柔性衬底白色有机电致发光器件的制备及其性能

采用以ITO为导电层的柔性透明PET基片作为衬底,以2-(2-羟基苯基)苯并噻唑螯合锌(Zn(BTZ),)作为发光层制备出结构为PET／ITO／PVK：TPD／Zn(BTZ)2／Al明亮的近白色柔性有机小分子电致发光器件。发光的色坐标值为x=0．242,y=0．359,在25V的直流电压驱动下,亮度为1000cd／m^2,量子效率达到了0．30％。并进一步在Zn(BTZ)2中掺入橙红色染料Rubrene,制成PET／ITO／PVK：TPD／Zn(BTZ)2：Rubrene／Al结构器件。实现了纯白色发光(色坐标值：x=0．339,y=0．339),非常接近于白色等能点,驱动电压为25V时器件的亮度达1200cd／m^2,且量子效率达0．35％。最后对器件的发光性能及机理进行了深入的研究和探讨。     

基于安卓平台的糖尿病监护系统的研究及实现

基于目前针对糖尿病的研究主要集中在健康管理及血糖浓度监测方面,在糖尿病病情控制方面并不乐观的现状,设计开发了一套能够实时监护老年患者注射药物情况的远程家庭医疗系统。该系统由智能检测硬件系统,手机客户端和WEB信息管理端组成,不仅可以解决独孤老人时常忘记注射胰岛素的问题,也有利于解决我国老年患者糖尿病监护难的问题,同时也能提醒青壮年实时携带注射针剂盒,缓解糖尿病并发症的发生。通过实时实验测试,该糖尿病监护系统可靠、稳定,且具有良好的实际应用价值。     

Design and analysis of two-dimensional photonic crystals channel filter

A novel three-port channel add/drop filter consisting of two waveguides and two cavities is proposed. One is used for a resonant tunneling-based channel add/drop operation from the bus waveguide to the add/drop waveguide, while the other is used to realize the wavelength-selective reflection feedback in the bus waveguide. By means of coupled mode theory in time, the conditions to achieve 100% add efficiency are derived thoroughly. Based on these theoretical analysis, the channel add filter and some other multi-channel filters are designed in two-dimensional photonic crystals (2D PCs) with square lattice of dielectric rods in air. The numerical results by using the finite-difference time-domain (FDTD) method demonstrate almost complete channel add/drop tunneling at resonance via the three-port systems.     

Fourier-domain low-coherence interferometry for differential mode delay analysis of an optical fiber

We propose a novel mode analysis and differential mode delay measurement method for an optical fiber using Fourier-domain low-coherence interferometry. A spectral interferometer based on a Mach-Zehnder interferometer setup was used with a broadband source and an optical spectrum analyzer to detect relative temporal delays between the guided modes of a few-mode optical fiber by analyzing spectral interference signals. We have shown that experimental results of the proposed method agree well with those results obtained by using a conventional time-domain measurement method. We have demonstrated that this new mode analysis technique has high sensitivity (<60 dB) and very good resolution (<1 ps/m).     

Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses

Er³⁺-doped tellurite glasses with molar compositions of xNb₂O₅-(14.7-x)Na₂O--10ZnO--5K₂O--10GeO₂-- 60TeO₂--0.3Er₂O₃ (x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm fibre and planar amplifiers. The effects of Nb₂O₅ on the thermal stability and optical properties of Er³⁺-doped tellurite glasses have been discussed. It is noted that the incorporation of Nb₂O₅ (x=5) increases the thermal stability of tellurite glasses significantly. Er³⁺-doped niobium tellurite glasses exhibit a large stimulated emission cross-section (7.2\times 10^-21- 10.7×10^-21~cm² and the gain bandwidth, FWHM×\sigma_e^{\rm peak} (274\times 10^-28 - 480×10^-28~cm³), which are significantly higher than that of silicate and phosphate glasses. In addition, the intensity of upconversion luminescence of the Er³⁺-doped niobium tellurite glasses decreases rapidly with increasing Nb₂O₅ content. As a result, Er³⁺-doped niobium tellurite glasses might be a potential candidate for developing laser or optical amplifier devices.     

Self-organized Criticality in an Earthquake Model on Random Network

A simplified Olami-Feder-Christensen model on a random network has been studied. We propose a new toppling rule — when there is an unstable site toppling, the energy of the site is redistributed to its nearest neighbors randomly not averagely. The simulation results indicate that the model displays self-organized criticality when the system is conservative, and the avalanche size probability distribution of the system obeys finite size scaling. When the system is nonconservative, the model does not display scaling behavior. Simulation results of our model with different nearest neighbors q is also compared, which indicates that the spatial topology does not alter the critical behavior of the system.     

A Solvable Decorated Ising Lattice Model

A decorated lattice is suggested and the Ising model on it with three kinds of interactions K₁, K₂, and K₃ is studied. Using an equivalent transformation, the square decorated Ising lattice is transformed into a regular square Ising lattice with nearest-neighbor, next-nearest-neighbor, and four-spin interactions, and the critical fixed point is found at K₁=0.5769, K₂=-0.0671, and K₃=0.3428, which determines the critical temperature of the system. It is also found that this system and the regular square Ising lattice, and the eight-vertex model belong to the same universality class.     

基于比较算法和单纯形法的电子枪快速设计方法

 采用比较算法快速寻找数据库中与目标导流系数相匹配的电子枪尺寸,采用缩尺法改变其尺寸到所要求的目标尺寸。考虑电子枪尺寸对注腰半径、导流系数、层流性等参数的影响,建立了评价电子注性能的目标函数,采用单纯形法优化目标函数实现最优的电子层流性,且基于比较算法和单纯形算法的设计方法具有通用性,工作效率高。     

溶胶-凝胶SiO2薄膜氨热两步后处理

 以正硅酸乙酯为前驱体,氨水作催化剂,采用溶胶-凝胶法提拉镀制SiO₂双面膜,对薄膜进行氨处理和热处理。采用椭偏仪、分光光度计、红外光谱、扫描探针显微镜、静滴接触角测量仪表征薄膜的特性。研究表明：经氨热两步后处理,膜厚持续减小,折射率经氨处理先增大了0.236,再经热处理又减小了0.202,膜层透光性变好,透过率峰值持续向短波方向移动;经两步后处理的膜面平整度明显变好,与水的接触角先增大到58.92°后减小到38.07°。     

H_2S_2的构型及其异构化的量子化学研究

采用量子化学中的二阶微扰(MP2)方法,在6-311+G(3df,2p)水平上,利用Gaussian软件优化反应物,过渡态和生成物的几何结构,在相同水平上对反应物,过渡态和生成物进行了频率分析,同时完成了内禀反应坐标(IRC)分析.进而利用过渡态理论,计算了温度在300K时的H迁移异构化反应的速率常数.研究结果表明,H2S2的构型有两种,分别为:线型和分叉型,其中线型HSSH的能量较低,为稳定结构;平衡常数很小,为2.2×10-20,不利于平衡从线型向分叉型异构体转化,反之,分叉型向线型转化较容易,因此分