首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   73966篇
  免费   12393篇
  国内免费   7293篇
化学   50923篇
晶体学   657篇
力学   4738篇
综合类   310篇
数学   8196篇
物理学   28828篇
  2024年   279篇
  2023年   1601篇
  2022年   2716篇
  2021年   2919篇
  2020年   3106篇
  2019年   2907篇
  2018年   2562篇
  2017年   2335篇
  2016年   3569篇
  2015年   3472篇
  2014年   4134篇
  2013年   5304篇
  2012年   6729篇
  2011年   6724篇
  2010年   4467篇
  2009年   4251篇
  2008年   4591篇
  2007年   4107篇
  2006年   3754篇
  2005年   3129篇
  2004年   2425篇
  2003年   1919篇
  2002年   1751篇
  2001年   1470篇
  2000年   1356篇
  1999年   1533篇
  1998年   1304篇
  1997年   1291篇
  1996年   1289篇
  1995年   1050篇
  1994年   921篇
  1993年   763篇
  1992年   674篇
  1991年   580篇
  1990年   501篇
  1989年   384篇
  1988年   335篇
  1987年   274篇
  1986年   249篇
  1985年   204篇
  1984年   143篇
  1983年   102篇
  1982年   80篇
  1981年   67篇
  1980年   65篇
  1979年   33篇
  1978年   30篇
  1977年   40篇
  1976年   30篇
  1973年   28篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
杨宇  黄醒良 《发光学报》1995,16(4):285-292
采用固源Si分子束外延,在较高的生长温度于Si(100)衬底上制备出Si1-xGex/Si量子阱发光材料。发光样品的质量和特性通过卢瑟福背散射、X射线双晶衍射及光致发光评估。背散射实验中观察到应变超晶格的反常沟道效应;X射线分析表明材料的生长是共度的、无应力释放的,结晶完整性好。低温光致发光主要是外延合金量子阱中带边激子的无声发射和横光学声子参与的激子复合。并讨论了生长温度对量于阱发光的影响。  相似文献   
32.
In theory, both polarity and steric hindrance are basic factors which affect molecular interactions. To investigate the optical properties and steric structures of chiral compounds having different chiral moieties which affect the wavelength of light reflection in liquid crystal (LC) cells, a series of novel chiral compounds and azobenzene derivatives were synthesized. The liquid crystalline phases of the compounds were identified using small angle X-ray diffraction, differential scanning calorimetry and polarizing optical microscopy. Cholesteric LC cells with various synthesized chiral dopants which selectively reflect visible light were first prepared, the photochemical switching behaviour of colours was then investigated, with special reference to the change in transmittance in cholesteric LC cells containing an azobenzene derivative as a photoisomerizable guest molecule. Reversible isomerization of azobenzene molecules occurred in the cholesteric systems, resulting in a depression of TChI and a shift of the selectively reflected wavelength. We discuss the photochemically driven change in the helical pitch of the cholesteric LCs with respect to structural effects involving the chiral moieties. Molecular interactions caused by the added dopants, reliability and stability of the photoisomerization, and UV irradiation effects on the cholesteric LC cells were also investigated. A real image was recorded through a mask on a cholesteric LC cell fabricated in this investigation.  相似文献   
33.
X.B. Liu  J.G. Li 《Journal of Non》2004,333(1):95-100
The microstructure evolution of decagonal quasicrystals in Al72Ni12Co16 alloy was investigated by the electromagnetic melting and cyclic superheating method. Single-phase decagonal quasicrystals have been obtained when the undercoolings were larger than 60 K. The decagonal quasicrystals formed at various undercoolings show different microstructural morphologies. Furthermore, grain refinement was found near the undercooling of 120 K. Based on current thermodynamic and dendrite growth theories, a dimensionless superheating parameter was adopted to explain the effect of processing conditions on the microstructure of Al72Ni12Co16 alloy. The result indicate that the fine equiaxied microstructure of decagonal quasicrystal (D-phase) formed near on undercooling of 120 K originates from the break-up of dendrites.  相似文献   
34.
A simple graphG is said to be fractionaln-factor-critical if after deleting anyn vertices the remaining subgraph still has a fractional perfect matching. For fractionaln-factor-criticality, in this paper, one necessary and sufficient condition, and three sufficient conditions related to maximum matching, complete closure are given.  相似文献   
35.
The universal condition for the formation of omnidirectional band gaps (OBG) in photonic crystal (PC) was derived with consideration of permeability of the materials. And it was found that there are four kinds of PCs: one of them has no OBG, and one always possesses OBG. For the other two kinds of PCs, there are OBG for only TM or TE waves respectively. Moreover, in all PCs, the OBG can be broadened by decreasing the refractive index of the ambient medium or/and increasing the contrast between the wave impedances of the component materials of the PC. PACS 42.70.Qs; 71.20.Tx  相似文献   
36.
In situ flying height testing technology is becoming more and more important in slider–disk interaction analysis and manufacturing quality control of disk drives and head-related components. Triple harmonic method is a quite promising choice for in situ flying height analysis, compared with other in situ methods reported up to now. This paper reports results of investigations on engineering issues of applying triple harmonic method for in situ flying height analysis. The paper reports results of analysis on the effects of various testing conditions on flying height testing repeatability and accuracy. Results suggest that working at reasonable high channel density and working on the ratio between third and first harmonics will be an advantage in terms of both flying height testing sensitivity and testing repeatability. Comparing with media thickness effect, the gap-length variation among different heads will be important if it is to study flying height difference among different heads and the testing is at high channel density. Also, it is suggested to work at AC erased track, in order to reduce the non-linearity caused by hard transition.  相似文献   
37.
38.
Summary High-purity indium was analysed by spark source mass spectrometry, using electrical and photoplate detection. For the calibration of the differences in elemental sensitivity, a standard sample was prepared in which 10 impurities were determined by graphite furnace atomic absorption spectrometry. In this way accuracies of less than 40% were obtained for relatively homogeneous elements at ppm and sub-ppm level. About 40 elements could be determined with detection limits of 10 to 30 ppb. Two pattern recognition methods, principal component analysis and clustering analysis, were applied to obtain information on trace element distribution, which indicated that a number of elements were strongly spatially correlated in the analysed sample.
Chemische Analyse und Verteilungsbestimmung von Spurenelementen in Indium-Matrix durch Funkenquellen-Massenspektrometrie

On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China  相似文献   
39.
本文研究了不同处理条件(处理功率、处理时间和处理压力)下等离子体气体(Ar、N2、O2和空气等)对高密度聚乙烯表面处理产生的自由基的ESR谱。我们观察到等离子体处理产生的自由基是相当稳定的,它的ESR信号强度随处理功率和处理时间增加而增加。但处理压力对它影响不大。我们证明了紫外线对高密度聚乙烯表面产生自由基作用随处理条件而变化。并初步解释了谱的超精细相互作用。  相似文献   
40.
We demonstrate a three orders of magnitude increase and stability in the backscattered fluorescence signal from nitrogen molecules by terawatt femtosecond laser pulse induced air filaments using a new method. The method is based on squeezing the initial beam diameter using a telescope. The effect of laser shot-to-shot fluctuations was included in numerical simulations by a random distribution of the initial intensity in both squeezed and non-squeezed beams. Statistical processing of the simulation results shows that the average diameter of plasma channels as well as the total amount of free electrons generated in a bunch of multiple filaments in air is larger in the squeezed beam. Shot-to-shot stability of the simulated plasma density increases in the squeezed beam. The change of this plasma density with propagation distance is in good qualitative agreement with the change of the range-corrected nitrogen fluorescence signal with distance. PACS 42.65.Jx; 42.60.Jf; 42.68.Ay; 42.68.Wt  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号