北京市制造业优先发展产业的选择分析

制造业作为国民经济的物质基础和产业主体,不仅是经济高速增长的发动机和产业结构优化的推动力,同时也是解决就业的重要产业。本文将综合评估模型应用于北京市制造业优先发展产业的选择,并对北京市应优先发展的产业进行了研究和分析。     

A Quantum-Mechanical Explanation of Buffer Gas Effect on Submillimeter Wave Laser

Based on the theory of molecular vibration relaxation, the model of buffer gas effect was built up. By theoretically deducing the vibrational lower-level deactivation rate of operating gas molecule with quantum mechanics, the selection rules of high-efficient buffer gas under different working conditions were educed and tested by experiments. The results could be helpful to the study of large-power wide-range efficient tunable miniature pulsed optically pumped submillimeter wave laser and its application.     

改进型氢氧联合循环及其性能初步分析

1前言氢能既具备矿石燃料的优点，又符合长远能源发展的要求，被称为21世纪的能源。氢能发电是氢能利用的一个重要方面，近年来出现了各种氢能发电方案。文献山提出了氢氧联合循环（包括混合式和面式）；此外还有高温蒸汽朗肯循环，氢氧燃烧，加热氦（或二氧化碳）的闭式透平K’］；对燃用液氢的系统也有论述＊’］。本文在已有工作的基础上，综合了混合式和面式氢氧联合循环的一些特点，提出了氢氧联合循环的改进型式。本文将着重讨论这种改进循环的性能，并与混合式多级再热氢氧联合循环加以比较，对氢氧联合循环的进一步发展作一初步尝…     

宽带扩展腔产生15飞秒光脉冲实验研究

用３ｍｍ长的钛宝石短棒和改进的非对称Ｚ型折叠腔结构进行自锁模实验，以石英棱镜对作为腔内色散补偿元件，在５Ｗ氩离子激光泵浦下，实现低阈值泵浦自锁模运转。在腔内不加任何调制元件的情况下实现软光阑锁模，获得最短脉冲宽度为１５ｆｓ，光谱宽度为８０ｎｍ，输出平均功率４００ｍＷ。     

偏振光在非球形气溶胶中传输特性的Monte Carlo仿真

非球形气溶胶是影响辐射传输的重要因素. 系统给出了矢量辐射传输Monte Carlo模型, 并验证了其准确度; 考虑入射光偏振态, 讨论了不同方向漫射光Stokes矢量对气溶胶形状的敏感性; 分析了气溶胶形状、入射光偏振状态对光波退偏振度、透过率及反射率的影响. 模拟仿真结果表明, 对于不同偏振态的入射光, 不同方向的Stokes矢量对气溶胶形状变化的灵敏程度并不一致, 而在天顶角0°方向区域,Q, U及V分量对形状的灵敏程度普遍不高; 气溶胶形状对反射漫射光退偏程度的影响强于透射漫射光, 入射光偏振态不同, 漫射光退偏程度也存在较大差异. 气溶胶形状对光波整体透过率与反射率影响显著, 且该影响随传播距离增大而增大; 入射光偏振态对透过率与反射率影响相对较小, 与自然光相比, 水平偏振光透过率略偏小, 反射率略偏大, 垂直偏振光反之, 圆偏振光与自然光的模拟结果相当.     

On the finite basis problem for the monoids of partial extensive injective transformations

Let \(PEI_n (POEI_n)\) be the monoid of all partial (order-preserving) extensive and injective transformations over a chain of order n. We give a sufficient condition under which a semigroup is nonfinitely based and apply this condition to show that the monoid \(PEI_3 (POEI_3)\) is nonfinitely based. This together with the results of Edmunds and Goldberg gives a complete answer to the finite basis problem for the monoid \(PEI_n (POEI_n)\): the monoid \(PEI_n (POEI_n)\) is nonfinitely based if and only if \(n\geqslant 3\). Furthermore, it is shown that the monoid \(PEI_n (POEI_n)\) is hereditarily finitely based if and only if \(n\leqslant 2\).     

红外分光光度法测定地下水中的石油类物质

采用红外分光光度法测定地下水中石油类物质。用四氯化碳萃取水中的石油类物质,将萃取物用硅酸镁吸附,脱除极性物质后进行测定。方法的检出限为0.014 mg/L,测定结果的相对标准偏差为0.65%~1.18%(n=l1)。用该方法对地下水样品进行测定并进行加标准回收试验,结果表明,地下水样品的加标回收率为84.0%~93.2%。该方法灵敏度高,操作简便、快速,可以满足地下水中石油类分析的要求。     

Are Triphenylamine‐Functionalized or Carbazole‐Functionalized Iridium Complexes the More Effective Phosphorescent Materials? A Theoretical Perspective

The ground and excited states, charge injection/transport, and phosphorescence properties of eleven carbazole‐ and triphenylamine‐functionalized Ir^III complexes were investigated by using the DFT method. By analyzing the spin–orbit coupling (SOC) matrix elements, radiative decay rate constants k_r, and the electronic structures and energies at the ${{\rm{S}}_{\rm{0}}^{{\rm{opt}}} }$ and ${{\rm{T}}_{\rm{1}}^{{\rm{opt}}} }$ states, it was possible to rationalize the order of the experimental phosphorescence quantum yields of a series of Ir^III complexes and to predict that [Ir(Nph‐2‐Cz‐tz)₃] has a higher phosphorescence quantum yield than [Ir(TPA‐tz)₃] (TPA=triphenylamine, tz=thiazolyl, Cz=carbazole, Nph=N‐phenyl). Carbazole‐functionalized Ir^III complexes were shown to be efficient phosphorescent materials that have not only fast but also balanced electron/hole‐transport performance as well as high phosphorescence quantum yields. The phosphorescence emission spectra can be modulated by modifying or replacing a pyridyl substituent.     

Template‐Free Synthesis of Core–Shell TiO2 Microspheres Covered with High‐Energy {116}‐Facet‐Exposed N‐Doped Nanosheets and Enhanced Photocatalytic Activity under Visible Light

Core–shell TiO₂ microspheres possess a unique structure and interesting properties, and therefore, they have received much attention. The high‐energy facets of TiO₂ also are being widely studied for the high photocatalytic activities they are associated with. However, the synthesis of the core–shell structure is difficult to achieve and requires multiple‐steps and/or is expensive. Hydrofluoric acid (HF), which is highly corrosive, is usually used in the controlling high‐energy facet production. Therefore, it is still a significant challenge to develop low‐temperature, template‐free, shape‐controlled, and relative green self‐assembly routes for the formation of core–shell‐structured TiO₂ microspheres with high‐energy facets. Here, we report a template‐ and hydrofluoric acid free solvothermal self‐assembly approach to synthesize core–shell TiO₂ microspheres covered with high‐energy {116}‐facet‐exposed nanosheets, an approach in which 1,4‐butanediamine plays a key role in the formation of nanosheets with exposed {116} facets and the doping of nitrogen in situ. In the structure, nanoparticle aggregates and nanosheets with {116} high‐energy facets exposed act as core and shell, respectively. The photocatalytic activity for degradation of 2,4,6‐tribromophenol and Rhodamine B under visible irradiation and UV/Vis irradiation has been examined, and improved photocatalytic activity under visible light owing to the hierarchical core–shell structure, {116}‐plane‐oriented nanosheets, in situ N doping, and large surface areas has been found.     

Well‐Defined Metal–Organic Framework Hollow Nanocages

Metal–organic frameworks (MOFs) have demonstrated great potentials in a variety of important applications. To enhance the inherent properties and endow materials with multifunctionality, the rational design and synthesis of MOFs with nanoscale porosity and hollow feature is highly desired and remains a great challenge. In this work, the formation of a series of well‐defined MOF (MOF‐5, Fe^II‐MOF‐5, Fe^III‐MOF‐5) hollow nanocages by a facile solvothermal method, without any additional supporting template is reported. A surface‐energy‐driven mechanism may be responsible for the formation of hollow nanocages. The addition of pre‐synthesized poly(vinylpyrrolidone)‐ (PVP) capped noble‐metal nanoparticles into the synthetic system of MOF hollow nanocages yields the yolk–shell noble metal@MOF nanostructures. The present strategy to fabricate hollow and yolk–shell nanostructures is expected to open up exciting opportunities for developing a novel class of inorganic–organic hybrid functional nanomaterials.