全文获取类型
收费全文 | 7433篇 |
免费 | 1370篇 |
国内免费 | 1190篇 |
专业分类
化学 | 6076篇 |
晶体学 | 81篇 |
力学 | 391篇 |
综合类 | 83篇 |
数学 | 786篇 |
物理学 | 2576篇 |
出版年
2024年 | 30篇 |
2023年 | 150篇 |
2022年 | 324篇 |
2021年 | 321篇 |
2020年 | 359篇 |
2019年 | 411篇 |
2018年 | 306篇 |
2017年 | 286篇 |
2016年 | 403篇 |
2015年 | 417篇 |
2014年 | 459篇 |
2013年 | 586篇 |
2012年 | 710篇 |
2011年 | 668篇 |
2010年 | 415篇 |
2009年 | 426篇 |
2008年 | 458篇 |
2007年 | 368篇 |
2006年 | 360篇 |
2005年 | 321篇 |
2004年 | 276篇 |
2003年 | 242篇 |
2002年 | 326篇 |
2001年 | 267篇 |
2000年 | 167篇 |
1999年 | 150篇 |
1998年 | 128篇 |
1997年 | 74篇 |
1996年 | 83篇 |
1995年 | 63篇 |
1994年 | 64篇 |
1993年 | 51篇 |
1992年 | 77篇 |
1991年 | 49篇 |
1990年 | 50篇 |
1989年 | 30篇 |
1988年 | 22篇 |
1987年 | 24篇 |
1986年 | 24篇 |
1985年 | 13篇 |
1984年 | 8篇 |
1983年 | 11篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1971年 | 1篇 |
1959年 | 2篇 |
1957年 | 2篇 |
1936年 | 3篇 |
排序方式: 共有9993条查询结果,搜索用时 15 毫秒
881.
Dan Zheng Li Han Yi Jiang Yan‐Ru Cao Jiang Liu Xiu Chen Yi‐Qing Li Xue‐Shi Huang 《Magnetic resonance in chemistry : MRC》2013,51(3):188-191
Four new prenylindole derivatives, (R)‐6‐(2,3‐dihydroxy‐3‐methylbutyl)indole (1), (R)‐6‐(2,3‐dihydroxy‐3‐methylbutyl)indolin‐2‐one (2), and an unseparated mixture of (Z)‐6‐(4‐hydroxy‐3‐methylbut‐2‐en‐1‐yl)indolin‐2‐one (3a) and (E)‐6‐(4‐hydroxy‐3‐methylbut‐2‐en‐1‐yl)indolin‐2‐one (3b) with a ratio of 3 : 2, were isolated from the culture broth of a streptomycete isolated from Ailuropoda melanoleuca feces. Their structures were elucidated on the basis of 1D and 2D NMR spectroscopic techniques. The absolute configuration of 1 was determined by Mosher's method. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
882.
Dan He Zhigang Xue Mohd Yusuf Khan Seok Kyun Noh Won Seok Lyoo 《Journal of polymer science. Part A, Polymer chemistry》2010,48(1):144-151
Styrene polymerization via generation of activators by monomer addition (GAMA) for atom transfer radical polymerization (ATRP) has been examined extensively with bulk FeX3 and FeX2 at 110 °C in conjunction with various phosphorus‐bearing ligands. It was found that GAMA possesses advantages over normal ATRP. Most importantly, narrower polydispersity index (PDI) values were observed from the styrene polymerizations with Fe(III) over those with Fe(II). Every instance of 2‐(diphenylphosphino)‐N,N′‐dimethyl‐[1,1′‐biphenyl]‐2‐amine and 2‐(diphenylphosphino) pyridine with the Fe(III) system were controlled excellently without addition of any radical initiator or reducing agent additives. Initiator type was found to exert a significant factor to influence on the controllability of polymerization. The initiation of 1‐phenylethyl chloride and methyl‐2‐chloropropionate gave rise to formation of polymers with narrow PDI (1.05–1.20), whereas those from 1‐phenylethyl bromide increased to 1.35. The GAMA of bulk styrene exhibited the best performance in terms of both rate and controllability compared with toluene and anisole. Both formation of block copolymer from the macroinitiator and efficient perturbation of polymerization with 2,2,6,6‐tetramethylpiperidine 1‐oxyl provided firm evidence to support the living and radical characteristics for the GAMA of styrene. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 144–151, 2010 相似文献
883.
This paper is concerned with the decay of Saint-Venant end effects for plane deformations of piezoelectric (PE)-piezomagnetic (PM) sandwich structures, where a PM layer is located between two PE layers with the same material properties or reversely. The end of the sandwich structure is subjected to a set of self-equilibrated magneto-electro-elastic loads. The upper and lower surfaces of the sandwich structure axe mechanically free, electrically open or shorted as well as magnetically open or shorted. Firstly the constitutive equations of PE mate- rials and PM materials for plane strain are given and normalized. Secondly, the simplified state space approach is employed to arrange the constitutive equations into differential equations in a matrix form. Finally, by using the transfer matrix method, the characteristic equations for eigen- values or decay rates axe derived. Based on the obtained characteristic equations, the decay rates for the PE-PM-PE and PM-PE-PM sandwich structures are calculated. The influences of the electromagnetic boundary conditions, material properties of PE layers and volume fraction on the decay rates are discussed in detail. 相似文献
884.
885.
886.
887.
The thermal decomposition behavior of double‐base rocket propellant SQ‐2 was studied by a Calvet microcalorimeter at four different heating rates. The kinetic and thermodynamic parameters were obtained from the analysis of the heat flow curves. The critical temperature of thermal explosion (Tb), the self acceleration decomposition temperature (TSADT), the adiabatic decomposition temperature rise (ΔTad), the time‐to‐explosion of adiabatic system (t), critical temperature of hot‐spot initiation (Tcr), critical thermal explosion ambient temperature (Tacr), safety degree (SD) and thermal explosive probability (PTE) were presented to evaluate the thermal hazard of SQ‐2. 相似文献
888.
Inorganic layered materials are a class of advanced functional materials that have attracted considerable attention by virtue of their practical applications in a wide variety of fields. Sys-tematic studies of structure, design, synthesis, and fabrication processing may extend the range of practical utility of inor-ganic layered functional materials, in areas such as food industry,chemical industry, energy engineering, environmental engineer-ing, drug and gene delivery, electronics technology, and materials protection. 相似文献
889.
Yan Ling ZHANG Wei Sheng LIU Yang LI Xue Yi MA* Yao Zu CHEN National Laboratory of Applied Organic Chemistry Department of Chemistry Lanzhou University Lanzhou Department of Chemistry Zhejiang University Hangzhou 《中国化学快报》2001,(4)
The importance of Vitamin A for human health has been stressed in resent studies1, meanwhile its derivative so-called retinoic acid (RA) has been widely used as pharmaceutical to treat several types of skin disease and cancer2,3. However the application of retinoic acid is restrained for its poor water solubility, unstability and side effect on the human body.Cyclodextrins (CDs) are macrocyclic oligosaccharides built up from 6, 7, or 8 glucopyranose units called (, (, and (-CD, respectively… 相似文献
890.
F. Pan M.-X. Xie J.-J. Lin X.-G. Xue J. P. Draayer 《The European Physical Journal B - Condensed Matter and Complex Systems》2009,72(4):479-484
The one-dimensional t-J
model Hamiltonian is realized by using hard-core boson operators. A
simple algorithm written in Mathematica based on a differential
realization of the hard-core bosons for finding exact solutions of
the model is proposed. As a simple example, some low-lying
excitation energies, the inverse compressibility, and the
superconducting structure factors, as well as the particle and spin
entanglement of a system with 8 sites are calculated. The results
not only confirm the validity of the hard-core boson picture, but
also indicate that a quantum phase transition near phase-separation
at zero temperature can also be recognized by the particle and spin
entanglement. 相似文献