双波长外腔共振和频中Boyd-Kleinman因子优化的理论研究

双波长外腔共振是提高和频转换效率的有效手段,然而基于Boyd-Kleinman(BK)理论,和频效率除了受基频光功率密度影响外,主要受BK因子限制。本文通过分析BK因子随腔结构参数的变化关系,给出基于外腔频率转换过程中BK因子优化的一般方案,从而为搭建相关实验提供必要的理论基础。     

计算机模拟光波的干涉

采用时域有限差分方法模拟了光的干涉这一物理现象.在物理实验的教学过程中光学实验以其高精度、高复杂度使得在实验教学过程中产生了一些负面影响.学生往往花费了较大精力去调节仪器,最终却得不到满意的实验数据,甚至得不到正确的实验结果.针对这一问题,可以采用数值模拟的方法得到很好的解决.文中不但模拟了实验现象,还验证了实验的理论公式,使得学生在观察现象的同时,对理论公式也能产生深刻的认识,最终起到了良好的课堂效果.     

3D coordinate measurement based on inverse photogrammetry and fringe analysis

A method based on inverse photogrammetry and fringe analysis is presented for 3D coordinate measurement. Measurement system mainly consists of a micro-camera fixed on one end of a measuring rod, a measuring probe on the other end and a liquid crystal display screen for displaying 2D fringe pattern in the measurement. In the measurement process, the probe contacts the surface of the measured object, and the CCD camera captures the stripes image on displays screen. The coordinates of camera principal point in the world coordinate system may be determined by the phase information carried in the fringe pattern. The coordinate relations between the principal point of the camera and the measuring probe can be determined with a least square optimization technique in camera coordinate system. This method has the advantage of large measurement range, good flexibility, and portable, which is suitable for field measurement. A result of our method is compared with that of the Coordinate Measuring Machine (CMM), which shows that the measurement accuracy of this method can meet accuracy requirement of the field measurement in large dimension.     

Quantitative measurement of large-aperture aspheric surfaces by off-axis Ronchi test

An off-axis Ronchi test based on the phase-shifting technique is presented to measure the aspheric mirror quantitatively. In this paper, slopes of deviations from the mirror's ideal aspheric shape are derived when an off-axis point source is used. By integrating these slopes, the deviations of the shape are obtained and then the tested shape can be reconstructed. Compared with the coaxial Ronchi test, the measurement error caused by combination fringes can be avoided, and this system is more flexible. In the experiment, a marked point is used to guide the phase unwrapping procedure, which improves the accuracy of extracting corresponding phase points. In addition, the method has strong anti-noise ability. The validity of the method has been verified by both computer simulations and a preliminary experiment.     

Flexible geometrical calibration for fringe-reflection 3D measurement

System geometrical calibration is a challenging task in fringe-reflection 3D measurement because the fringe displayed on the LCD screen does not lie within the camera's field of view. Commonly, a flat mirror with markers can accomplish system geometrical calibration. However, the position of the markers must be precisely located by photogrammetry in advance. In this Letter, we introduce a calibration method by use of a markerless flat mirror. Experiments in phase measuring deflectometry demonstrate that the proposed method is simple and flexible.     

基于自由镜面反射位姿评估的条纹反射摄影测量

在条纹反射摄影测量中,由于产生条纹图形的液晶显示器不直接出现在摄像机的视场范围内,摄像机与液晶显示器之间的位姿标定是条纹反射摄影测量的主要难点。为了简化标定过程,提出了采用平面镜直接对液晶显示器上的条纹反射3次并利用固定摄像机接收反射条纹,通过对摄像机与条纹虚像之间的3次位姿评估,完成摄像机与液晶显示器的位姿标定的方法。在镜面面形测量中,利用两者之间的位姿关系可以将待测点的反射光线和入射光线统一在摄像机坐标系下,完成光线的三角交会,实现镜面面形测量。数值模拟和实验结果表明,此方法简单易行,且精度较高。     

绝缘晶体热导率理论计算简单模型(英文)

本论文给出了一个计算绝缘晶体的热导率的简单计算公式,该公式的准确性已经在大多数的绝缘晶体材料热导率计算结果上得到证明,该计算公式与Slack和Berman提出的公式在本质上是一样的。然而,在Slack和Berman提出的公式中的一些参数,例如德拜温度等,很难直接得到。本文中我们不仅进一步简化了计算热导率的计算公式,公式中涉及的参数都可以利用一些简单的方法得到,同时又具有很高的准确性。本文的工作进一步证明了Peierls的导热理论。     

石英晶体产业概述

水热法人造石英晶体材料的产能自二十世纪五十年代开始不断增长,二十一世纪初达到顶峰。随着世界石英晶体元器件向高频、小型化、片式化、耐辐照方向发展,产品品种和产量发生很大变化。高Q值、低腐蚀隧道密度、包裹体少是压电石英材料未来发展的趋势;而包裹体和条纹(脉理)是光学石英晶体两大关键技术指标。     

Chemiluminescence excited photoelectrochemistry using graphene-quantum dots nanocomposite for biosensing

Chemiluminescence was used as the exciting light source to construct a universal photoelectrochemical platform based on a reduced graphene oxide-CdS nanocomposite, which greatly improves the photovoltaic transfer efficiency and leads to excellent performance for the photoelectrochemical immunoassay.     

Mechanisms of the cascade synthesis of substituted 4-amino-1,2,4-triazol-3-one from Huisgen zwitterion and aldehyde hydrazone: a DFT study

The detailed reaction mechanisms of the title reaction are shed light on by using the density functional theory (DFT). The calculated results have demonstrated that the whole reaction takes place via four processes (processes (I-IV)), among which, three possible reaction mechanisms are proposed for process (II) (channels 1-3) and two for process (IV) (channels 4-5). According to our calculated results, channel 3 and channel 5 are verified to be most energetically favorable. As interpreted in the text, in process (II), the proton transfer should be performed prior to the nucleophilic attack, and the AA-Type transfer strategy is more likely to occur. The global reactivity index (GRI) and frontier molecular orbital (FMO) analyses of the aldehyde hydrazone have further supported the AA-Type mechanism. In process (IV), however, the titled product has been demonstrated to be formed by the synergetic elimination of two protons via a six-membered ring transition state. Taking an integrated view, the highest energy barrier for the whole reaction along the most favorable pathway is 32.19 kcal/mol, which is consistent with the mild thermal experimental conditions. More interestingly, the qualified mechanisms in this work have given a perfect explanation to the optimal reactants molar ratio of highest yields (R1/R2/R3 = 2/1/1) employed in the experiment.