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利用通用有限元程序ANSYS对中国氦冷固态氚增殖剂实验包层模块(CH HCSB TBM)第一壁进行了稳态热分析。结果表明,第一壁铍保护板和RAFM钢的最高温度符合热工安全设计要求。对第一壁表面热流密度随时间变化的瞬态情况进行了分析,给出了随时间变化的结果。对第一壁两种典型的事故情形开展了初步分析,并对分析结果和事故影响进行了相应讨论。     

Three-Dimensional Waves in Tilt Thermal Boundary Layers

We numerically and theoretically study the stabilities of tilt thermal boundary layers immersed in stratified air. An interesting phenomenon is revealed： the stationary longitudinal-roll mode becomes unstable to some oscillating state even when the Grashof number is smaller than its corresponding critical value. By stability analysis, this phenomenon is explained in terms of a new three-dimensional wave mode. The effect of the tilt angle on the stability of the boundary flows is investigated. Since the new three-dimensional wave is found to be the most unstable mode when the title angle is between 30° and 64°, it is expected to play an important role in the transition to turbulence.     

Investigation on Guided-Mode Characteristics of Hollow-Core Photonic Crystal Fibre at Near-Infrared Wavelengths

Guided-mode characteristics of hollow-core photonic crystal fibre （HC-PCF） are experimentally and theoretically investigated. The transmission spectrum in the range from 755 to 845nm is observed and the loss is measured to be 0.12dB/m at 800nm by cut-back method. Based on the full-vector beam propagation method and the full-vector plane-wave method, the characteristics of mode field over propagation distance 1 m are simulated, and the results show that the propagation efficiency can be above 80%. Compared with the fundamental guided mode well confined in air core within shorter propagation distance, the second-order guided mode leaks into the cladding region and gradually attenuates due to larger refractive index difference. The primary loss factors in HC-PCF and the corresponding solutions are elementarily discussed.     

Derivative of Electron Density in Non-Equilibrium Green's Function Technique and Its Application to Boost Performance of Convergence

The non-equilibrium Green＇s function （NEGF） technique provides a solid foundation for the development of quantum mechanical simulators. However, the convergence is always of great concern. We present a general analytical formalism to acquire the accurate derivative of electron density with respect to electrical potential in the framework of NEGF. This formalism not only provides physical insight on non-local quantum phenomena in device simulation, but also can be used to set up a new scheme in solving the Poisson equation to boost the performance of convergence when the NEGF and Poisson equations are solved self-consistently. This method is illustrated by a simple one-dimensional example of an N＋＋ N＋ N＋＋ resistor. The total simulation time and iteration number are largely reduced.     

Re-entrant-Groove-Assisted VLS Growth of Boron Carbide Five-Fold Twinned Nanowires

We report a preferential growth of boron carbide nanowires with a five-fold twinned internal structure. The nanowires are found to grow catalytically via iron boron nanoparticles, but unusually the catalytic particle is in contact with the low-energy surfaces of boron carbide with V-shaped contact lines. We propose that this catalytical growth may be caused by preferential nucleation at the re-entrant grooves due to the twinning planes, followed by rapid spreading of atomic steps. This is consistent with the observed temperature dependence of the five-fold twinned nanowire growth.     

高分子支载的金鸡纳生物碱催化剂在不对称催化反应中的应用进展

综述了近年来高分子支载的金鸡纳生物碱催化剂在不对称双羟基化反应、不对称Michael加成反应、活性亚胺的不对称烷基化反应以及潜手性酮的不对称还原反应中的应用及最新进展。     

Bloch定理与散射平面波的干涉

从波动学的角度分析空晶格模型中的自由电子在周期性晶体势微扰作用下转变为晶体中Bloch电子的过程,揭示出了这一过程的物理实质,结果表明,在晶体势微扰作用下,代表空晶格模型中自由电子定态波函数的行进平面波在晶体内各点处产生了各种许可波矢的散射平面波,Bloch定理是晶体微观结构的平移对称性（即周期性）使得这些散射平面波产生干涉的结果。     

壬基酚聚氧乙烯醚的冲击压缩实验研究

 利用二级轻气炮对有机大分子乳化剂壬基酚聚氧乙烯醚（C₃₅H₆₄O₁₁）进行了系列动高压加载实验。在11~42 GPa冲击压力范围内测量了7个Hugoniot数据。结果表明,在17.8 GPa处,该物质的Hugoniot曲线出现拐折。这一现象意味着在高温高压条件下,壬基酚聚氧乙烯醚体系的分子基团发生了结构性相变。     

三价镧系离子掺杂的Cd3Al2 Ge3O12的长余辉发光

系统地研究了三价镧系离子在Cd3Al2Ge3O12基质中的长余辉发光。总结了余辉性能与激活离子电负性的关系。研究发现该体系中易失电子的激活离子产生的余辉效果较好。在254nm紫外光激发下,基质和所有镧系离子(Pm除外)掺杂的样品都有发光和余辉。按照发光和余辉性质的不同可以将激活离子分为三类：Pr^3 、Tb^3 和Dy^3 等是有特征余辉发光的离子;Eu^3 和Sm^3 等是有特征发射,但没有特征余辉发光的离子;Ce^4 、La^3 、Nd^3 以及其他是没有特征发光的镧系离子。长余辉的产生是由缺陷引起的。由于Cd^2 离子在高温下容易挥发,基质中存在大量的Cd^2 离子空位,这种空位可以作为俘获电子的陷阱。同时为了补偿Cd^2 所产生的正电荷,在Cd^2 离子空位周围会有相应的负离子空位产生,比如氧离子空位。这种补偿作用的存在使得基质本身的缺陷种类和数量十分丰富,使得该体系的余辉性能比较优越。     

不同形态MEH-PPV的构象及其光学特性

通过对在固溶体、稀溶液、薄膜和纳米孔中MEH—PPV的PL和PLE谱的测量分析,研究不同形态下MEH-PPV分子链的构象及其对电子能带和光学性质的影响。在THF稀溶液中,MEH—PPV分子链基本上皆为分立态;在MEH—PPV薄膜中,分子链基本上皆为聚集态;在MEH-PPV／PS固溶体中,MEH—PPV分子链为聚集态和分立态两构象并存,聚集态的比例随MEH-PPV浓度的增加而升高;在多孔氧化铝模板纳米孔中,MEH—PPV分子链形成链束。分立态、聚集态和链束这三种不同构象的分子链具有不同的电子能带结构和光学性质。