LC Coupled with TOFMS for Metabonomics Study of Mini-pigs with Atherosclerosis

In this study, serum metabolic profiles of mini-pigs with atherosclerosis (AS) were analyzed by LC–TOFMS. Partial least-squares to latent structure-discriminant analysis and orthogonal projection to latent structure-discriminant analysis were used for group differentiation and selection of potential biomarkers. The mini-pig disease models were constructed by feeding a high-fat diet and inducing coronary injury, in accordance with the mechanism of AS pathogenesis. To characterize the development of AS, serum samples were collected and analyzed at two time points (two and ten weeks). Separate distinct clustering of results from normal and model mini-pigs could be observed for both the two and ten-week samples. With the development of AS, the metabolism of the model mini-pigs was more substantially disturbed. Major metabolites contributing to the discrimination were fatty acids, lysophosphatidylcholines, and bile acids. These potential biomarkers are related with inflammation, oxidative stress, and abnormal lipid and energy metabolism.

     

Z=18—82原子的同步辐射内壳层光电离积分截面的计算和讨论

此文计算了Ｚ＝１８－８２的原子在北京同步辐射４Ｂ９Ａ束线的白色Ｘ光照射下的光电离积分截面Ｇ值。结果表明，有三个Ｇ值较大的区域，Ｚ＝１８－２０，３９－４７和５９－８２，最大值分别为３．８×１０－６，１．６×１０－５和３．５×１０－５ｐｈｏｔｏｎｓ·ｃｍ２／ｓ。同时，估计了平衡时主要多重电荷态离子数目，分析了用同步辐射和离子阱进行多重电荷态实验的新的候选原子，讨论了有关实验方法和技术。     

C60/PMMA复合材料的反饱和吸收与光限幅特性研究

本文报导C₆₀/PMMA复合材料的制备方法,并采用调QNd:YAG倍频脉冲激光照射C₆₀/PMMA夏合材料,研究了其反饱和吸收与光限幅将性。在线性透射率为46%条件下,光限幅阈值能量密度为65mJ/cm²,材料破坏能量密度阈值为600mJ/cm².与C₆₀甲苯溶液相比具有一定的优点。     

标量场与电磁场相互作用体系中的Gasimir效应

摘要本文用Feynmann路径积分方法,研究了一种U(1)规范场理论中的Casimir效应。在一圈图近似下,计算了带电标量场在两个平行的理想金属板之间的Casimir能,并对低维情况进行了讨论。     

一种生物柴油代用品在HZSM-5分子筛催化剂上的催化热解

为了深入了解生物柴油在ZSM-5沸石上的催化反应机理,在常压的流动反应器中进行了生物柴油代用品丁酸甲酯在氢型ZSM-5(HZSM-5)催化剂上的热解和催化热解. 热解产物使用气相色谱-质谱法定性和定量测量. 动力学模型和实验表明,气相中氢提取反应是热解过程中丁酸甲酯分解的主要途径,但在HZSM-5上,丁酸甲酯则主要通过解离生成烯酮和甲醇消耗;与无催化反应相比,丁酸甲酯在HZSM-5上的初始分解温度降低了约300 K. 并且通过Arrhenius方程获得了在催化热解和均相热解条件下丁酸甲酯消耗的表观活化能. 明显降低的表观活化能证实了HZSM-5对丁酸甲酯热解的催化性能. 此外催化剂的活化温度对HZSM-5的某些催化性能具有一定的影响. 该研究对进一步的实际生物柴油燃料的催化燃烧具有一定的指导意义.     

Further results on large sets of disjoint group‐divisible designs with block size three and type 2n41

Large sets of disjoint group‐divisible designs with block size three and type 2ⁿ4¹ were first studied by Schellenberg and Stinson because of their connection with perfect threshold schemes. It is known that such large sets can exist only for n ≡0 (mod 3) and do exist for all odd n ≡ (mod 3) and for even n=24m, where m odd ≥ 1. In this paper, we show that such large sets exist also for n=2^k(3m), where m odd≥ 1 and k≥ 5. To accomplish this, we present two quadrupling constructions and two tripling constructions for a special large set called ^*LS(2ⁿ). © 2002 Wiley Periodicals, Inc. J Combin Designs 11: 24–35, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/jcd.10032     

The solvability conditions for inverse eigenproblem of symmetric and anti‐persymmetric matrices and its approximation

The problem of generating a matrix A with specified eigen‐pair, where A is a symmetric and anti‐persymmetric matrix, is presented. An existence theorem is given and proved. A general expression of such a matrix is provided. We denote the set of such matrices by ??????_Eⁿ. The optimal approximation problem associated with ??????_Eⁿ is discussed, that is: to find the nearest matrix to a given matrix A* by A∈??????_Eⁿ. The existence and uniqueness of the optimal approximation problem is proved and the expression is provided for this nearest matrix. Copyright © 2002 John Wiley & Sons, Ltd.     

5,10-二(对-氨基)四苯基卟啉和吖啶黄之间激发能量的传递

利用Forster能量传递机制,研究了氯仿溶液中吖啶黄向5、10-二(对-氨基)四苯基卟啉(简称TBP)的激发能量传递和TBP.浓度变化时对能量传递速度常数的影响.实验结果表明,吖啶黄和TBP之间具备能量共振传递的条件,并且计算了能量共振传递的临界距离为0.42nm、传递效率为0.72和传递速度常数为1.42×107s-1.这些数据对复合膜光电转换器件的设计将具有重要意义.