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991.
A novel method for the dynamic determination of cetirizine dihydrochloride in urine using surface enhanced Raman scattering (SERS) has been developed. Comparison of SERS activities between gold and silver colloid was made based on the analysis of the transmission electron micrographs and the SERS spectra, revealing that silver colloid is much more efficient on the signal enhancement performance. The primary sites of the adsorption on the nanoparticle surface were represented by the feature peaks of piperazine at ca. 1050?cm?1 and phenyl rings at ca. 1630?cm?1, respectively. The best signal response was extracted at pH 7 at the Cl?:Ag+ molar ratio of 2:1. The matrix effect was eliminated by subtracting the spectral contribution of the blank urine from the sample spectra. Sample preparation procedures were minimized. Quantification could be simply accomplished on the predicted versus actual concentration curve, within the Raman shift range from 500 to 2500?cm?1. Neither modeling nor complicate calculation was required. The method was shown to be specific and applicable for drug urine concentration monitoring in situ. 相似文献
992.
Pancracio Palting Shan Tao Lai Ying Nan Chiu Jorge Ricardo Letelier 《Journal of mathematical chemistry》1997,21(1):31-49
Succinct expressions for the matrix elements of various vibrational operators have been derived in the basis of the nondegenerate
harmonic oscillator. Among these are the matrix elements of
and
, which are found to be dependent upon two quantities and their derivatives. Furthermore, the derivative property of the commutator
is used to obtain an explicit expression for the derivatives of an operator in terms of its nested commutator with the conjugate
momentum. It may be applied to any of the above cases to obtain the matrix representatives of expressions such as the mixed
products
, for example. In addition, a simple expression for 1/q is given and its derivatives may be evaluated by this commutator technique. Also the matrix elements of a Gaussian-type operator
has been evaluated.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
993.
Larsson J Chang Z Judd E Schuck PJ Falcone RW Heimann PA Padmore HA Kapteyn HC Bucksbaum PH Murnane MM Lee RW Machacek A Wark JS Liu X Shan B 《Optics letters》1997,22(13):1012-1014
We demonstrate an apparatus for measuring time-dependent x-ray diffraction. X-ray pulses from a synchrotron are diffracted by a pair of Si(111) crystals and detected with an x-ray streak camera that has single-shot resolution of better than 1 ps. The streak camera is driven by a photoconductive switch, which is triggered by 100-fs laser pulses at a repetition rate of 1 kHz. The laser and the streak camera are synchronized with the synchrotron pulses. In the averaging mode, trigger jitter results in 2-ps temporal resolution. We measured the duration of 5-keV pulses from the Advanced Light Source synchrotron to be 70ps. 相似文献
994.
Xian Mei SHANG Ji Zhou WU Qing Shan LI 《中国化学快报》2006,17(6):821-824
In recent years, there has been considerable interest in organotin(Ⅳ) compounds. One of the important reasons is that many organotin compounds are biologically active1-3. The diorganotin(Ⅳ) complex containing carboxylate ligand have been investigated fo… 相似文献
995.
Forsythiasuspensa(ThUnb.)VahlhasbeenusedintradihonalChinesemedicineforanhiallammatoryandamibacterialpmposes.AnUInberofcompoundssuchasforsythiaside,phillygeninrengyoletc.haVebeenidentifiedl-#fromthefactsofmisplat.AsPartofourstudyontheachveprinciplesoftradihonalChinesemedicine,wereinvestigatCdthechemicalconstitllentsofRsuspensa.heartycompoundshavebeenisolatCdfromthisspecies.ThispaperdescribesthestrUcturalelucidahonofthreenewcompoundsfsuspenolicacid(1),forSythensideA(2),andforsythensideB(3)… 相似文献
996.
A Novel White Light Emitting Long-lasting Phosphor 总被引:4,自引:0,他引:4
BingFuLEI YingLiangLIU ZeRenYE ChunShanSHI 《中国化学快报》2004,15(3):335-338
A novel white light emitting long-lasting phosphor Cd1-xDyxSiO3 is reported in this letterThe Dy^3 doped CdSiO3 phosphor emits white light. The phosphorescence can be seen with the naked eye in the dark clearly even after the 254nm UV irradiation have been removed for about 30min. In the emission spectrum of 5% Dy^3 doped CdSiO3 phosphor, there are two emission peaks of Dy^3 , 580nm (^4F9/2→^6H13/2) and 486nm (^4F9/2→^6H15/2), as well as a broad band emission located at about 410nm. All the three emissions form a white light with CIE chromaticity coordinates x=0.3874, y=0.3760 and the color temperature is 4000 K under 254 nm excitation. It indicated that this phosphor is a promising new luminescent material for practice application. 相似文献
997.
Three novel 25,27-dihydroxy-26,28-bis(3-benzylselenopropoxy)-5,11,17,23-tetra-tert-butylcalix[4]-arene (2),25,27-dihydroxy-26,28-bis[3-(2-hydroxyethylseleno)propoxy]-5,11,17,23-tetra-tert-butyl-calix[4]arene (3) and 25,27-dihydroxy-26,28-bis(3-propylselenoproppxy)-5,11,17,23-tetra-tert-butyl-calix[4]arene (4) were synthesized for the comparison of their ion-selectivity in ion-selective electrodes (ISE). X-ray structure of the CH/π complex of 4.CH2Cl2 was elucidated. ISEs based on 2-4 as neutral ionophores were prepared, and their selectivity coefficients for Ag (logKAg,M^pot) were investigated against some main group metal ions and transition metal ones using the fixed interference method (FIM). These ISEs showed excellent Ag^ selectivity over most of the interfering cations examined. It is evident that the stronger Hg^2 interference may not be produced while hard donors (hydroxy) are close to the soft selenium donors. 相似文献
998.
报道2,4-Br2C6H3OCH(CN3)CO2Sn(C6H11)2CU3(1)和2-OCH3-4-CH3CH=CHC6H3OCH2CO2Sn(C6H11)2CH3(H2O)(Ⅱ)的晶体结构和分子结构。(Ⅰ)单斜晶系,空间群P21/c,a=13.067(3),b=10.594(3),c=18.157(4),β=106.99(2)°,Z=4,Dc=1.672g/cm3,V=2403.73,μ=43.731cm-1,Mr=622.99,F(000)=1232;(Ⅱ)单斜晶系,空间群P21/n,a=10.409(1),b= 12.570(2),c=20.664(2),β=83.51(1)°,Z=4,Dc=1.281g/cm3,V=2686.4A3,μ=9.761cm-1,Mr=539.28,F(000)=1120.最后的偏离因子,化合物(Ⅰ)R=0.046,Rω=0.046;化合物(Ⅱ)R=0.049,Rω=0.047。晶体结构解析表明,化合物(Ⅰ)和(Ⅱ)中的锡均被配体的3个碳和2个氧原子配位,配位原子呈畸变三角双锥构型;化合物中的环己基均为椅式构象;化合物(Ⅱ)中,配位水分子和另一分子的羰基氧与芳环上的甲基氧? 相似文献
999.
The kinetics and mechanism of the reduction of enneamolybdonickelate(IV) by arsenite in aqueous acid solution was studied by spectrophotometry. The reaction rate increases with increasing concentrations of H+ and with temperature. The associated rate law is:
. The rate constants and activation parameters of the rate-determining step were evaluated. A mechanism related to this reaction was proposed. 相似文献
1000.
建立了正化学源-气相色谱-质谱技术测定食用植物油中有机锡化合物残留的方法。食用油样品经环己烷-乙酸乙酯(1:1,v/v)溶解后,经凝胶渗透色谱(GPC)净化,目标馏分用四乙基硼酸钠进行衍生。采用基质校正曲线外标法定量,在20~2000 μg/L范围内,7种有机锡化合物均呈现良好的线性关系,相关系数大于0.99,定量限为0.3~1.2 μg/kg。对芝麻油样品进行加标回收试验,在0.05、0.10、0.20 mg/kg 3个添加水平下,7种有机锡化合物的平均回收率为66.2%~103.2%,相对标准偏差均小于11.5%。该方法精密度好,灵敏度高,可用于食用植物油中有机锡化合物残留量的测定。 相似文献