全文获取类型
收费全文 | 6221篇 |
免费 | 858篇 |
国内免费 | 842篇 |
专业分类
化学 | 4887篇 |
晶体学 | 77篇 |
力学 | 327篇 |
综合类 | 80篇 |
数学 | 601篇 |
物理学 | 1949篇 |
出版年
2024年 | 16篇 |
2023年 | 88篇 |
2022年 | 181篇 |
2021年 | 187篇 |
2020年 | 248篇 |
2019年 | 256篇 |
2018年 | 187篇 |
2017年 | 171篇 |
2016年 | 313篇 |
2015年 | 315篇 |
2014年 | 360篇 |
2013年 | 510篇 |
2012年 | 509篇 |
2011年 | 480篇 |
2010年 | 420篇 |
2009年 | 356篇 |
2008年 | 475篇 |
2007年 | 410篇 |
2006年 | 366篇 |
2005年 | 362篇 |
2004年 | 287篇 |
2003年 | 239篇 |
2002年 | 198篇 |
2001年 | 180篇 |
2000年 | 140篇 |
1999年 | 109篇 |
1998年 | 76篇 |
1997年 | 63篇 |
1996年 | 54篇 |
1995年 | 45篇 |
1994年 | 39篇 |
1993年 | 52篇 |
1992年 | 47篇 |
1991年 | 38篇 |
1990年 | 20篇 |
1989年 | 15篇 |
1988年 | 16篇 |
1987年 | 14篇 |
1986年 | 17篇 |
1985年 | 13篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1974年 | 4篇 |
1935年 | 2篇 |
排序方式: 共有7921条查询结果,搜索用时 0 毫秒
61.
A New Reaction-controlled Phase-transfer Catalyst System 总被引:1,自引:0,他引:1
MingQiangLI XiGaoJIAN GuiMeiWANG YanYU 《中国化学快报》2004,15(3):350-352
A new reaction-controlled phase-transfer catalyst system was designed and synthesized.In this system, heteropolytungstate [C7H7N(CH3)3]9PW9O34 was used for catalytic epoxidation of cyclohexene with H2O2 as the oxidant. The conversion of H2O2 was 100% and the yield of cyclohexene oxide was 87.1% based on cyclohexene. Infrared spectra showed that both fresh catalyst and the recovered catalyst do have completely same absorption peak, indicating the structure of catalyst is very stability and can be recycled. 相似文献
62.
63.
Nan Yan FU Mei Li PANG Yao Feng YUAN Ji Tao WANG* Department of Chemistry National Key Laboratory of Elemento-organic Chemistry Nankai University Tianjin 《中国化学快报》2002,13(10)
A highly efficient catalyst indium (III) tribromide is used to synthesize 5-alkoxy- carbonyl-4-hydrocarbyl-3,4-dihydropyrimidin-2(1H)-ones by a three-component coupling of β-keto ester, aldehydes and urea through improved Biginelli reaction. 相似文献
64.
Yang G Miao R Jin C Mei Y Tang H Hong J Guo Z Zhu L 《Journal of mass spectrometry : JMS》2005,40(8):1005-1016
Interaction of carboplatin with cytochrome c (Cyt. c) has been investigated by electrospray ionization mass spectrometry (ESI-MS) and tandem mass spectrometry (MS/MS). ESI-MS studies revealed that the ring-opened adducts of carboplatin with Cyt. c were formed in the stoichiometric ratio of 1:1 and 2:1 at pH 5.0 and 37 degrees C and in the stoichiometric ratio of 1:1 only at pH 7.0 and 37 degrees C. It was also found that Cyt. c could be cleaved by carboplatin at pH 2.5 and 50 degrees C. The cleaved fragments of Cyt. c were determined by ESI-MS and MS/MS analysis to be Glu66 approximately Met80, Ac-Gly01 approximately Met65, Glu66 approximately Glu104, Ac-Gly01 approximately Met80 and Ile81 approximately Glu104. The carboplatin prefers to anchor to Met65 first, then to Met80. To further confirm the binding site of Met, AcMet-Gly was used as the model molecule to investigate its interaction with carboplatin and its hydrolysis reaction. On the basis of species detected during the reaction monitored by ESI-MS, a possible pathway of the cleavage reaction was proposed. 相似文献
65.
Unlabeled fluoroimmunoassay with a europium chelate is described. The recommended method is simple because the complicated labeling process is omitted. The recovery of some samples ranges from 91 to 111%. The relative standard deviation of the method is less than 10%. The detection limit is about 10−10mol liter−1antigen. 相似文献
66.
[reaction: see text] Modulation of the fluorescein fluorescence in the presence of spiropyran and ferric ion by light was observed. Such fluorescence modulation was due to the low oxidation potential of complex MC.Fe(2+), which made the electron transfer from MC.Fe(2+) to Flu(+)()(*)() thermodynamically favorable. As a result, the communication between two molecular switches based on fluorescein and spiropyan, respectively, was realized via the reversible Fe(III)/Fe(II) redox couple. The communicating behavior corresponds well to the function of an INHIBIT logic gate. 相似文献
67.
68.
YueMingLIU FengMeiZHANG HaiHongWU HaiJiaoZHANG JianGuoYANG XingTianSHU MingYuanHE 《中国化学快报》2004,15(10):1258-1260
A SAPO-11 silicoaluminophosphate molecular sieve with stable crystal structure was synthesized for the first time. After removing template by calcination, its crystal space group still retains Icm2 which the as-synthesized has. The catalyst deriving from the present SAPO-I 1 materials shows higher isomerization selectivity and higher paraffin hydroisomerization yield than those reported elsewhere. 相似文献
69.
70.
几种热塑性特种工程塑料的热分析研究 总被引:5,自引:0,他引:5
聚芳醚和聚芳硫醚两类聚合物都为热塑性的耐高温特种高分子材料 ,由于它们的加工性好、加工成型效率高 ,受到了世界各国的高度重视。这两类聚合物在结构上有许多相似之处 ,如它们的主链都含苯环、酮基或砜基 ,而聚芳醚类聚合物的柔性基团为醚键 ,聚芳硫醚类聚合物的柔性基团为硫醚键 ,但由于氧和硫在元素周期表中属于同一族元素 ,原子结构仍然相似 ,因而在某些方面具有一定的可比性。研究它们的性能差异对于改进聚合物性能以及进行进一步的结构设计将有一定的帮助。在这两类聚合物中 ,国内已商品化生产的品种有PEEK、PES和PPS ,有… 相似文献