全文获取类型
收费全文 | 7989篇 |
免费 | 1398篇 |
国内免费 | 1278篇 |
专业分类
化学 | 6461篇 |
晶体学 | 132篇 |
力学 | 459篇 |
综合类 | 100篇 |
数学 | 849篇 |
物理学 | 2664篇 |
出版年
2024年 | 16篇 |
2023年 | 154篇 |
2022年 | 290篇 |
2021年 | 308篇 |
2020年 | 380篇 |
2019年 | 432篇 |
2018年 | 310篇 |
2017年 | 289篇 |
2016年 | 410篇 |
2015年 | 423篇 |
2014年 | 477篇 |
2013年 | 609篇 |
2012年 | 743篇 |
2011年 | 714篇 |
2010年 | 452篇 |
2009年 | 455篇 |
2008年 | 509篇 |
2007年 | 398篇 |
2006年 | 405篇 |
2005年 | 367篇 |
2004年 | 313篇 |
2003年 | 264篇 |
2002年 | 342篇 |
2001年 | 280篇 |
2000年 | 178篇 |
1999年 | 177篇 |
1998年 | 142篇 |
1997年 | 88篇 |
1996年 | 107篇 |
1995年 | 77篇 |
1994年 | 84篇 |
1993年 | 63篇 |
1992年 | 96篇 |
1991年 | 71篇 |
1990年 | 68篇 |
1989年 | 35篇 |
1988年 | 25篇 |
1987年 | 28篇 |
1986年 | 27篇 |
1985年 | 16篇 |
1984年 | 9篇 |
1983年 | 11篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1971年 | 1篇 |
1959年 | 2篇 |
1957年 | 3篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
91.
92.
Yanfeng Zhao Nengsheng Ye Rongli Zhang Xue Feng Guoan Luo Yiming Wang 《Frontiers of Chemistry in China》2007,2(4):422-427
High-resolution two-dimensional gel electrophoresis (2-DE), followed by computer-assisted image analysis was used to screen
protein patterns of normal and infarcted myocardial tissues for quantitative and qualitative differences in protein expression.
In the gels of pH 5–8 immobilized pH gradient (IPG) strips, 851 protein spots were detected in normal myocardial tissue and
1 032 protein spots were resolved in infarcted myocardial tissue. Thirteen protein spots only expressed in normal myocardial
tissue, and 14 protein spots only expressed in infarcted myocardial tissue. Results also showed that 49 protein spots displayed
quantitative changes in expression between normal and infarcted myocardial tissue. Eleven protein spots were subjected to
mass spectrometry (MS) analysis and seven proteins were identified by peptide mass fingerprinting (PMF). These proteins may
be involved in cardiovascular injury, and could play an important role in the treatment of coronary heart disease.
__________
Translated from Chemical Journal of Chinese Universities, 2006, 8(27): 1467–1471 [译自: 高等学校化学学报] 相似文献
93.
94.
Gong Y Xiang Y Yue B Xue G Bradshaw JS Lee HK Lee ML 《Journal of chromatography. A》2003,1002(1-2):63-70
Two bonded chiral stationary phases (CSPs), 8-aminoquinoline-2-ylmethyl- and 8-aminoquinoline-7-ylmethyl-diaza-18-crown-6-capped [3-(2-O-beta-cyclodextrin)-2-hydroxypropoxy]propylsilyl silica particles (non-porous, 1.5 microm), have been prepared and evaluated using capillary liquid chromatography at high pressures (> or = 8000 p.s.i.). High column efficiency (up to 400 000 plates m(-1)) was achieved for chiral separations. These CSPs with two recognition sites, i.e. substituted-diaza-18-crown-6 and beta-cyclodextrin combined with high chromatographic efficiency provide good resolution of a variety of enantiomers and positional isomers in relatively short times under reversed-phase conditions. After inclusion of a Ni (II) ion from the mobile phase, the positively charged crown ether-capped beta-cyclodextrin facilitates specific static, dipolar, and host-guest complexation interactions with solutes. 相似文献
95.
96.
There have been remarkable progresses in manipulating heterogeneous catalysts' nanostructures in the past decade. The concept of single atom alloy (SAA) was firstly proposed in 2012 when researchers successfully stabilized single Pd atoms on the Cu(111) surface. However, earlier work in 2009, which focused on replacing one Au atom with a Pd atom in thiolate protected Au25 nanoclusters, could also be considered as the pioneer work of single atom alloy. Both kinds of single atom alloys exhibited the potential of maximum utilization of scarce elements and attractive catalytic performances. The well‐defined structures of SAA catalysts make accurate modeling possible, which further realizes the rational design of single atom alloy catalysts. In this review, we summarize the research trajectory of single atom alloys as well as recent achievements in this field. We also introduce several commonly adopted characterization methods for SAA catalysts such as scanning tunneling microscopy (STM), temperature programmed reaction (TPR), extended X‐ray absorption fine structure (EXAFS) spectra, matrix assisted laser desorption/ionization mass spectrum (MALDI‐MS) and differential pulse voltammetry (DPV). Through discussing recent progresses in SAA catalysts, we propose that future researches in this filed should be focused on exploring new kinds of metal nanocrystals and controlling the nanostructure of SAA even more precisely. 相似文献
97.
用共振电离飞行时间质谱仪分析土壤中超痕量气态金 总被引:2,自引:0,他引:2
采用激光共振电离飞行时间质谱技术(简称RIS-TOF技术)对土壤中超痕量气态金的含量进行了分析研究。RIS-TOF谱仪具有极高的灵敏度和很强的选择性,避免了对样品的预富集过程。本文给出了该谱仪对金元素的检测限和65个土壤中气态金样品的分析结果,以及用中子活化法随机抽样检查的结果。 相似文献
98.
在实验室固定床反应装置上,选用Mo-Ni-P/Si-Al工业催化剂,对精煤液化中油进行了加氢裂化制取喷气燃料的实验。考察了反应温度、空速对芳烃加氢转化及产品馏分分布的影响。通过加氢裂化,降低了油品芳烃含量,提高了喷气燃料馏分的收率。在总压为15MPa,反应温度为350—360℃,空速为0.8—1.0h~(-1)条件下,获得了芳烃含量低于10w%的低结晶点的优质喷气燃料产品。并对煤液化中油制取的喷气燃料的组成和性质进行了分析和评价。 相似文献
99.
100.
流动注射化学发光法测定甲氨蝶呤 总被引:8,自引:0,他引:8
研究了甲醛增强高锰酸钾与甲氨蝶呤的化学发光反应,由此建立了一种测定甲氨蝶呤的流动性注射化学发光分析法,方法的检出限为3.4×10^-9g/mL,相对标准偏差为1.1%(2.0×10^-6g/mL甲氨蝶呤,n=11)线性范围为1.0×10^-8~1.0×10^-5g/mL。该法已用于甲氨蝶呤针剂及片剂中甲氨蝶呤含量的测定。 相似文献