不同方法制备的CO2-3替换磷灰石固溶体晶体化学的FTIR研究

采用不同方法制备了CO2-3替换的磷灰石固溶体,利用FTIR结合XRD对其进行了晶体化学研究,结果表明均相沉淀法制备的碳羟磷灰石(CHAP)属B型替换且替换方式是[CO3·OH]四面体替换[PO4]四面体;固相离子交换法制备的CHAP属A型替换且替换方式是[CO3]三角形配位体替换通道位置的OH-;固相反应法制备的碳氟磷灰石(CFAP)属B型替换,其替换方式是[CO3·F]四面体替换[PO4]四面体;sol-gel法制备的CHAP属AB混合型替换,其Ψ3分裂为Ψ3-1,Ψ3F,Ψ3-4.高斯函数法拟合表明Ψ3F峰是A型替换的Ψ3-2与B型替换的Ψ3-3的叠合.当WCO2-3＜3.34%时,随CO2-3含量增加,A型替换量增大,且当WCO2-3=3.34%时达最大值,当3.34%＜WCO2-3＜7.52%时,随CO2-3含量增加,B型替换量增大,且当WCO2-3= 7.52%时亦到饱和.     

系统动力学模型结构分析中表函数的改进方法

分析了非线性系统动力学(SD)模型中表函数环节的传统表示方法,指出该方法对于进行SD模型的结构分析所造成的障碍,并提出了用牛顿插值的承袭性算法来改进表函数环节的表示方法的思路.接着分别介绍了用差商和差分牛顿插值法改进表函数的过程.最后,通过一个实例说明了表函数改进的方法,并展示了以此为基础进行结构分析的思路.     

几种N-取代马来酰胺酸辅酶模型的核磁共振研究

我们对8种N-取代马来酰胺酸辅酶模型与不同类型的亲核试剂反应后生成的产物进行了¹H、¹³C NMR的研究, 测得¹H、¹³C谱化学位移,研 究探讨其规律性, 并测试了IR谱和元素分析.     

系列类立方烷型Fe4S4簇合物的XPS分析

对7种类立方烷型Fe_4S_4簇合物进行了XPS分析,得到了中心离子Fe的价态,给出了系列Fe_4S_4中骨架硫的结合能,由峰合成结果给出各种S、N的比例与按结构式计算的结果相同。     

复制受限的环境演算中模态逻辑的内涵性

环境演算(MA)的模态逻辑AL进行了研究．在考虑了复制操作和限制操作的情况下，提出了逻辑等价的协归纳操作描述，并利用协归纳关系与进程结构同余关系进行比较，证明了若对MA加上约束条件得到子集MAIF^syn，此时逻辑等价(=L)与结构同余关系是等价的，即AL在MAIF^syn中是内涵的．同时发现由于复制操作的存在，AL的内涵性受到了影响，使得AL的区分能力被削弱，但通过对复制公式的构造验证了AL的表达能力．     

多元χ演算运行时错误的不可判定性

针对多元χ演算运行时刻通信安全的判定性问题进行了研究．通过从Lazyλ项到χ项的编码，将判定一个Lazyλ项是否有范式的问题归约为进程是否有通信错误的问题．证明了在多元χ演算中，通讯错误也是不可判定的．结论说明不存在算法直接来检测进程的通信安全性，而只有通过其他间接的手段(如构造类型系统)才能部分达到预防运行时错误的目的．     

Three Types of Expression in Dark-Soliton Perturbation Theory Based on Squared Jost Solutions

Three types of expression in the dark-soliton perturbation theory based on squared Jost solutions are invesgigaged in ghis paper. It is shown that there are three formally different results about the effects of perturbagion on a dark soliton, and it is proved by means of a transformation between two integral variables that they are essentially equivalent.     

Study on the Chemical Constituent from the Seed of Litchi chinensis Sonn.

Seed of Litchi chinensis Sonn. is a traditional Chinese medicine, having curative effects on gastric disease, diabetes,and relieving pain.[1] Two new compounds 4-O-p-coumaroylquinic acid butyl ester (1) and 3-O-p-coumaroylquinic acid butyl ester (2), along with five known compounds: 5-O-p-coumaroylquinic acid butyl ester (3),[2] 3-O-p-coumaroylquinic acid methyl ester (4),[3] n-butyl-1-β-D-fructopyranoside (5),[4] D-1-O-methylmyo-inositol (6)[5] and 1H-imidazole-2,3-dihydro-2-oxo-4-carboxylic acid methyl ester (7)[5] were isolated and purified from the ethanol extracts of the seed of L.chinensis Sonn. Their structures, shown in Figure 1, were elucidated by ESI-MS, 1H NMR and 13C NMR, including 2DNMR spectroscopy.     

图中相互独立的4圈和含4个点的路

设k是一个正整数，G是一个顶点数为|G|=4k的图. 假设σ\-2(G)≥4k-1, 则G有一个支撑子图含k-1个4圈和一条顶点数为4的路，使得所有这些圈和路都是相互独立的. 设G=(V\-1,V \-2;E)是一个二分图使得|V\-1|=|V\-2|=2k. 如果对G中每一对满足x∈V\-1和y∈V\-2的不 相邻的顶点x和y 都有d(x)+d(y)≥2k+1, 则G包含k-1个相互独立的4圈和一条顶点数为4的路，使得所有这些圈和路都是相互独立的，并且此度条件是最好的.     

Tokamak Experiment and Tokamak Engineering——Development of the Plasma Diagnostics on HL-2A Tokamak

The main mission the HL-2A tokamak is of the experiments on to explore the divertor physics and to investigate the plasma confinement, transport and instabilities with high power auxiliary heating and advanced fuelling, it is necessary to develop more new diagnostics and increase the spatial and temporal resolutions of the measurements for exist system. Up to now, about 30 diagnostic systems have been moved from HL-1M to HL-2A tokamak. Other 10 diagnostic systems are being designed and installed on the device. In developed in last 2 years, will be presented.