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91.
The density of the vibrational states of an SiO2 melt under various PT conditions, the distributions of the Si-O-Si and O-Si-O angles in it, and its IR absorption spectra have been calculated by molecular dynamics with the use of a pairwise additive Born-Mayer potential. A comparison with the experimental data reveals that the ionic approximation selected is capable of basically reproducing the structural and spectroscopic properties of the melt, but the distributions of the bond angles are considerably broader than the experimentally determined distributions, and the absorption band caused by the stretching vibrations is not displayed in the calculated spectrum. The disparities indicated are apparently due to the isotropic nature of the potential of the interparticle interactions.V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 27, No. 4, pp. 467–470, July–August, 1991. Original article submitted October 12, 1990. 相似文献
92.
93.
94.
M. F. Bundule A. F. Mishnev V. K. Lusis D. Kh. Mutsenietse A. Z. Zandersons G. Ya. Dubur 《Chemistry of Heterocyclic Compounds》1991,27(9):995-998
The molecular crystal structure of 4-phenyl-3,5-diethoxycarbonyl-1,2,6-trimethyl-1,2-dihydropyridine has been investigated by x-ray structural analysis. The three-dimensional structural properties of the molecule have been compared against the large observed reactivity of the 3-ethoxycarbonyl group with respect to nucleophilic substitution reactions.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1236–1239, September, 1991. 相似文献
95.
96.
We compute an intrinsic rank invariant for quasitriangular Hopf algebras in the case of general quantum groupsU
q
(g). As a function ofq the rank has remarkable number theoretic properties connected with modular covariance and Galois theory. A number of examples
are treated in detail, including rank (U
q
(su(3))) and rank (U
q
(e
8)). We briefly indicate a physical interpretation as relating Chern-Simons theory with the theory of a quantum particle confined
to an alcove ofg. 相似文献
97.
Pakhurova T. F. Paulin'sh Ya. Ya. Gudrinietse É. Yu. Dashkevich S. V. Ablovatskaya M. V. 《Chemistry of Heterocyclic Compounds》1982,18(11):1217-1217
Chemistry of Heterocyclic Compounds - 相似文献
98.
The temporal characteristics of stimulated Raman scattering (SRS) under 22-ps laser excitation were studied in eight oxide crystals with a T 2 optical-phonon dephasing time variable by up to two orders of magnitude. The measured SRS pulse width was shortened from 13.8 ps for Ba(NO3)2 (T 2 = 26.5 ps) to 4 ps for the LiNbO3 (T 2 = 0.38 ps) crystal. The dependence of SRS pulse width on the dephasing time was analyzed in the framework of the known SRS theory. 相似文献
99.
Alexander Ya. Kruger 《Set-Valued Analysis》2006,14(2):187-206
The paper continues investigations of stationarity and regularity properties of collections of sets in normed spaces. It contains
a summary of different characterizations (both primal and dual) of regularity and a list of sufficient conditions for a collection
of sets to be regular. 相似文献
100.
We analyze the statistical behavior of signals in nonlinear circuits with delayed feedback in the presence of external Markovian noise. For the special class of circuits with intense phase mixing we develop an approach for the computation of the probability distributions and multitime correlation functions based on the random phase approximation. Both Gaussian and Kubo-Andersen models of external noise statistics are analyzed and the existence of the stationary (asymptotic) random process in the long-time limit is shown. We demonstrate that a nonlinear system with chaotic behavior becomes a noise amplifier with specific statistical transformation properties. 相似文献