[VS_4Cu_6(Py)_8I_3]的合成和晶体结构

在(NH4)3VS4/CuI/Py反应体系中合成了新化合物 [VS4Cu6(Py)8I3]并测定其晶体结构。该化合物(C40H40N8Cu6I3S4V)属正交晶系, 空间群为Fdd2, 晶胞参数为: a = 29.924(6), b = 13.475(3), c = 25.853(5) , V = 10425(4) ?, Dc = 2.006 g/cm3, Mr = 1573.92, Z = 8, (MoK) = 4.546 mm-1, F(000) = 6048。结构由直接法解出, 用全矩阵最小二乘法修正, 最终偏离因子R = 0.023, wR = 0.069。簇合物分子是由6个带端基配体的Cu沿着四面体单元VS4的6条SS边配位而成, 6个Cu排列成了1个八面体, V基本位于八面体的中心, 整个分子具有C2对称性。     

逆序数的应用

本文通过“1 4-1 5”智力玩具和最优戴断切割问题两个实例 ,讨论了逆序数在解决实际问题中的应用     

用紧耦合方法研究C4+和O6+与He原子碰撞

用双中心原子轨道紧耦合方法计算了C4+-He以及O6+-He碰撞的单俘获总截面,入射离子的能量范围为10～100keV/amu,所得计算结果在实验误差范围内与实验值很好符合.对满壳层入射离子,研究了单俘获截面随入射离子电荷态的变化,并讨论了原子轨道展开波函数数目对计算结果的影响.p     

Population transfer in multilevel system through modified stimulated Raman adiabatic passage

Stimulated Raman adiabatic passage (STIRAP) has been successfully extended to multilevel system. During the STIRAP process, the intermediate levels have notable population which is detrimental if these levels could decay to other levels through spontaneous emission. This paper proposes a novel method to reduce the intermediate level population during the STIRAP process. A complete population transfer can be achieved in this modified STIRAP even if the intermediate level decays to other levels.     

Periodic and subharmonic solutions of a class of subquadratic second-order Hamiltonian systems

Some solvability conditions of periodic and subharmonic solutions are obtained for a class of subquadratic nonautonomous second-order Hamiltonian systems by the minimax methods in critical point theory.     

Lp[0,1]空间Müntz有理逼近的Jackson型估计

设Λ={λn}n∞=1为正的实数数列,且当n→∞时,有λn↘0.本文给出了当λn≤Mn-1/2,n=1,2,…,(其中M＞0为一正常数)时Müntz系统{xλn}的有理函数在Lp[0,1]空间的逼近速度,主要结论为Rn(f,Λ) Lp≤CMω(f,n-1/2)Lp,1≤p≤∞.     

J/ψ衰变到重子、反重子对中SU(3)对称性破坏的研究

利用粒子数据手册(PDG2004)公布的J/ψ衰变到重子、反重子对(BB)各个衰变道分支比的平均值, 对重子八重态的SU(3)对称性重新做了分析. 研究了J/ψ→BB中电磁相互作用和强相互作用的干涉. 得到了在J/ψ→BB中SU(3)单态、电磁 相互作用和SU(3)破坏各个因素所占的大小.     

Micromagnetic analysis of transition noise for high-density perpendicular recording

In this paper, specific issues related to high-density perpendicular magnetic recording processes, such as transition noise properties and cross-track correlation lengths, were investigated with the help of micromagnetic analysis. The effects of media parameters were taken into consideration, including intergranular exchange coupling, and exchange distribution, irregular grain shapes, magnetization saturation distribution, and anisotropy distribution. The micromagnetic simulation results showed that the effect of anisotropy distribution on transition noise is more significant than magnetization saturation distribution, and it is crucial to reduce this effect to achieve a high signal-to-noise ratio. Additionally, a new method to further estimate the partial erasure threshold was proposed to approximate the partial erasure effects, and the relation between the microtrack jitter and total track jitter was investigated.     

挖坑机钻头主轴纵向振动系统模型的建立与控制

首先利用弹性杆理论和H am ilton变分原理建立了挖坑机钻头主轴及钻尖在工作过程中由于外激励的作用使钻尖与土壤互相作用而产生纵向振动的动力学模型,同时给出边界条件和初始条件.其次通过把系统外激励函数当作控制变量,利用Banach空间几何性质证明了此系统存在唯一最优控制元.