Magnetically retrievable Bi2WO6/Fe3O4/Na-MMT composite: fabrication and photocatalytic activity

Research on Chemical Intermediates - Magnetically retrievable bismuth tungstate/iron oxide/sodium montmorillonite composite (Bi2WO6/Fe3O4/Na-MMT) was synthesized via a simple solvothermal process....     

Cu2SnSe3/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries

Metal selenides as anode materials for sodium-ion batteries have attracted considerable attention owing to their high theoretical specific capacities and variable composition and structures.However,the achievement of long cycle life and superior rate performance is challenging for these selenide materials due to the volume variation upon cycling.Herein,a composite composed of a new binary-metal selenide[Cu2SnSe3(CSS)]and carbon nanotubes(CNTs)was constructed via a hydrothermal process followed by calcination at 600℃.Benefited from the unique structure of binary-metal selenide and the conductive network of CNTs,the Cu2SnSe3/carbon nanotubes(CSS/CNT)composite exhibits excellent electrochemical performance when used as an anode material for sodium-ion batteries.A reversible specific capacity of 399 mA·h/g can be maintained at a current density of 100 mA/g even after 100 cycles.This work provides a promising strategy for rational design of binary-metal selenides upon delicate crystal phase control as electrode materials.     

Constructing boronate-bridged core-satellite gold nanoassembly and its application in high sensitive colorimetric detection of benzoyl peroxide residues in food matrices

Here,a new designed core/satellite gold nanoprobe was developed for detecting trace mount of benzoyl peroxide(BPO) based on its deboronation.This gold nanoassembly(the BE-Au NPs_12/65) wa s constructed via borate ester formation between large 4-mercaptophenylboronic acid(MPBA) modified Au NPs(the MPBAAu NPs₆₅,as cores) and small dopamine modified AuNPs(the D PA-AuNPs₁₂,as satellites).Particularly,upon addition of BPO,it would trigger the deboronation for the BE-AuNPs_12/65 probes accompanying with distinct color changes from blue,purple to wine red,which implied the disassembly of the core/satellite nanostructure after the breakage of carbon to boron chemical bond.By measuring the absorbance ratio at 665 nm and 545 nm,quantification of BPO was achieved in the range of 10.0-100.0 nmol/L,which could also be easily observed by naked eyes.The nanoprobe utilized a boronate deprotection mechanism and the LSPR properties of Au NPs to provide high selectivity for detecting BPO over similar ROS/RNS with the limit of detection as low as 7.2 nmol/L.The practical applicability of this assay was verified through successful determining BPO in flour samples,which demonstrated its great potentials in food safety field.     

计算机网络的长程相关特性

针对一种计算机网络模型，利用节点排队长度累计量的均方涨落函数，研究了网络节点在时间上的长程相关特性.结果表明，随着负载的增加，网络节点数据包排队长度在时间上由自由流状态的不相关或短程相关逐渐演变为临界和拥塞时的长程相关，关联范围逐渐增大，长程关联特性开始显现.在自由流状态时，节点的不相关或短程相关，并且有一致的数值为0.5的幂指数这一典型特征.而在临界状态时，节点数据包排队长度长程相关，有大于0.5的幂指数为特征.并且随网络规模的增大，节点间的群体作用逐渐显著，幂指数呈下降趋势. 关键词： 计算机网络 相变 长程相关 幂律     

OSCILLATORY INTERLAYER COUPLING WITH Cu AND Zr UNDERLAYER THICKNESS FOR Co/Cu MULTILAYERS

Oscillatory behavior (with a period of about 9 nm) of antiferromagnetic coupling with the thicknesses of Cu and Zr underlayers is reported for sputtered Co(1 nm)/Cu(2.3 nm) multilayers. The related oscillation of magnetoresistance is also observed. Based on the analysis of X-ray diffraction patterns, the variation of crystallographic orientation and modulation period is proved not responsible to the phenomenon. But the underlayer strongly affects the growth orientation of multilayer.     

Ridgelet bi-frame

This article introduces a new bi-frame called ridgelet bi-frame. The ridgelet bi-frame consists of two ridgelet frames that are dual to each other. The construction of the ridgelet bi-frame starts with a bi-frame built on a biorthogonal wavelet system in the Radon domain. The image of the resulting bi-frame under an isometric map from the Radon domain to L²(R²) is also a bi-frame, which we refer to as the ridgelet bi-frame. The ridgelet bi-frame can be thought of as an extension of the notion of the orthonormal ridgelet, which provides a more flexible and effective tool for image analysis and processing applications. An algorithm for image denoising based on the new bi-frame is developed. Experimental examples have demonstrated that the excellent performance can be achieved when using the ridgelet bi-frame for image denoising.     

（L^p,L^q） Estimates for Multilinear Oscillatory Singular Integralswith Smooth Phases

In this paper,the authors establish the weighted (L^p,L^q) estimates for a class of multilinear oscillatory singular integrals with smooth phases.Certain endpoint estimates are also considered.     

HFC-152a的同步辐射真空紫外光电离和光解离研究

利用同步辐射真空紫外光，研究了HFC-152a(CH₃CHF₂)的光电离和光解离过程，通过测量各离子的光电离效率曲线，得到了该分子的电离能(11.94±0.04eV)和所有碎片离子的出现势，运用GAUSSIAN-03程序计算了母体和碎片及相应离子的结构、电子态和能量. 结合理论计算的结果，分析了母体离子可能的光电离解离通道及相关通道的解离能. 关键词： 同步辐射 光电离 出现势 HFC-152a     

二氧化钛多孔膜的UV-Vis光谱与光催化性能研究

以钛酸四丁酯(Ti(OBu)4)、乙醇胺(MEA)、聚乙二醇(PEG)和无水乙醇为反应体系,采用溶胶-凝胶法制备了TiO2溶胶并通过浸渍提拉法制得了TiO2多孔膜,用UV-Vis,XRD和AFM对制得的多孔膜进行了表征,讨论了薄膜的紫外-可见透过光谱随着薄膜层数的变化规律以及其与膜厚的关系,结果表明在本实验条件下薄膜转移得很均匀,每层膜厚度约为60nm。多孔膜的光催化测试结果表明,随着薄膜层数的增加,光催化活性也逐渐增强,10层多孔膜的光催化活性最高。     

胶原蛋白温度效应的Raman光谱研究

在不同温度下对Ⅰ型胶原蛋白进行了拉曼光谱测定。结果表明：随温度的升高，多数谱线向低波数移动，但CH2的变形振动谱线1302cm^-1向高波数移动，苯丙氨酸的特征振动谱线1003cm^-1的波数基本保持不变。同时还给出了拉曼谱线强度随温度的变化关系，得到了0，40，68，90℃四个变性峰，其中40，68℃的峰与DSC(差示扫描量热法)和SHG(二次谐波法)的测量结果一致，0℃的峰为冰冻相变，90℃的变性峰为胶原的二级结构被破坏所致。当温度达到150℃时，谱线强度显著降低，大部分谱线消失，胶原的一级结构遭到破坏。实验还发现胶原纤维在低温区具有较好的复性特性。