131Pm衰变的首次观测

利用³²S轰击¹⁰⁶Cd靶,通过3p4n反应产生了¹³¹Pm,反应产物经过毛细管及带收集传输系统传输到低本底区,测量了反应产物的X,γ单谱,并进行了X-γ,γ-γ符合测量,得到了¹³¹Pm的半衰期及衰变γ线,并建立了简单的衰变纲图.     

基于有限元分析的大型固体激光器稳定性指标重分配

在大型固体激光器结构稳定性设计中,使用等概率分配方法的分配值作为光学元件稳定性设计指标常常会增加结构设计的难度,造成结构建造的巨大浪费。为此,提出了基于结构有限元分析的稳定性指标重分配方法,即将同一光路中光学元件振动响应引起靶点光束的定位误差作为各自的权重系数,采用线性加权和法对稳定性指标进行重新分配。稳定性指标重分配后,所得到的同一光路中各光学元件的安全系数相等。利用此方法对某大型固体激光装置主机装置靶区一条光路中光学元件的稳定性指标进行了重分配,得到每条光路上光学元件稳定性的安全系数均为1.229,满足结构稳定性设计要求。     

Facet‐Dependent On‐Surface Reactions in the Growth of CdSe Nanoplatelets

Facet‐dependent on‐surface reactions are systematically studied on zinc‐blende CdSe nanoplatelets with atomically‐flat {001} basal facets and small yet non‐polar side facets. The on‐surface half‐reactions between the surface Se sites and Cd carboxylates in the solution are qualitatively equivalent to those on the spheroidal counterparts. Conversely, the on‐surface half‐reactions between the surface Cd sites and the activated Se precursors in solution show a strong facet‐dependence, which includes three distinguishable stages. In the first stage, the Se precursors adsorb onto the small and non‐polar side facets of the nanoplatelets. The second stage is initiated by the adsorbed Se precursors at the side‐basal plane edges and proceeds from the edges to the center of the basal planes in quasi‐zeroth‐order kinetics. In the third stage, the nanoplatelets are dismantled, which includes the creation of a hole in the middle and a build‐up of thick edges.     

Tunable On‐Chip Sources with Aperiodic Metasurface

Surface plasmons show tremendous capability in integrated communication, quantum computing and sensing. Excitations and manipulations of surface plasmons are essential in developing integrated photonic devices. Here, a systematic study of tunable emission of surface plasmons with an eightfold quasicrystal metasurface, which acts as an on‐chip source, is presented. It is shown that the quasicrystal structure can switch on or off the surface plasmons propagation channels in the desired direction. Meanwhile, such a quasicrystal structure can be polarization‐dependent or polarization‐independent based on different constituent slit pairs. The proposed quasicrystal design provides more freedom for steering surface plasmons in the launching process. Thus, it may significantly simplify the design and fabrication of integrated plasmonic devices.     

Sandwich enzyme-linked immunosorbent assay for naringin

Among the currently used immunoassay techniques, sandwich ELISA exhibits higher specificity, lower cross-reactivity, and a wider working range compared to the corresponding competitive assays. However, it is difficult to obtain a pair of antibodies that can simultaneously bind to two epitopes of a molecule with a molecular weight of less than 1000 Da. Naringin (Nar) is a flavonoid with a molecular mass of 580 Da. The main aim of this study was to develop a sandwich ELISA for detecting Nar. Two hybridomas secreting anti-Nar monoclonal antibodies (mAbs) were produced by fusing splenocytes from a mouse immunised against Nar-bovine serum albumin (BSA) conjugated with a hypoxanthine–aminopterin–thymidine (HAT)-sensitive mouse myeloma cell line; a sandwich ELISA for detecting Nar was developed using these two well-characterised anti-Nar mAbs. The performance of the sandwich assay was further evaluated by limit of detection (LOD), limit of quantification (LOQ), recovery, and interference analyses. A dose-response curve to Nar was obtained with an LOD of 6.78 ng mL⁻¹ and an LOQ of 13.47 ng mL⁻¹. The inter-assay and intra-assay coefficients of variation were 4.32% and 7.48%, respectively. The recovery rate of Nar from concentrated Fructus aurantii granules was 83.63%. A high correlation was obtained between HPLC and sandwich ELISA. These results demonstrate that the sandwich ELISA method has higher specificity for Nar than indirect competitive ELISA.     

化学品安全性快速评价方法

简要评述了化学品安全性的传统评价方法。详细介绍了一种快速评价化学品安全性的重要方法——诱变性测试法。该方法选用几种标准(或特定)的鼠伤寒沙门氏菌(Salmonella typhimurium)作为观察对象来研究待测化学品对菌株的诱变情况，以菌株回复突变的数目表征待测化学品的诱变性。当回复突变数目为零剂量(化学品)的2倍以上时，所测定化学品具有诱变性。具有诱变性的化学品为不安全化学品。     

单壁碳纳米管提升正极复合材料杯[4]醌/介孔炭CMK-3储锂性能

将杯[4]醌(Calix[4]quinone,C4Q)通过灌注法与有序介孔炭CMK-3制备成纳米复合材料,可抑制其在常规有机电解液中的溶解。 为了进一步提升其电化学性能,本文在C4Q/CMK-3复合材料中加入单壁碳纳米管(SWCNTs),减少了CMK-3的用量,并代替导电炭黑Super-P作为导电剂,通过脱泡搅拌法制备了C4Q/CMK-3/SWCNTs复合材料。 研究表明,当m(C4Q)：m(CMK-3)：m(SWCNTs)为1：1：1时,电化学性能最佳,0.1 C电流密度下循环100圈后,电池的容量保持为238.7 mA·h/g,当电流密度增大到1 C时,放电容量仍有260 mA·h/g,这是由于SWCNTs在复合材料C4Q/CMK-3中构建了三维导电网络,增强了电极的稳定性,降低了电池内阻,从而提升了电池的循环性能与倍率性能。     

Hollow Fiber-Solid Phase Microextraction of Polycyclic Aromatic Hydrocarbons from Environment Water Followed by Flash Evaporation GC/MS

Chromatographia - A solid phase microextraction coupled with flash evaporation GC/MS technique was developed for the quantitative determination of polycyclic aromatic hydrocarbons (PAHs) in water...     

动载荷下螺栓连接的优化设计

把螺栓法兰密封连接结构简化成-质量、弹簧、阻尼系统，其中阻尼包括黏性阻尼和库仑阻尼两个部分。用此模型对法兰在指数衰减脉冲激励下的响应进行了数值仿真，研究了螺栓中预应力、螺栓个数、法兰螺栓间的阻尼对法兰结构响应的影响，螺栓中预应力和螺栓个数对螺栓变形峰值有较大影响，阻尼对螺栓峰值的影响较小。     

Dynamic Stress Resulting from a Plane Compressional Wave in Two-particle Reinforced Composites

In this paper, based on the theory of elastodynamics, the multiple scattering of elastic waves and dynamic stress in multiparticle reinforced composites is investigated, and the analytical solution of this problem is obtained. By using the wave function expansion method, the expressions of total wave fields in each medium are presented. The addition theorem of spherical Bessel functions is employed to accomplish the translation for different local coordinate systems. According to the continuous boundary conditions around the particles, the expanded mode coefficients are determined. As an example, the variation of dynamic stress concentration factors at the interface between the particles and the matrix under different parameters is analyzed. It can be seen from the results that when the incident frequency is different, the effect of the distance between the centers of the particles on the dynamic stress varies greatly. Only when the distance is greater than a certain number can its effect be ignored. When the distance is fixed, the effect of material properties on dynamic stress is also examined.