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991.
The use of phase-Doppler anemometry (PDA) to characterize the detail in-flight plasma sprayed particle behavior has been demonstrated
previously [Ma et al. Plasma Chem Plasma Process 24(1):85; 25(1):56] The present articles shows further that a direct relationship
may exist between the PDA measured particle volume flux and the coating microstructure and deposition efficiency (DE). In
the situation when the precise particle temperature information is not available, the PDA measured particle volume flux may
provide an alternative to predict quantitatively the variation of the coating microstructure and the DE. By monitoring the
in-flight particle volume flux variations, instead of the particle velocity, size and temperature individually and simultaneously,
the optimal settings of the plasma spraying parameters may also be determined conveniently. However, it is noted that the
effective applications of such approach depend largely on the particle surface morphology and the pre-determination of the
particle size range. 相似文献
992.
993.
H. D. Dahmen P. Manakos T. Mannel T. Ohl 《Zeitschrift fur Physik C Particles and Fields》1989,44(1):139-147
The photon two-point function is calculated using the exponential representation for the time-evolution operator taking into account terms up to second order ine in the exponent. The limiting case of vanishing electron mass is examined and it is shown that mass singularities cancel by means of unitarity. Near mass shell the causal Green function exhibits in the limit of vanishing electron mass the expected cut behaviour, off mass shell we recover the result of the usual perturbation theory. 相似文献
994.
The Ni(II) ion catalyzed thermal decomposition of peroxomonosulfate (PMS) was studied in the pH range 3.42–5.89. The rate is first order in [PMS] and Ni(II) ion concentrations. At pH greater than or equal to 5.23, the reaction becomes zero order in [PMS] and this changeover in the order of the reaction occurs at a higher concentration of nickel ions. The first‐order kinetics in PMS can be explained as a rate‐limiting step and is the transformation of nickel peroxomonosulfate into nickel peroxide. This peroxide intermediate reacts rapidly with another PMS to give oxygen and Ni(II). The formation of nickel peroxide is associated with a small negative or nearly zero entropy of activation. The zero‐order kinetics in [PMS] can be explained by the fact that the hydrolysis of aquated nickel(II) ions into hydroxocompounds is the rate‐limiting step. The turnover number is 2 at pH 3.42 and increases with pH. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 39: 320–237, 2007 相似文献
995.
The spectra of the intensity fluctuations of light scattered by large (erythrocytes of whole blood) and small (vesicles of surgical bile) particles in natural conditions were studied. It is shown that photon correlation spectroscopy can be used in analysis of variations in the size of biological particles in normal and pathological conditions and as an express method of noninvasive diagnostics of diseases. 相似文献
996.
Blundell Tom L. Bolanos-Garcia Victor Chirgadze Dimitri Y. Harmer Nicholas J. Lo Thomas Pellegrini Luca Sibanda B. Lynn 《Structural chemistry》2002,13(3-4):405-412
Signaling in living systems needs to achieve high specificity, to be reversible, and to achieve high signal to noise. Signaling mediated by multiprotein systems has evolved that avoids the requirement for high-affinity binary complexes that would be difficult to reverse and which, in the overcrowded cell, would lead to excessive noise in the system. Symmetrical structures are only occasionally formed. When they are, it is principally to colocate components, for example, the tyrosyl kinases of growth factors, where dimers form. Symmetry is, however, often broken, presumably to create more sensitivity and specificity in the signaling system by assembling other components, into higher-order multiprotein systems. The binding of a single heparin to two 1:1 FGF:FGFR complexes is an example, as is the binding of a single ligase to the Xrcc4 dimer, perhaps so creating a further DNA-binding site. 相似文献
997.
T Kusama T Soga Y Ono E Kumazawa E Shioya Y Osada S Kusumoto T Shiba 《Chemical & pharmaceutical bulletin》1991,39(8):1994-1999
Two novel analogs of a biosynthetic precursor of lipid A (2) were synthesized. The one analog (3) has acyl groups identical to those of 2, and the other (4) has tetradecanoyl groups in place of the (R)-3-hydroxytetradecanoyl groups of 2. Both 3 and 4 possess an alpha-glycosidically-bound phosphonooxyethyl group in place of the alpha-glycosyl phosphate group of 2. Compounds 3 and 4 exhibited definite antitumor activity against Meth A fibrosarcoma and low toxicity in rabbits, as the original compound 2 does. The replacement of the hydroxytetradecanoyl groups with tetradecanoyl groups barely affected the antitumor activity, but slightly enhanced the toxicity in rabbits. 相似文献
998.
999.
V. A. Nikitenko S. V. Mukhin S. P. Pivneva G. R. Vlas'yants I. A. Karetnikov S. G. Stoyukhin 《Journal of Applied Spectroscopy》1991,54(6):578-581
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 54, No. 6, pp. 960–964, June, 1991. 相似文献
1000.