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881.
高分子凝胶化反应对功能高分子骨架结构有重要影响,它经历溶胶一凝胶的不可逆转变(sol-geltransition);导致高分子网络结构及分子尺寸的突变,动力学过程和机理十分复杂,因此,人们对这一领域的研究始终贯注了巨大兴趣.追溯过去,人们对高分子凝胶化过程的研究经历了由未考虑环化、搭环的Flory-stockmayer理论问;静态渗流理论[’]到动态凝胶化模型*三个发展阶段·后者除克报了前两种的不足外,还引入了与几何形状密切相关的动态标度处理方法.近年来,分形概念的产生更激励了动态标度的发展,这种增长模型的研究方法考虑了增长… 相似文献
882.
Qing Feng JIANG You Jun ZHOU Jian Zhong YAO Jia Guo LU Ju ZHU Chun Quan SHENG Can Hui ZHENG Bing YAO 《中国化学快报》2006,17(8):995-998
Since George R. Pettit’s group isolated cycloheptapeptide phakellistatin 1 from sponge1, over ten similar cyclic peptides have been obtained2-5. Phakellistatin 134 (Figure 1) is a cycloheptapeptide isolated from the brown snubby sponge from the South Chi… 相似文献
883.
IntroductionSnake-cageresin,alsoca1ledsnake-cagepolyelectrolyte['],isaspecialkindofamphotericresin.ItwasfirstinvestigatedbyHatchM.J.etal.in1957[z].Thetypicalandusefulsnake-cageresinisRetardation11A-8(l1A-8inthecon-text)manufacturedbyDowChemicalCoI,TD.Itissynthesizedbypolymerizingacrylicacidinsidethenetworkofastrongbasicanionexchangeresinwith8%crosslinking.Thus,theresinconsistsofacrosslinkedpolymermatrix,cage,andalinearpolymer,socalledsnake,whichisphysicallytrappedinsidethecage.Thecagepol… 相似文献
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887.
Hyperbranching polymerization of aziridine on silica solid substrates leading to a surface of highly dense reactive amine groups 总被引:2,自引:0,他引:2
Silica solid substrates such as fused silica, silicon wafers with a natural oxide layer, and glass were treated with aziridine to produce reactive primary amine groups on the top surface. We found that the hydroxyl group on the substrate was able to initiate the ring-opening polymerization of aziridine, resulting in highly branched poly(ethyleneimine) on the surface. In dichloromethane, the thickness of the organic film reached 25 A in 20 h and the absolute density of the primary amine group on the surface was 23 amines/nm(2). Atomic force microscopy shows an embossed morphology after the polymerization in dichloromethane, while use of toluene gives a rather smooth surface. The resulting organic layer shows high thermal and pH stability. 相似文献
888.
We have studied an anionic ligand effect in iron porphyrin complex-catalyzed competitive epoxidations of cis- and trans-stilbenes by various terminal oxidants and found that the ratios of cis- to trans-stilbene oxide products formed in competitive epoxidations were markedly dependent on the ligating nature of the anionic ligands. The ratios of cis- to trans-stilbene oxides obtained in the reactions of Fe(TPP)X (TPP = meso-tetraphenylporphinato dianion and X(-) = anionic ligand) and iodosylbenzene (PhIO) were 14 and 0.9 when the X(-) of Fe(TPP)X was Cl(-) and CF(3)SO(3)(-), respectively. An anionic ligand effect was also observed in the reactions of an electron-deficient iron(III) porphyrin complex containing a number of different anionic ligands, Fe(TPFPP)X [TPFPP = meso-tetrakis(pentafluorophenyl)porphinato dianion and X(-) = anionic ligand], and various terminal oxidants such as PhIO, m-chloroperoxybenzoic acid (m-CPBA), tetrabutylammonium oxone (TBAO), and H(2)O(2). While high ratios of cis- to trans-stilbene oxides were obtained in the reactions of iron porphyrin catalysts containing ligating anionic ligands such as Cl(-) and OAc(-), the ratios of cis- to trans-stilbene oxide were low in the reactions of iron porphyrin complexes containing nonligating or weakly ligating anionic ligands such as SbF(6)(-), CF(3)SO(3)(-), and ClO(4)(-). When the anionic ligand was NO(3)(-), the product ratios were found to depend on terminal oxidants and olefin concentrations. We suggest that the dependence of the product ratios on the anionic ligands of iron(III) porphyrin catalysts is due to the involvement of different reactive species in olefin epoxidation reactions. That is, high-valent iron(IV) oxo porphyrin cation radicals are generated as a reactive species in the reactions of iron porphyrin catalysts containing nonligating or weakly ligating anionic ligands such as SbF(6)(-), CF(3)SO(3)(-), and ClO(4)(-), whereas oxidant-iron(III) porphyrin complexes are the reactive intermediates in the reactions of iron porphyrin catalysts containing ligating anionic ligands such as Cl(-) and OAc(-). 相似文献
889.
The reaction of Ag2SO4 and bpp (bpp = 1,3‐bis(4‐pyridyl)propane) in H2O afforded the complex [Ag2(bpp)2(SO4) · 6.5H2O·CH3OH]n, 1. The IR and TGA have been recorded and the structure has been determined. Crystal data for 1: Space group C2/c, a = 17.885(4), b = 25.230(6), c = 8.832(2) Å, β = 105.437(4)°. V = 3841(1) Å3, Z = 8 with final residuals R1 = 0.0710 and wR2 = 0.1620. The complex shows a three‐dimensional supramoleclar structure constructed with two‐dimensional infinite [Ag2(bpp)2]n sheetlike layers pillared by Ag‐Ag interactions and Ag····O (SO4) interactions in the solid state. 相似文献
890.
NiCoB超细非晶合金的化学制备和热稳定性研究 总被引:4,自引:0,他引:4
用化学还原法制备了Ni-B、Co-B及不同含量的Ni-Co-B超细非晶态微粒.电感耦合等离子光谱(ICP)测定合金的组成表明:微粒中Ni与Co的含量可通过调节反应溶液中Ni与Co离子浓度来控制.X衍射(XRD)、透射电镜(TEM)及电子衍射证实合金是粒径约为20nm的非晶相球状颗粒.用示差量热法(DSC)考察了制备条件对非晶态合金热稳定性的影响.发现相同组成不同含量及不同条件下制得的样品其热稳定性均有差异.初步解释了引起这种差别的原因.从而揭示了非晶态合金结构的复杂性. 相似文献