Preparation and characterization of optically active polystyrene via a chiral nitroxide‐mediated polymerization

2,2,6,6‐Tetramethyl‐4‐[d‐(+)‐10‐camphorsulfonyl]‐1‐piperidinyloxy was synthesized and used as a chiral nitroxide for the bulk polymerizations of styrene initiated with benzoyl peroxide (BPO), tetraethylthiuram disulfide (TETD), and thermal initiation. The results showed that the polymerizations proceeded in a controlled/living way; that is, the kinetics presented approximately first‐order plots, and the number‐average molecular weights of the polymers with narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight) increased with the monomer conversion linearly. The molecular weight distributions in the case of thermal initiation were narrower than those in the case of BPO and TETD, whereas the polymerization rate with BPO or TETD as an initiator was obviously faster than that with thermal initiation. In addition, successful chain‐extension reactions were carried out, and the structures of the obtained polymers were characterized by gel permeation chromatography and ¹H NMR. The specific rotations of the polymers were also measured by polarimetric analysis. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1522–1528, 2006     

湍流燃烧二阶矩模型的大涡模拟验证

对美国Sandia国家实验室测量的甲烷-空气湍流射流火焰进行了三维大涡模拟(LES),其统计的时均量以及脉动量符合实验测量值,且和RANS代数二阶矩湍流燃烧模型模拟结果大致符合。LES统计得到的化学反应率系数脉动和甲烷浓度脉动的互关联与对应的时均量梯度的乘积分布趋势相同,大小幅值的位置也相对应,与二阶矩湍流燃烧模型的封闭假设相符,验证了二阶矩代数燃烧模型的合理性。     

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HT-7中性束诊断电源系统的计算机控制系统由PLC、工控机、逻辑控制和定时单元等组成。对起弧、束流引出等实验进行了研究。在多种参数下,通过调节弧压、进气量等观察了其对弧流的影响。初步实验结果表明,在高压35kV、弧流80A的情况下,束电流可以达到3.6A,引出的中性束流功率可以稳定地达到50kW以上。     

模糊神经网络在复合地基沉降量预测中的应用

复合地基后期沉降变形对于建筑物设计及安全具有重要意义,针对通过长期沉降观测以得到复合地基的最终沉降需要耗费较多资源的问题,提出了一种基于模糊神经网络的预测方法.该方法考虑沉降变化过程有较大的随机性和模糊性,直接将样本数据进行模糊化,所得的模糊数代表了样本点集与控制点集中各分量之间的相关度,并依此建立模糊BP神经网络进行学习和估算.实验结果表明了该方法对沉降进行预测是可行与有效的,且在相对误差的有效控制方面优于BP网络方法与灰色方法.     

The practice for eight-year operation of the cobalt-60 irradiation facility at Beijing Radiation Application Research Center

The radiation facility was made by Sulzer Company in Switzerland. The designed capacity is 3.7 × 10¹⁶Bq( 1MCi) and 12.21 × 10¹⁵Bq(330kCi)of Cobalt -60 source was loaded at the first phase. Current cobalt -60 source-loading is 2.4 × 10¹⁶Bq(650kCi). The equipment assembling and installation regulating and testing were completed at the end of 1988. The facility was put into commissioning in 1989. It operates 7000–8000 hours per year. The facility has been utilized to carry out many research work and irradiate many kinds of items. Lots of economical benefits have been gained since then. Now it is becoming a radiation processing model base in China. This paper summarized the strong and weak points of the design of the facility through in eight years' practice and analysed the economical benefits.     

全息散斑条纹的提取及图像处理

介绍了一种新的全息散斑条纹的提取方法.理论和实验表明:对全息散斑底片逐点再现时,两伴生亮斑条纹是全息散斑底片一级衍射光的杨氏干涉条纹,与中央的杨氏条纹是一致的,有较高的条纹对比度且没有背景光晕的影响.利用计算机数字图像处理技术对伴生散斑条纹进行处理,定量测试了受静载物体的面内位移.     

高效液相色谱法分离测定洛伐他汀及其开环酸

改进了洛伐他汀的分析方法，以甲醇：水＝80：20为流动相，采用紫外检测器检测，使用C4色谱柱定性、定量分析了洛伐他汀及洛伐他汀羟基酸，并得出了相关方程．实验证明，采用新的色谱条件可在有效地分析洛伐他汀及其开环酸的基础上，节约分析成本．     

Covalent attachment of phospholipid analogous polymers to modify a polymeric membrane surface: a novel approach

A novel method for the surface modification of a microporous polypropylene membrane by tethering phospholipid analogous polymers (PAPs) is given, which includes the photoinduced graft polymerization of N,N-dimethylaminoethyl methacrylate (DMAEMA) and the ring-opening reaction of grafted poly-(DMAEMA) with 2-alkyloxy-2-oxo-1,3,2-dioxaphospholanes. Five 2-alkyloxy-2-oxo-1,3,2-dioxaphospholanes, containing octyloxy, dodecyloxy, tetradecyloxy, hexadecyloxy, and octadecyloxy groups in the molecular structure, were used to fabricate the PAP-modified polypropylene membranes. The attenuated total reflectance FT-IR spectra of the original, poly(DMAEMA)-grafted, and PAP-modified membranes confirmed the chemical changes on the membrane surface. Scanning electron microscope pictures showed that, compared with the original membrane, the surface porosities ofpoly(DMAEMA)-grafted and PAP-modified membranes were somewhat reduced. Water contact angles measured by the sessile drop method on PAP-modified membranes were slightly lower than that on the original polypropylene membrane, but higher than those on poly(DMAEMA)-grafted membranes with the exception of octyloxy-containing PAP-modified membranes. However, BSA adsorption experiments indicated that the five PAP-modified membranes had a much better protein-resistant property than the original polypropylene membrane and the poly(DMAEMA)-grafted membranes. For hexadecyloxy- and octadecyloxy-containing PAP-modified membranes, almost no protein adsorption was observed when the grafting degree was above 6 wt %. It was also found that the platelet adhesion was remarkably suppressed on the PAP-modified membranes. All these results demonstrate that the described approach is an effective way to improve the surface biocompatibility for polymeric membranes.     

毛细管凝胶电泳的激光光热在线检测

近年来,毛细管电泳已成为一种高效快速的微化学分离分析新技术,在无机、有机及生物化学分析中得到了广泛的应用.但毛细管的内径小,进样量在pg～ng级,给样品的检测带来新的困难.因此,发展高灵敏度的显微在线检测器,已成为毛细管电泳技术发展中的重要环节.基于各种原理的检测器研究已有报道~[1].Dovichi等曾用热透镜技术在线检测了乙腈/     

(4S)-4-羧基杂氮硅三环的合成

利用L-N,N-双(β-羟乙基)丝氨酸及L-N,N-双(β-羟乙基)苏氨酸与三乙氧基硅烷或氯烷基三乙氧基硅烷反应合成了具有手性的(4S)-4-羧基杂氮硅三环(1～5),并运用IR、~1HNMR、EI-MS等手段表征了结构。证据显示存在着贯穿笼状结构的N→Si配键。