基于色酮骨架的新型Pd(II)配合物的合成及其晶体结构

以3-碘代色酮、降冰片烯、新戊酸钯和三(4-甲氧苯基)膦为原料,通过“一锅法”合成了一种含色酮骨架的新型Pd(II)配合物,其结构经¹H NMR, ¹³C NMR, ³¹P NMR和HR-MS（ESI-TOF）表征。X-射线单晶衍射分析显示该配合物晶体属于三斜晶系,P₁空间群,Pd与周围的4个原子形成了扭曲的平面四边形结构。     

氟里昂113在多频强红外场离解过程中的V-V能量转移

用TEACO₂激光9P(24),9P(22),9P(20),9P(18)四支线组成的多频强红外场“超激发”氟里昂₁₁₃分子,使其达到很高激发态。由分解曲线可以看出CF₂Cl·CFCl₂与CF₃·CCl₃之间的V-V能量转移有明显的“虹吸”作用。从所得主要产物C₂P₆,C₂Cl₆,C_关键词：     

用HREELS研究氢在GaAs和InP的(111),(111)表面上的吸附

氢在GaAs和InP表面上的吸附可以用高分辨率电子能量损失谱(HREELS)来探测。Ga—H,As—H,In—H和P—H键的伸缩振动各自对应于不同的能量损失。但是As—H振动极容易和Ga—H振动追加声子损失相混淆,只有从损失峰的相对强度比较上来区别。实验得到吸附的氢与表面原子的成键情况取决于表面的原子结构及电子分布。对于GaAs(111)面,低暴露量时只形成Ga—H键,而高暴露量时还可以形成As—H键。而InP(111)表面由于是经过磷气氛退火处理的,在低暴露量下In—H与P—H键均可形成。InP(Ⅲ)面上只看到P—H损失峰,说明这个表面是完全以P原子结尾的。在(Ⅲ)面上出现小面的情形,则表面Ⅲ族和Ⅴ族原子均可同氢成键。 关键词：     

可用于激光核聚变的闪烁中子探测器

在当前激光核聚变实验中,中子集中在短时间内出现、且产额低。为适应这种特点,要求探测器的效率高,分辨时间短。利用闪烁中子探测器探测激光核聚变所产生的中子,能测定中子产额,记录中子能量,而且探测效率高,分辨时间短。缺点是易受γ射线、X射线的干扰。     

研测动态问题的旋转孔径散斑照相法Ⅱ:矩位、平四位、直三位孔径

本文提出了旋转孔径散斑照相法中三种新颖的基本孔径:矩位孔、平四位孔和直三位孔,进行了理论分析和实验证明。采用新孔径拍摄散斑照相,散斑信息利用率高,衍射晕能量分布合理,信噪比提高,因而散斑条纹清晰度得到改善,相应的实验误差减小。     

A METHOD FOR FINDING POTENTIALS CORRESPONDING TO POLYNOMIAL-FACTOR EIGENFUNCTIONS IN QUANTUM MECHANICS

A method for finding potentials corresponding to polynomial-factor eigenfunc-tions is given for the Schr（?）dinger equation as an example.It is shown that theeigen-solutions for harmonic and Columb's potentials in quantum mechanics are the twoexamples which can be given by this method and some other examples are discovered.This method and some results of this paper may be useful for hadron structure mo-del theory.One of the examples is the equation in Ref.（4）which is derived fromBethe-Salpeter equation for the case that the straton is tightly bounded in certain po-tential well.When this method is applied to that equation for three dimensionalcentral symmetric potential V（r）=V₀—2（N+（1/2））β^-1（√V₆r²）+（V₆r⁶）, some resultsare obtained as shown in Fig. 2 in which λ′ must be considered as a linear function of m².The so called“quasic Regge trajectory”behavior is manifested.     

Y(Co1-xCux)5中子衍射研究

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非圆截面环流器硬X射线辐射强度的绝对测量

本文给出了逃逸电子在孔拦上轰击出的硬X射线能谱及其辐射强度,描述了硬X射线闪烁谱还原成能谱的分析处理法,并对NaI(T1)探测器的绝对光峰效率进行了测量。     

ANGULAR MOMENTUM CORRELATION OF FRAGMENTS IN DEEP INELESTIC COLLISIONS

The role of the non-diagonal difusion coefficient D12 of the two dimensional F-P EQ. In the mean value of angular momentum of fragments, their varaince and covaraince are discussed. It is found that D12 doesnot influence the equilibrium value of the quantities, but influences the rate for the quantities to reach equilibrium. So that it mainly influences the angular momentum transfer at the beginning of the reaction and that of large incident angular momentum partial waves. We also find that the covaraince is especially sensitive to D12.     

Two-dimensional photon counting imaging detector based on a Vernier position sensitive anode readout

A two-dimensional photon counting imaging detector based on a Vernier position sensitive anode is reported. The decode principle and design of a two-dimensional Vernier anode are introduced in detail. A photon counting imaging system was built based on a Vernier anode. The image of very weak optical radiation can be reconstructed by image processing in a period of integration time. The resolution is superior to 100 μm according to the resolution test. The detector may realize the imaging of very weak particle flow of high-energy photons, electrons and ions, so it can be used for high-energy physics, deep space exploration, spectral measurement and bio-luminescence detection.