Pyrolysis-GC/MS of Menthyl Esters of N-Benzoxycarbonyl Amino Acid

With the aid of a Pyrolysis-GC/TOF MS technique,the pyrolysis behaviour of two menthyl esters of N-benzoxycarbonyl amino acid was investigated.A clear pattern emerges involving the cleavage of the bond linking the menthyl ring to the carboxy group,followed by further degradation of the fragments.The major pyroproducts were p-menth-1-ene pyrolysed at a higher temperature or p-menth-2-ene pyrolysed at a lower temperature,and va-rious derivatives of cyclohexene pyrolyzed from the menthyl ring.In addition,some ...     

Microfluidic System for Synthesis of Trigonal Selenium Nanowires

<正>A microfluidic system was developed for the synthesis of trigonal selenium(t-Se) nanowires,which was composed of a glass microchip coupled with a poly(methyl methacrylate)(PMMA) microchip.In the glass microchip, amorphous selenium(a-Se) colloid was prepared by reducing selenious acid with an excess amount of hydrazine at a temperature of 100℃.In the coupled PMMA microchip,a-Se was transformed into more stable t-Se seeds via sonication at room temperature.The residence time of the reactants in both microchips was optimized by varying the dimension and length of the microchannel each.The t-Se nanowires were formed by anisotropic growth of selenium crystallite during sonication and aging under the assistance ofβ-cyclodextrin(β-CD).Various stages of the nanowires' growth were investigated.The as-synthesized products were characterized by powder X-Ray diffraction(XRD),Raman spectroscopy,scanning electron microscopy(SEM),transmission electron microscopy(TEM) and selected-area electron diffraction(SAED).     

吲哚化合物绿色高效的硫氰酸化反应

本文报道了在温和绿色的条件下,以过氧化氢(H₂O₂)作为氧化剂,进行吲哚化合物区域选择性硫氰酸化反应。结果表明：该反应体系中,无论是氮取代吲哚还是游离氨基吲哚均可获得较高的产率。产物2a～2o的结构经¹H NMR和¹³C NMR表征。该方法的主要特点是反应条件温和,反应时间短,产率高。     

18F标记吲哚苯醌衍生物分子探针的合成及正电子发射型计算机断层显像

基于2-苯基萘型结构,以2-甲基吲哚和四氯苯醌、1-二甲基胺-2-丙炔和碘甲基硼酸频哪醇酯分别作为起始底物,经5步反应合成了一种吲哚苯醌类分子探针的前体。其结构经¹H NMR, ¹³C NMR和HR-MS(ESI)表征。对该前体进行放射性标记,再经高效液相色谱分析纯化,最后将探针注入小鼠体内进行正电子发射型计算机断层显像（PET）。结果表明：探针分子进入小鼠体内后,在膀胱、胆和肠道聚集,随后经肠道和膀胱代谢排出体外。     

铁基分子筛活性位点的制备控制及对NH3-SCR活性的影响

采用离子交换法,通过不同制备条件制备Fe-beta分子筛,并探讨不同制备条件对催化剂活性位点和NH3-SCR活性的影响。通过UV-Vis分析,将不同位置的吸收峰归属于不同的铁活性位点,300nm以下的高能谱区可以归属于孤立的Fe3+位点,300nm-400nm间归属于低聚的FexOy簇,而400nm以上为Fe2O3大颗粒聚合物。对比不同催化剂的SCR活性发现,孤立的Fe3+和低聚态的Fe3+是主要的活性位点,这两种物种的所占比例高低直接影响了催化剂的活性。而大尺度的Fe2O3为非活性位点,因尽量控制并降低其所占比例。另外低聚态的Fe3+所占比例越高,N2O的生成量越高,N2的选择性越差。因此,在制备过程中,除了控制大尺度的Fe2O3的含量,同时要尽量降低低聚态的Fe3+的含量,以增加N2的选择性。采用离子交换法制备Fe-beta催化剂,pH、交换温度、前驱体种类、硅铝比、煅烧条件等制备条件会对Fe-beta的活性位点造成影响,从而导致活性差异。根据实际应用需求,调控制备条件,可有效控制活性物种的分布,制备具有高效NH3-SCR活性的铁基分子筛催化剂。     

Promotion Effect of Gold on Mo/ZSM-5 Catalyst for the Catalytic Cracking of Light Diesel Oil to Increase Propylene Production

Kinetics and Catalysis - Using a modified deposition-precipitation method, a series of Au–Mo/ZSM-5 catalysts with different Au loadings were prepared. The XRD, nitrogen adsorption-desorption,...     

基于化学成分关联的二烯类橡胶垫对汽油鉴定干扰性研究

基质干扰一直是火灾现场助燃剂物证鉴定领域研究的重点和难点.本研究基于前期对分子结构中含有"烷基苯"的典型基质丁苯橡胶的研究结果,考察了干扰性与分子结构的相关性,为进一步探究基质材料干扰助燃剂检验鉴定的官能团结构,选择4种二烯类橡胶垫(丁苯橡胶垫、天然橡胶垫、丁基橡胶垫和三元乙丙橡胶垫)为研究对象,以确定含二烯类结构的橡...     

弹性蛋白酶生物催化酯水解的综合实验设计*

酯的水解是有机化学实验教学中的一个重要化学反应,传统的酯水解实验设计是利用酸性或碱性环境在加热的条件下进行水解,而本实验设计将酯水解与生物催化相结合,利用弹性蛋白酶的水解功能,在常温及中性环境下实现对4-三氟甲基-7-丙酰氧基香豆素的水解。该实验设计创新性地将酯水解和酶催化相结合,有利于拓展学生的知识面,培养化学生物学复合型人才。同时,生物催化反应具有反应温和、环境友好等特点,符合当代绿色化学的需求。     

基于气相色谱-静电场轨道阱高分辨质谱法快速筛查和确证农产品中222种农药残留

该文在QuEChERS方法的基础上采用固相分散萃取样品处理一体机(Sio-dSPE)对样品进行前处理,结合气相色谱-静电场轨道阱高分辨质谱法(GC-Orbitrap MS)对农产品中多农药残留进行筛查和确证.对Sio-dSPE前处理方法中盐析剂和除水剂的种类、净化剂的种类与用量、基质效应等进行考察.在最优条件下,采用G...     

电化学免疫传感器检测TET1蛋白

基于Ten-eleven translocation 1(TET1)蛋白催化5-甲基胞嘧啶(5-Methylcytosine,5mC)生成5-羟甲基胞嘧啶(5-Hydroxymethylcytosine,5hmC),结合5hmC抗体的免疫识别反应,建立了一种电化学分析方法用于TET1蛋白的特异性检测.以金纳米颗粒(Au...