小地老虎性信息素分泌腺体的部位及其超微结构

对羽化不同天数(1、3、5、7 d)小地老虎Agrotis ypsilon(Rottemberg)雌蛾性信息素分泌腺体的位置及结构进行了光学显微镜、扫描电镜、透射电镜的观察.结果表明:小地老虎性信息素分泌腺体位于腹部末端第8、9节节间膜腹面.求偶时,伸出节间膜,为一黄白色的囊泡.腺体表面分布着饱满的锥状体.腺体细胞呈单层排列,中央细胞为柱状,细胞核为椭圆形.细胞与细胞间有明显的胞连接,细胞基底膜基褶较多,质膜上分布着微绒毛,并与内表皮连接,内表皮之上含有多层几丁质,胞质中含有空泡、线粒体、脂质粒及光面内质网,并且随着蛾龄的增加,脂质粒和光面内质网的数量会显著增多.研究小地老虎性信息素腺体发育过程中的超微结构,有助于阐明性信息素生物合成、释放的机制.     

GEOMETRIC AND ELECTRONIC STRUCTURES OF Ti8C12 CLUSTER

The electronic structure of Ti₈C₁₂ clusters with three possible geometric structures suggested in the literature is studied using the discrete-variational local-density-functional method. The results show that the ground states of the clusters are all degenerate, which means further Jahn-Teller distortions for the geometric structures of clusters. The results also indicate that the distorted dodecahedral Ti₈C₁₂ cluster, which is proposed by Guo et al. and optimized by the first principle calculations, is the most stable one among the clusters we considered and its electronic structure can explain the experimental observations. In this cluster, there is a strong pd bonding between Ti and C atoms, and the density of states at the Fermi energy is high.     

DISSOLUTION OF IRON TO COPPER IN Fe60Cu40 ALLOY BY MECHANICAL ALLOYING AND SUBSEQUENT DECOMPOSITION

A metastable alloy with composition Fe₆₀Cu₄₀ can be prepared in single phase of a fcc structure by mechanical alloying, although Fe-Cu system is virtually immiscible in its equilibrium state at ambient temperature. The M?ssbauer spectra of this supersaturated solid solution could be fitted by two subspectra whose hyperfine magnetic fields are 200 kOe and 250kOe. In this metastable alloy, the iron atoms at the interface are easy to form clusters characterized as α-Fe at a temperature below 250℃, whereas the iron atoms in the body will cluster together at a higher temperature above 350℃ and behave as γ-Fe, and then transform to ferromagnetic bcc iron occurs.     

石墨炉原子吸收光谱法测定山药中镉含量的不确定度评定

建立有效的数学模型,全面分析了微波消解石墨炉原子吸收光谱法测定山药中镉不确定度的主要来源,并系统地评定各因素的不确定度。结果表明,对于山药中镉含量为25.12μg/kg的样品,扩展不确定度为3.47μg/kg(k=2),最终测量结果表示为25.12±3.47μg/kg。影响最终不确定度的主要有标准溶液配制、测量重复性及样品回收率3个分量,而称重和消解液的定容过程对结果影响较小。通过对测量的不确定度评定,为有效地控制山药中镉含量的检测提供可靠的理论依据。     

Sb2O3的丰度对（1-x）La0.6Dy0.1Sr0.3MnO3/（x/2）（Sb2O3）电输运性质的影响

用固相反应法制备(1-x)La0.6Dy0.1Sr0.3MnO3/x/2(Sb2O3)(x=0.00,0.02,0.15)样品,通过X射线衍射(XRD)图谱,扫描电子显微镜(SEM)照片及SEM能谱(EDS),ρ～T曲线研究样品的结构及电输运性质.结果表明:Sb离子没有进入Mn位,Sb2O3包覆在La0.6Dy0.1Sr0.3MnO3颗粒表面,Sb2O3起助熔剂作用,使得复合样品的颗粒变大且大小相对均匀;复合样品的绝缘体-金属转变温度TP较纯的La0.6Dy0.1Sr0.3MnO3的TP提高20K左右,对x=0.15的样品电阻高峰值比纯的La0.6Dy0.1Sr0.3MnO3的峰值电阻率增大两个数量级,用自旋极化隧穿理论予以解释.     

A class of hybrid DG/FV methods for conservation laws II: Two-dimensional cases

By comparing the discontinuous Galerkin (DG) methods, the k-exact finite volume (FV) methods and the lift collocation penalty (LCP) methods, a concept of ‘static reconstruction’ and ‘dynamic reconstruction’ was introduced for higher-order numerical methods in our previous work. Based on this concept, a class of hybrid DG/FV methods was presented for one-dimensional conservation law using a ‘hybrid reconstruction’ approach. In the hybrid DG/FV schemes, the lower-order derivatives of the piecewise polynomial are computed locally in a cell by the traditional DG method (called as ‘dynamic reconstruction’), while the higher-order derivatives are re-constructed by the ‘static reconstruction’ of the FV method, using the known lower-order derivatives in the cell itself and in its adjacent face neighboring cells. In this follow-up paper, the hybrid DG/FV schemes are extended onto two-dimensional unstructured and hybrid grids. The two-dimensional linear and non-linear scalar conservation law and Euler equations are considered. Some typical cases are tested to demonstrate the performance of the hybrid DG/FV method, and the numerical results show that they can reduce the CPU time and memory requirement greatly than the traditional DG method with the same order of accuracy in the same mesh.     

On the Well-Posedness Problem and the Scattering Problem for the Dullin-Gottwald-Holm Equation

In this paper, we study the well-posedness of the Cauchy problem and the scattering problem for a new nonlinear dispersive shallow water wave equation (the so-called DGH equation) which was derived by Dullin, Gottwald and Holm. The issue of passing to the limit as the dispersive parameter tends to zero for the solution of the DGH equation is investigated, and the convergence of solutions to the DGH equation as ²0 is studied, and the scattering data of the scattering problem for the equation can be explicitly expressed; the new exact peaked solitary wave solutions are obtained in the DGH equation. After giving the condition of existing peakon in the DGH equation, it turns out to be nonlinearly stable for the peakon in the DGH equation.     

紫外差光谱测定Gd(Ⅲ), Yb(Ⅲ)与HBED配合物的条件稳定常数

在0.01 mol·L-1 N-2-羟乙基哌嗪-N'-2-乙磺酸(Hepes), pH 7.4, 室温条件下, 应用紫外差光谱滴定观察了Gd(Ⅲ), Yb(Ⅲ)与N, N'-二(2-羟苄基)乙二胺-N, N'-二乙酸(HBED)的结合. 结果表明 Gd(Ⅲ), Yb(Ⅲ)与HBED均形成1∶1的配合物, 其紫外差光谱均于237和291 nm处出现吸收峰, 在237 nm处配合物Gd-HBED与Yb-HBED的摩尔吸光系数分别为 ΔεGd=(22.52±0.20)×103 cm-1·mol-1·L, ΔεYb=(27.15±0.11)×103 cm-1·mol-1·L; 配合物Gd-HBED与Yb-HBED的条件稳定常数分别为 lgKGd-HBED=13.56±0.28, lgKYb-HBED=16.06±0.03, 符合线性自由能关系.     

微波-模板法合成锂离子电池正极材料LiMn2O4机理的光谱学研究

采用微波-PAM模板法合成了具有尖晶石结构的锰酸锂材料,利用动态红外光谱（FTIR）对该方法的反应机理进行了研究。在前驱体的制备和在LiMn2O4晶核形成过程中,由于聚丙烯酰胺与反应母体之间的弱键合作用,使其在晶粒生长过程中对LiMn2O4的团聚规律与缺陷结构起到重要调控作用。     

熔融织构Y0．8Ca0．2Ba2Cu3Oy的电子比热

采用热驰豫方法在0到9T范围内测量了熔融织构Y0．8Ca0．2Ba2Cu3Oy的比热．零场下，2-180K的比热结果可以用Einstein模型来描述．通过4-Einstein峰拟合声子谱的方法，我们分别处理了不同磁场下超导转变附近的比热，获得了晶格比热和不同磁场下的电子比热，并将实验结果与London模型的计算结果进行对比，发现London模型能够很好地模拟出我们的实验结果．