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971.
Changlun Shao Zhiyong Guo Hong Peng Guangtian Peng Zhongjing Huang Zhigang She Yongcheng Lin Shining Zhou 《Chemistry of Natural Compounds》2007,43(4):377-380
A new isoprenyl phenyl ether, 3-hydroxy-4-(3-methylbut-2-enyloxy)benzoic acid methyl ester (1), together with 4-hydroxybenzoic acid (2), 2-hydroxy-6-methylbenzoic acid (3), and 4-hydroxy-3-methoxybenzoic acid (4) were isolated from Mangrove fungus (No. B60) from the South China Sea. The structures of the compounds were established
on the basis of NMR spectroscopic and mass spectrometric data. In the preliminary bioassay, compound 1 exhibited antibacterial and antifungal activities. Compound 1 also inhibited cytotoxicity to the hepG2 cell line with an IC50 value of 10.0 μg/mL.
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 313–314, July–August, 2007. 相似文献
972.
评述了液晶态分子在分析化学中的应用进展,包括其超分子的分子识别作用,液晶在色谱,光谱探针,核磁共振谱等分析化学领域中的应用。 相似文献
973.
在硼氢化钾碱性溶液中对金属氢化物(MH)电极的表面进行化学还原处理,提高了MH电极的放电容量、活化性能和电催化活性.用其为负极组装的AA型MH-Ni电池进行了封口化成,电池放电容量达到1150mAh,5C下电池的放电容量达到0.2C下容量的80%以上,电池在1C100%DOD(放电深度)充放电条件下,循环寿命由原来的100次左右提高到200次以上 相似文献
974.
利用IR,EXAFS, ~(13)CO同位素交换反应及与NO作用等手段研究了Pt羰基簇合物[Pt_3(CO)_6]~(2-)_n(n=3,4)在NaY分子筛超笼内的合成机理.在氧化样品Pt~(2+)/NaY上300-373 K的还愿羰基化过程中,首先Pt~(2+)与CO反应生成PtO(CO)物种(波数σ_(CO)=2110 cm~(-1)),然后聚集成“Pt_3(CO)_6”(σ_(CO)=2112,1896和1841 cm~(-1)),最后生成深绿色的Pt羰基簇合物Pt_(12)(CO)_(24)]~(2-)/NaY(σ_(CO)=2080,1824 cm~(-1)).“Pt_3(CO)_6”的羰基在室温下能迅速地与~(13)CO发生交换,而[Pt_3(CO)_6]~(2-)_n(n=3,4)的羰基与~(13)CO的同位素交换即使在343 K也进行得很慢,室温下,NO能逐步破坏Pt羰基簇合物的层间和层内Pt-Pt键,得到中间物种“Pt_3(CO)_6”和PtO(CO),同时在气相产生CO_2和N_2O.而由上述两中间物种出发,300-353 K温度下,在CO气氛中的还原羰基化又能可逆地得到原羰基簇合物. 相似文献
975.
Sinenxan A, a taxoid isolated from callus tissue cultures of Taxus yunnanensis was converted into 13-oxo-7,9-dideoxy-2-debenzoyl-2-acetyl-baccatin IV and 7,9-dideoxy-2-debenzoyl-4-deacetyl-baccatin IV, a key framework of 1,7,9-trideoxypaclitaxel. Several special steps in this transformation are worthy of note: (1) deoxygenation by treatment with hypophosphorous acid at C-14 position; (2) a highly regioselective O-deacetylation of taxanes at C-5 position; and (3) stereoselective reduction of the 13-carbonyl group by transannular assistance from the C-4-hydroxyl. 相似文献
976.
Marta Gonzlez‐lvarez Gloria Alzuet Jos Luis García‐Gimnez Benigno Macías Joaquín Borrs 《无机化学与普通化学杂志》2005,631(11):2181-2187
Three flavonoid copper(II) complexes Cu2(quercetin)(CH3COO)3(CH3OH) ( 1 ), Cu(anthrarufin)(CH3COO)·1/2H2O ( 2 ) and Cu(naringin)(OCH3)(CH3OH)2 ( 3 ) have been synthesized and characterized by elemental analysis, IR, electronic absorption and EPR (X‐band) spectroscopy. The complexes have a strong protective action over the Δsod1 mutant of S. cerevisiae against reactive oxygen radicals generated by an external source of free radicals (H2O2 or the superoxide‐generating, menadione). On the other hand, the complexes cleave DNA efficiently even in the absence of reducing agents. The main reactive oxygen species responsible for the DNA strand cleavage have been determined using radical scavengers. A probably mechanism of the DNA damage is proposed. 相似文献
977.
V. I. Lozinsky I. A. Simenel M. G. Semenova L. E. Belyakova M. M. Il’in V. Ya. Grinberg A. S. Dubovik A. R. Khokhlov 《Polymer Science Series A》2006,48(4):435-443
The free-radical copolymerization of N-vinylcaprolactam and N-vinylimidazole (at an initial comonomer ratio of 85: 15, mol/mol) initiated by a persulfate-tertiary amine redox system in 10% aqueous DMSO at 25 and 65°C (at temperatures below and above the temperature of phase separation in the reaction system, respectively) yielded macromolecular products that were subsequently separated into thermally precipitating and nonprecipitating fractions. Investigations of these fractions by capillary viscometry, static and dynamic laser light scattering, and high-sensitivity DSC showed that macromolecules of both types of copolymers are strongly associated in aqueous solutions. Upon heating of solutions of thermally nonprecipitating fractions, additional aggregation takes place and this phenomenon is accompanied by a decrease in the size of particles without loss in their solubility until at least 70°C is reached. As for the set of properties exhibited in aqueous solutions, the thermally nonprecipitating fraction of the copolymer synthesized at 65°C may be assigned to protein-like macromolecules. 相似文献
978.
Qiang Li Pingfan Wu Yongge Wei Hongyou Guo 《Journal of organometallic chemistry》2006,691(6):1223-1228
An organic-inorganic hybrid compound, (Bu4N)2[Mo6O18(NAr)] (Ar = p-BrC6H4) has been synthesized via the DCC dehydrating protocol of the reaction of [α-Mo8O26]4− with 4-bromoaniline hydrochloride in anhydrous acetonitrile, which has been characterized by UV-Vis spectra, 1H NMR and single crystal X-ray diffraction study. By comparing the UV-Vis spectra, which were used to monitor the reaction, the optimum preparative condition for this compound was also determined. This compound crystallizes in the monoclinic space group P21/n, which is featured in a terminal para-bromophenylimido group linked to an Mo atom of a hexamolybdate cluster by a Mo-N triply bond. In addition, there are π-π dimerization of the neighboring cluster anions though the parallel aromatic rings in their crystals. 相似文献
979.
A series of 2-benzyl-1,3-dicabonyl derivatives was synthesized.Their insulin-sensitizing activity was evaluated in 3T3-L1 preadipocyte cells.Compounds3,26 and 27 were found to possess strong insulin-sensitizing activity in vitro and were selected for further hypoglycemic evaluation in vivo. 相似文献
980.
With frontal analysis(FA),the dependence of adsorption isotherms of insulin on the composition of mobile phase in reversed phase liquid chromatography (RPLC) has been investigated,This is also a good example to employ the stoichiometric displacement theory (SDT) for ivestigating solute adsorption in physical chemistry.Six kinds of mobile phase in RPLC were employed to study the effects on the elution curves and adsorption isotherms of insulin.the key points of this paper are:(1) the stability of insulin due to delay time after preparing,the organic solvent concentration,the kind and the concentration of ion-pairing agent in mobile phase were found to affect both elution curve and adsorption isotherm very seriously.(2)To obtain a valid and comparable result,the composition of the mobile phase employed in FA must be as same as possible to that in usual RPLC of either analytical scale or preparative purpose.(3)Langmuir Equation and the SDT were employed to imitate these obtained adsorption isotherms.The expression for solute adsorption from solution of the SDT was found to have a better elucidation to the insulin adsorption from mobile phase in RPLC. 相似文献