Preparation of Anodized Aluminum for Electrodeposition of Metals (Co-Cu System) into Pores of Oxide

Conditions under which anodized aluminum is treated first in a dilute solution of phosphoric acid and then in a fluoroborate immersion solution in order to deposit a multilayer system of cobalt and copper in the pores in the oxide were studied.     

Segregation in the Falicov--Kimball Model

The Falicov–Kimball model is a simple quantum lattice model that describes light and heavy electrons interacting with an on-site repulsion; alternatively, it is a model of itinerant electrons and fixed nuclei. It can be seen as a simplification of the Hubbard model; by neglecting the kinetic (hopping) energy of the spin up particles, one gets the Falicov–Kimball model. We show that away from half-filling, i.e. if the sum of the densities of both kinds of particles differs from 1, the particles segregate at zero temperature and for large enough repulsion. In the language of the Hubbard model, this means creating two regions with a positive and a negative magnetization. Our key mathematical results are lower and upper bounds for the sum of the lowest eigenvalues of the discrete Laplace operator in an arbitrary domain, with Dirichlet boundary conditions. The lower bound consists of a bulk term, independent of the shape of the domain, and of a term proportional to the boundary. Therefore, one lowers the kinetic energy of the itinerant particles by choosing a domain with a small boundary. For the Falicov- Kimball model, this corresponds to having a single “compact” domain that has no heavy particles. Received: 21 June 2001 / Accepted: 4 January 2002     

Stochastic radiative transfer in a finite plane-parallel medium with general boundary conditions

The time-independent radiative transfer problem in a scattering and absorbing planar random medium with general boundary conditions and internal energy source is considered. The medium is assumed to consist of two randomly mixed immiscible fluids, with the mixing statistics described as a two-state homogeneous Markov process. The problem is solved in terms of the solution of the corresponding free-source problem with simple boundary conditions which is solved using Pomraning-Eddington approximation in the deterministic case. A formalism, developed to treat radiative transfer in statistical mixtures, is used to obtain the ensemble-averaged solution. The average partial heat fluxes are calculated in terms of the albedoes of the source-free problem. Results are obtained for isotropic and anisotropic scattering for specular and diffused reflecting boundaries.     

Vanadium valency charge state in solid solutions ScNb2−2xTa2xVO9

Phase equilibria in the Sc₂O₃-V₂O₅-Nb₂O₅-Ta₂O₅ system and properties of ScNb_2−2xTa_2xVO₉ phases were studied by X-ray phase analysis, optical and radio spectroscopy. A continuous series of solid solutions was shown to exist at 0≤x≤1. V(IV) centers with different crystallographic surrounding were detected for all the considered compositions. A correlation between the number of V(IV) ions and the width of the forbidden gap in the solid solutions was found.     

Pseudomeasure character of the ultraspherical semigroups

We prove that the diffusion semigroups generated by the second order differential ultraspherical (Gegenbauer) operator are pseudomeasure operators.     

Quantum frequency standards based on the soliton state of a Bose-Einstein condensate

A method for stabilizing frequency based on using the soliton state of the Bose-Einstein condensate of alkali metal atoms as an atomic source was suggested. The critical total number of lithium condensate particles at which the existence of a quasi-one-dimensional soliton in the condensate was possible and the lifetime of such a soliton were estimated. The attainable accuracy of measuring reference transition frequencies in the suggested standard was shown to be substantially higher than with the known quantum frequency standards.     

High energy asymptotics of the scattering amplitude for the Schrödinger equation

We find an explicit function approximating at high energies the kernel of the scattering matrix with arbitrary accuracy. Moreover, the same function gives all diagonal singularities of the kernel of the scattering matrix in the angular variables. This paper is dedicated to Jean-Michel Combes on the occasion of his sixtieth birthday.     

Likelihood Ratio Processes for Markovian Particle Systems with Killing and Jumps

We consider Markov processes built from pasting together pieces of strong Markov processes which are killed at a position dependent rate and connected via a transition kernel. We give necessary and sufficient conditions for local absolute continuity of probability laws for such processes on a suitable path space and derive an explicit formula for the corresponding likelihood ratio process. The main tool is the consideration of the process between successive jumps – what we call ‘elementary experiments’ – and criteria for absolute continuity of laws of the process there. We apply our results to systems of branching diffusions with interactions and immigrations. This revised version was published online in June 2006 with corrections to the Cover Date.