Thermal Emulsion Polymerization without any Conventional Initiators and Emulsifiers

Stable poly(styrene-co-sodium styrene sulfonate) (P(St-NaSS) nanoparticles with broader size distribution were synthesized by thermal emulsion polymerization without any conventional initiators and emulsifiers. The obtained polymer nanoparticles have higher ξ potential, and the particle sizes have broad distribution. The stability of polymer particles originated from the addition of small amounts of ionic comonomer, NaSS, which can act as an emulsifier in somewhat. The monomer conversion could reach up to about 28 wt% in 48 h, and did not increase by further polymerization when higher polymerization temperature (120 ℃) was employed. This polymerization system may be give some further understand for mechanism of emulsion polymerization.     

生物相容性BAB型两亲嵌段共聚物的合成及其自组装

Lys(z)-NCA was synthesized in the presence of triphosgene, amphiphilic triblock copolymers poly(N^c-CBZ-Lysine)-PEG-poly(N^c-CBZ-Lysine) were synthesized in DMF using amino-end ended PEG as initiator with the mechanism of anion ring opening polymerization. The structures of block copolymers were characterized by IR, ^1H-NMR,GPC and DSC. The results showed triblock copolymers with expected structure and low polydispersity in molecular weight could be synthesized by this method. At the same time, the self-assembling behaviors of block copolymer were investigated by TEM. A novel helical aggregates were found to be formed in DMF. Because of biocompatibility of two components of block copolymers, these block copolymers have potential applications in the field of biomaterials.     

含热致液晶性共聚酯的聚砜共混物

将一种含萘环的热致液晶性共聚酯与聚砜树脂熔融共混并挤塑成条。毛细管流变性测试表明，这一共聚酯降低了共混物的表观粘度，甚至低于其本身的粘度。共混物受剪切作用形成了各向异性的微纤增强结构，并具有皮芯结构，在液晶聚俣物含量低到２％与０．５％的样条中仍有共聚酯微纤形成。共聚酯微纤提高了聚砜的力学性能，含２０％共聚酯共混物挤塑条的位伸模量为聚砜树脂的二倍半。     

含胆汁酸和胆固醇的双亲性聚合物的研究进展

胆固醇和胆汁酸是广泛存在于自然界中的天然物质 ,生物相容性好 ,被广泛地用于高分子的疏水性改性 ,得到的双亲性聚合物 ,在水相中可以自组装或自聚集成纳米粒子。本文综述了含胆固醇或胆汁酸的双亲性聚合物的最新研究进展以及它们在药物载体系统中的应用。     

离子液体两相不对称氢甲酰化催化反应的研究

从(R)-BINAP出发制备水溶性磺酸钠盐配体(R)-BINAPS,采用离子液体BF4和PF6为介质,实现其Rh配合物对乙酸乙烯酯的两相不对称氢甲酰化反应.实验结果表明,在以BF4为介质的乙酸乙烯酯不对称氢甲酰化反应中,该催化剂在温和条件下显示出高于相应均相体系的产物ee值和异构醛选择性,并在6次循环使用中,反应产物的ee值、选择性和转化率均无明显改变;在离子液体体系中添加适当的甲苯时,油溶性配体(R)-BINAP与Rh组成的配合物催化剂亦可形成类似的两相反应体系,但其活性和选择性在重复使用中呈明显下降趋势.本文还考察了溶剂体系、膦铑比、温度、压力、时间等的影响,并尝试苯乙烯的两相不对称氢甲酰化反应.     

间接原子吸收法测定乳酸环丙沙星

研究了在弱酸性介质中，乳酸环丙沙星与雷氏盐定量生成缔合物的反应条件，以及通过原子吸收法测定沉淀中Cr的含量而间接测定乳酸环丙沙星含量的分析方法。线性范围在5－40mg/L，相对标准偏差为2．5％，回收率在98％－101％之间。     

Novel Gel—like Process for Synthesizing Submicron LiaNi0.8Co0.2O2 Powders Used in Lithium Ion Batteries

A novel gel-like process has been developed for synthesizing LiaNi0.8Co0.2O2 powders,using citric acid as a chelating agent. This process improves the homogeneity of constituent cation and enhances their reactivity in the obtained precursor. The results of electrochemical test demonstrated that these materials exhibited excellent electrochemical properties. Its initial capacity reached 181.6 mAh/g and reversible efficiency at the first cycle is about 88.6%.     

过渡金属配合物催化剂及其分子设计构思的发展与相互作用

讨论了某些不对称合成和α－烯烃定向配位聚合及α－烯烃氢甲酰化的过渡金属配合物向络合催化剂的发展与催化剂分子设计构思的发展及相互促进作用，并藉以说明过渡金属配合物定向络合物催化剂的分子设计已具备向计算机辅助设计发展的科学基础。     

1—二茂铁甲酰基—4—芳基氨基硫脲的合成及光谱性质研究

通过二茂铁基甲酸肼与芳基异硫氰酸酯的加成反应合成了一系列1-二茂铁甲酰基-4-芳基氨基硫脲,产物结构经元素分析和红外光谱及核磁共振氢谱予以确认.     

高含水聚乙烯醇弹性体

本文介绍了用反复冻结～融溶过程制备高含水聚乙烯醇弹性体的方法,并测定了该弹性体的机械、溶解和溶胀性能。结果表明,该弹性体可同时具有很高的含水率(85—90％)和较高的抗张强度(10~5—10~6Pa),且在37℃的水中有良好的稳定性能。