methods to probe temporal charge redistribution on the surface of dielectrics, we were able to extract the surface humidity for the first time. The first method is based on the relaxation time constants of the current through carbon nanotube field‐effect transistors (CNTFETs), and the second is based on electric force microscopy (EFM) measurements. Moreover, we found that applying external gate biases modifies the surface humidity. A theoretical model based on dielectrophoretic attraction between the water molecules and the substrate is introduced to explain this observation, and the results support our hypothesis. Furthermore, it is found that upon the adsorption of two to three layers of water the surface conductivity saturates. 相似文献
32.
Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese 下载免费PDF全文
Dr. Uttam Kumar Das Dr. Subrata Chakraborty Dr. Yael Diskin‐Posner Prof. David Milstein 《Angewandte Chemie (International ed. in English)》2018,57(41):13444-13448
We have developed unprecedented methods for the direct transformation of primary alcohols to alkenes in the presence of hydrazine, and for the synthesis of mixed alkenes by the reaction of alcohols with hydrazones. The reactions are catalyzed by a manganese pincer complex and proceed in absence of added base or hydrogen acceptors, liberating dihydrogen, dinitrogen, and water as the only byproducts. The proposed mechanism, based on preparation of proposed intermediates and control experiments, suggests that the transformation occurs through metal–ligand cooperative N?H activation of a hydrazone intermediate. 相似文献
33.
Alexander?Weisman Yael?Gafni Mark?Vernik Ilya?KuselmanEmail author 《Accreditation and quality assurance》2003,8(6):263-266
Characterization of in-house reference materials (IHRMs) with traceable property values for the mometasone furoate assay is discussed. The traceability of the value carried by the IHRM has been established to the value carried by a higher metrological status United States Pharmacopoeia Reference Standard (USP RS). A comparative approach is used to overcome systematic errors in measurement results, specific to the measurement method and/or to the laboratory developing the IHRM. The traceability chain was realized by the simultaneous analysis of the IHRM and the USP RS test portions under the same conditions. 相似文献
34.
Carpenter JE Christoffels A Weinbach Y Hide WA 《Journal of computational chemistry》2002,23(7):755-757
The exponential increase in expressed sequence tag (EST) sequence data amplifies the computational cost of clustering sequences such that new algorithms are required to analyze data at a greater rate. We have parallelized d2_cluster on a SGI Origin 2000 multiprocessor and observed a speedup of approximately 100x on 126 processors when processing a 15,876 EST dataset. The parallelized d2_cluster code is obtainable from the SANBI website (http://www.sanbi.ac.za/CODES). 相似文献
35.
McIntire TM Scott Lea A Gaspar DJ Jaitly N Dubowski Y Li Q Finlayson-Pitts BJ 《Physical chemistry chemical physics : PCCP》2005,7(20):3605-3609
Self-assembled monolayers (SAMs) of vinyl-terminated 3- and 8-carbon compounds were generated on Si substrates and reacted at room temperature with approximately 1 ppm gaseous O(3). A combination of atomic force microscopy (AFM), scanning electron microscopy (SEM), Auger electron spectroscopy (AES) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the surface composition and morphology after oxidation. A distribution of large ( approximately 0.1-10 microm) organic aggregates was formed, while the surrounding substrate became depleted of carbon compared to the unreacted SAM. This highly unusual result establishes that the mechanism of ozonolysis of alkene SAMs must have a channel that is unique compared to that in the gas phase or in solution, and may involve polymerization induced by the Criegee intermediate (CI). Oxidation at 60% RH led to the formation of a number of smaller aggregates, suggesting water intercepted the CI in competition with aggregate formation. The uptake of water, measured using transmission FTIR, was not increased upon oxidation of these films. In conjunction with literature reports of polymer formation from VOC-NO(x) photooxidations, these results suggest that formation of aggregates and polymers in the atmosphere is much more widespread than previously thought. The implications for the ozonolysis of alkenes on surfaces, for the transformation of organics in the atmosphere, and for the reactions and stability of unsaturated SAMs, are discussed. 相似文献
36.
37.
Dr. You-Quan Zou Dr. Niklas von Wolff Dr. Michael Rauch Dr. Moran Feller Dr. Quan-Quan Zhou Dr. Aviel Anaby Dr. Yael Diskin-Posner Dr. Linda J. W. Shimon Dr. Liat Avram Yehoshoa Ben-David Prof. Dr. David Milstein 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(14):4715-4722
Glycolic acid is a useful and important α-hydroxy acid that has broad applications. Herein, the homogeneous ruthenium catalyzed reforming of aqueous ethylene glycol to generate glycolic acid as well as pure hydrogen gas, without concomitant CO2 emission, is reported. This approach provides a clean and sustainable direction to glycolic acid and hydrogen, based on inexpensive, readily available, and renewable ethylene glycol using 0.5 mol % of catalyst. In-depth mechanistic experimental and computational studies highlight key aspects of the PNNH-ligand framework involved in this transformation. 相似文献
38.
Lev M. Bregman Yair Censor Simeon Reich Yael Zepkowitz-Malachi 《Journal of Approximation Theory》2003,124(2):194-218
We present a modification of Dykstra's algorithm which allows us to avoid projections onto general convex sets. Instead, we calculate projections onto either a half-space or onto the intersection of two half-spaces. Convergence of the algorithm is established and special choices of the half-spaces are proposed.The option to project onto half-spaces instead of general convex sets makes the algorithm more practical. The fact that the half-spaces are quite general enables us to apply the algorithm in a variety of cases and to generalize a number of known projection algorithms.The problem of projecting a point onto the intersection of closed convex sets receives considerable attention in many areas of mathematics and physics as well as in other fields of science and engineering such as image reconstruction from projections.In this work we propose a new class of algorithms which allow projection onto certain super half-spaces, i.e., half-spaces which contain the convex sets. Each one of the algorithms that we present gives the user freedom to choose the specific super half-space from a family of such half-spaces. Since projecting a point onto a half-space is an easy task to perform, the new algorithms may be more useful in practical situations in which the construction of the super half-spaces themselves is not too difficult. 相似文献
39.
Stadler C de Lacey AL Montet Y Volbeda A Fontecilla-Camps JC Conesa JC Fernández VM 《Inorganic chemistry》2002,41(17):4424-4434
ZORA relativistic DFT calculations are presented which aim to model the geometric and electronic structure of the active site of NiFe hydrogenases in its EPR-active oxidized states Ni-A (unready state) and Ni-B (ready state). Starting coordinates are taken from the X-ray structure of a mutant of Desulfovibrio fructosovorans hydrogenase refined at 1.81 A resolution. Nine possible candidates for Ni-A and Ni-B are analyzed in terms of their geometric and electronic structure. Comparison of calculated geometric and magnetic resonance parameters with available experimental data indicates that both oxidized states have a micro-hydroxo bridge between the two metal centers. The different electronic structures of both forms can be explained by a modification of a terminal cysteine in Ni-B, best modeled by protonation of the sulfur atom. A possible mechanism for the activation of both oxidized forms is presented. 相似文献
40.
Mahlako Malesele Nkogatse Motsehoa Cynthia Ramotsehoa Frederick Christofel Eloff Caradee Yael Wright 《Photochemistry and photobiology》2019,95(1):439-445
The exposure of outdoor car guards to solar ultraviolet radiation (UVR), the majority with deeply pigmented skin, to solar UVR was measured for five consecutive days during early spring (September 2017) in South Africa using electronic UVR dosimeters attached to the upper arm of each participant. The exposure of the nape of the neck, forehead, nose, cheek and hand was extrapolated from the measurements. The onsite ambient solar UVR on a flat, horizontal, unshaded surface was measured concurrently. The sun‐related knowledge, behavior and attitudes of the car guards were evaluated using questionnaires. Total personal daily solar UVR exposure as a percentage of the ambient solar UVR exposure was 24%. The exposure of car guards on several body sites was in excess of the occupational threshold limit value. Sleeved shirts and hats were the most commonly used sun protection measures (worn by 70% and 80%, respectively). Considering the high levels of solar UVR reported on most days throughout the year in South Africa, more studies quantifying the personal exposure of outdoor workers in both the informal and formal sectors are necessary. 相似文献