A New Sandwiched-type Polyoxotungstate Containing {Cd4} Transition-metal Cluster： Synthesis,Structure and Luminescent Property

A new sandwiched polyoxometalate [HK11Cd4Cl2（PW9034）2]·18H2O （1）, incor- porating a unique hybrid tetranuclear cadmium cluster （abbreviated to {Cd4}） with two trivacant polyanions [B-α-PW9O34]9-, has been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, UV-vis, and single-crystal X-ray diffraction analysis. Crystal data for 1： monoclinic, space group C2/c, a = 19.2997（4）, b = 13.8014（3）, c = 31.9819（8） A, β = 102.764（2）°, V= 8308.3（3） A3, Z = 4, P2O86Cl2K11Cd4W18H37, Mr = 5735.13, Dc = 4.584 mg-mm-3, F（000） = 10084, μ = 26.579 mm-1, the final R = 0.0378 and wR = 0.0989 for 6558 observed reflections （I〉 2σ（I））. X-ray crystallographic study shows that the molecular structure of 1 contains four cadmium atoms. Two CdO6 distorted octahedra and two CdOsC1 distorted octahedra combine with each other in turn via edge-sharing, resulting in a regular rhomb-like cluster sandwiched between two {B-a-PW9034} units. Further, the sandwich-type polyoxoanions were connected by K＋ ions to form a complicated 3-D open-framework through connecting with each terminal O atom of the [Cd4C12（PW9O34）2]12- polyoxoanions. In addition, compound 1 exhibits photoluminescence property at room temperature and the band gap can be assessed at 3.25 eV.     

面向对象的串并行有限元分析系统

研究了面向对象的串并行有限元分析系统的关键实现技术。首先介绍的有限元系统类库分析,重点阐明了面向对象方法应用于串并行有限元分析所具有的优势,基于此将集成系统归纳成多个组成类库:包括数学计算类库、数据处理类库、有限元基本类库、数值分析模型类库、图形类库以及应用框架工具类库等,进而介绍分析程序的面向对象实现方法及过程,最后形成一个集成的交互式并行有限元分析框架OOParaFEA(Object OrientedParallel FEA framework)。系统快速高效的实现,表明面向对象的方法的确从软件的可维护性、可扩充性以及减少复杂性等方面带来前所未有的优势,并且由于其固有的继承特性而使其特别适合团队协作开发大型有限元分析软件,从而给我国大规模科学计算软件的研制提供一个新思路。     

Teleportation of Multipartite State via W State

A scheme of teleporting a multi-particle state via W state is presented. The W class states serve as quantum channels. After the sender operates both Von Neumann measurements and Bell-state measurements and then inform the receiver her results, the receiver can reconstruct the original state by corresponding unitary transformation. The probability of successful teleportation is also obtained. Special example of four-particle state is discussed in detail.     

极化子效应对ZnS/CdSe核壳量子点光吸收系数的影响

在有效质量近似下,利用量子力学密度矩阵理论,从理论上研究了考虑极化子效应后核壳量子点中线性、三阶非线性以及总的光吸收系数在不同条件下随入射光能量变化的关系。通过数值计算,分析了电子-LO声子和电子-IO声子相互作用对ZnS/CdSe柱型核壳结构量子点光吸收系数的影响。结果表明,极化子效应对光吸收系数有很大影响,不同声子模式对光吸收系数影响大小不同。考虑电子-LO声子后,光吸收系数被大大提高。另外,入射光强和弛豫时间对系统的吸收系数也有很大影响。     

基于反中值滤波的红外焦平面自适应非均匀性校正方法

分析了红外焦平面阵列非均匀性的噪声特性，提出了一种用反中值滤波为核心的红外焦平面自适应校正的方法。针对实际的图像进行了实验，实验证明该方法在校正效果、收敛速度、对静止目标保持能力及可硬件化等方面都有较好的表现。     

用肖特基电容电压特性数值模拟法确定调制掺杂AlxGa1-xN/GaN异质结中的极化电荷

研究发展了用肖特基电容电压特性数值模拟确定调制掺杂Al_xGa_1-xN/GaN异质结中极化电荷的方法.在调制掺杂的Al_0.22Ga_0.78N/GaN异质结上制备了Pt肖特基接触,并对其进行了C-V测量.采用三维费米模型对调制掺杂的Al_0.22Ga_0.78N/GaN异质结上肖特基接触的C-V特性进行了数值模拟,分析了改变样品参数对C-V特性的影响.利用改变极化电荷、n-AlGaN 关键词： xGa_1-xN/GaN异质结')" href="#">Al_xGa_1-xN/GaN异质结 极化电荷 电容电压特性 数值模拟     

一种易于硬件实现的图像有损压缩算法

原始图像数据经过小波变换后,根据子带系数之间在空间上和方向上所呈现出的带间相似性,将像素集合重新定义为集合树。通过对直流系数量化编码和交流系数比特深度编码中的参数K和熵编码中长度分别为3bit码字（choicel）和4bit码字（choice2）的编码方式的选择实现数据的渐进性编码,使产生的码流具有内嵌特性,可以对任意码流进行截取和译码,实现对码率的有效控制。提出了一种具有复杂度低、易于硬件实现的图像有损压缩算法。经过系统仿真证明此算法有利于提高重建图像的质量。     

混合物质高压状态方程的计算

 介绍了在温度相同的条件下,混合物中各组元通过密度-压强迭代法,达到温度和压强平衡,再结合叠加原理,编程计算出混合物质状态方程。为验证该程序,对氘氚与氩按不同比例混合时的状态参量进行了分析。当氘氚中含少量氩时,计算得到的状态方程与纯氘氚符合较好;同样地,氩中含少量氘氚时的状态方程也与纯氩的很接近。这说明该程序是可行的。     

广义经典力学系统的第一积分与变分方程特解的联系

给出了广义经典力学系统的变分方程,研究了变分方程的解与系统的第一积分之间的联系,并证明可由系统的第一积分求得变分方程的特解. 关键词： 广义经典力学系统 第一积分 变分方程     

The fractal measurement of experimental images of supersonic turbulent mixing layer

Flow visualization of supersonic mixing layer has been studied based on the high spatiotemporal resolution Nano-based Planar Laser Scattering(NPLS) method in SML-1 wind tunnel. The corresponding images distinctly reproduced the flow structure of laminar,transitional and turbulent region,with which the fractal measurement can be implemented. Two methods of measuring fractal dimension were introduced and compared. The fractal dimension of the transitional region and the fully developing turbulence region of supersonic mixing layer were measured based on the box-counting method. In the transitional region,the fractal dimension will increase with turbulent intensity. In the fully developing turbulent region,the fractal dimension will not vary apparently for different flow structures,which em-bodies the self-similarity of supersonic turbulence.