培养学生的兴趣、独立性、自主性与素质教育

30年前,甚至十几年前物理系还是一个众生向往的殿堂,那些决心献身科学并且品学兼优的佼佼者进入到这个领域,从而受到同龄人的尊敬和羡慕.一代优秀的物理学工作者就是在这个环境中成长起来,成为今天物理科研与教学领域的中坚力量.然而随着时代的发展,社会的需求,职业市场的选择以及人们价值观的改变,部分优秀的中学毕业生选择了更现实的领域,如经济、计算机等,他们毕业后可以较轻松地获得工作条件优越,报酬丰厚的职业.因而大量的人才从物理学,特别是纯物理学领域中流失了.这些年再加上出国留学热,甚至在高中毕业就已走上出国之路,对我们人才培养的冲击之大是难以估计的.物理学在许多学生及家长眼中已沦为第二等的学科,或是不得已的选择.     

关于奇ATm核1/2+[411]转动带的系统分析

壳模型计算表明,1/2⁺[411]出现于¹⁵⁷Tm核的基态可能是由非轴对称形变造成的.但是新近从¹⁵⁷Yb衰变纲图给出的¹⁵⁷Tm低激发谱中,指认了一个建立在1/2⁺[411]带头上的基态转动带,并认为该带的性质是轴对称的,提取了该带的惯性参数与脱耦合参数.通过对奇ATm核1/2⁺[411]转动带的系统分析,强调了在¹⁵⁷Tm核中非轴对称γ自由度效应的重要性.     

High efficiency of Mn–Ce‐modified TiO2 catalysts for the low‐temperature oxidation of Hg0 under a reducing atmosphere

Manganese‐ and cerium oxide‐modified titania catalysts were prepared by the deposition precipitation for the removal of elemental mercury (Hg⁰) from simulated yellow phosphorus off‐gas at low temperature. In addition, these catalysts were characterized by X‐ray diffraction, Brunauer–Emmett–Teller measurements, X‐ray photoelectron spectroscopy and field‐emission scanning electron microscope to determine the surface morphology of the obtained compounds and explore their formation mechanism. The results revealed that a Mn–Ce loading and reaction temperature of 10% and 150 °C, respectively, as well as a Mn/Ce molar ratio of 2:1, led to an optimal efficiency for the oxidation of elemental mercury. Furthermore, the effects of flue gas components were investigated. The presence of O₂ clearly promoted the oxidation of Hg⁰. A CO atmosphere did not affect the Hg⁰ oxidation, when compared with N₂, whereas the presence of H₂S and water vapor inhibited the oxidation process. Furthermore, the X‐ray photoelectron spectroscopy spectra of Hg 4f revealed that the elemental mercury adsorbed by the catalyst is present as HgO. Finally, the Hg⁰ catalytic oxidation mechanism was discussed on the basis of the experimental results and characterization analysis.     

含噻吩杂环Schiff碱及其配合物的合成与发光性质

在热乙醇中合成了2-乙酰基噻吩缩异烟酰肼及其与Cd(II)、Cu(II)和Zn(II)形成的三种配合物;利用元素分析、摩尔电导测定,以及红外光谱、紫外光谱和热分析确定了合成产物的组成和结构,并测定了配合物的组成及发光性质.结果表明,酰肼的配位方式的不同导致配合物呈现不同的发光性质.     

基于NPP-VIIRS夜间灯光数据的山西省GDP空间化模拟

选取山西省为研究对象,以美国国家极轨合作仪件-可见红外成像辐射计套件（NPP-VIIRS）夜间灯光数据、GDP统计数据等为数据源,构建GDP空间化拟合模型,建立山西省GDP密度图,据此研究山西省经济的空间差异性。通过对NPP-VIIRS夜间灯光数据的空间化处理,提取灯光指数,并将其与GDP进行回归拟合,建立最佳回归模型,得到GDP密度拟合图;利用县级GDP数据进行线性纠正,从而提高GDP的模拟精度。结果表明：（1）NPP-VIIRS夜间灯光数据与GDP的相关性较高,可用于山西省GDP模拟;（2）与GDP分区建模相比,GDP整体建模的精度更高;（3）山西省GDP的空间分布整体呈由城市中心逐渐向周边辐射的特点,构成GDP过渡带。     

Bi-2223喷雾热分解粉末热处理工艺优化

Bi-2223 带材目前在电流引线、 超导电机、 超导电缆、 超导限流器等领域实现了许多示范性应用, 载流性能是表征其性能的重要指标, 而高质量的前驱体粉末是最终带材性能的关键保障. 本文选用具有工艺简单、 粉末效率高、 批次稳定性好等优点的喷雾热分解法制备的Bi-2223 前驱体粉末, 利用 TG-DSC、XRD、SEM 等测试手段对低氧条件下不同保温时间烧结的粉末进行分析, 并结合最终带材的载流性能测试结果, 获得了最优粉末烧结参数, 为后续喷雾热分解粉末的进一步生成 Bi-2223 相以及高性能粉末的制备提供了依据.     

The geometrical interpretation of uncertainty relation in Minkowski space

Clifford algebraic geometry corresponds to Minkowski space. Using the discrete structure of Minkowski space, we can abstract a class n-dimensional hyperbolic Hilbert phase space. To discussing the causality of physical event in Minkowski space, we can obtain the geometrical interpretation of uncertainty relation.     

滤紫外和红外光的荧光玻璃的研制及其应用

研制出了掺铈、钐的滤紫外和红外光的硼硅酸盐荧光玻璃，测试了该玻璃的吸收光谱和荧光谱，并用其做了固体激光器工作物质的紫外和红外滤光套，能使激光效率提高２５％－５０５，从而促进固体激光器的微型化和实用化。     

Adsorption of carbon disulfide on activated carbon modified by Cu and cobalt sulfonated phthalocyanine

A series of adsorbents were studied for removal efficiency of carbon disulfide (CS₂) under micro-oxygen conditions. It was found that activated carbon modified by Cu and cobalt sulfonated phthalocyanine (CoSPc) denoted as ACCu–CoSPc showed significantly enhanced adsorption ability. Reaction temperature was found to be a key factor for adsorption, and 20 °C seems to be optimal for CS₂ removal. Samples were analyzed by N₂-BET, XRD, XPS, SEM–EDS and CO₂-TPD. The characterization results demonstrated that large quantities of SO₄ ^2? anions were formed and adsorbed in the reaction process. SO₂, CS₂ and COS were detected in the effluent gas generated from the temperature programmed desorption of ACCu–CoSPc–CS₂. Therefore, it can be concluded that ACCu–CoSPc most likely acted as a catalyst in the adsorption/oxidation process on the surface of the impregnated sample. The generated sulfide and sulfur oxide can cover the active sites of adsorbents, resulting in pronounced reduction of adsorbent activity. Finally, the exhausted ACCu–CoSPc can be regenerated by thermal desorption.     

Development of an enzyme‐linked immunosorbent assay and immunoaffinity chromatography for glycyrrhizic acid using an anti‐glycyrrhizic acid monoclonal antibody

In this work, a new monoclonal antibody specific for glycyrrhizic acid was prepared and characterized. A hybridoma secreting an anti‐glycyrrhizic acid monoclonal antibody was produced by fusing splenocytes from a mouse immunized against a glycyrrhizic acid–bovine serum albumin conjugate with the hypoxanthine–aminopterin–thymidine‐sensitive mouse myeloma cell line (Sp2/0‐Ag14). Subsequently, an indirect, competitive enzyme‐linked immunosorbent assay for glycyrrhizic acid was developed using the monoclonal antibody. In this assay, we detected an effective measuring range of 78.12–2500 ng/mL. Both intra‐assay and inter‐assay repeatability and precision were achieved, with relative standard deviations lower than 10%. In addition, glycyrrhizic acid levels in both formulated Chinese medicines and biological samples were determined with high sensitivity and efficiency. We then successfully developed a reliable immunoaffinity chromatography to separate glycyrrhizic acid completely from its parent medicine. These methods will contribute to further research investigations to better understand the interactions of glycyrrhizic acid with other drugs in the complex system of traditional Chinese medicine.