利用场发射显微镜研究O2对单壁碳纳米管场发射的影响

利用场发射显微镜和四极质谱计研究了充入高纯O2的四极质谱和O2对单壁碳纳米管场发射的影响.单壁碳纳米管经过约1000℃的热处理得到清洁态场发射像后，充入O2，分别测量了O2吸附和脱附后场发射的I V特性.实验观测到在单壁碳纳米管上O2的吸附使场发射电流减小，说明逸出功增加.在10-4Pa的O2压强下对单壁碳纳米管进行约1000℃的热处理，可以产生氧化刻蚀作用，观测到场发射像的变化，并测量了氧化刻蚀产生的I V特性变化. 关键词： 单壁碳纳米管 场发射显微镜 场发射 四极质谱     

Isolation and On‐Line LC/CD Analysis of 3,8″‐Linked Biflavonoids from Gnidia involucrata

Investigation of the methanol extract of the roots of Gnidia involucrata (Thymelaeaceae) led to the isolation and characterization of two new 3,8″‐biflavonoid diastereoisomers, named GB‐4 ( 6a ) and GB‐4a ( 6b ). Their absolute configurations were determined in mixture by on‐line LC/CD measurements, which also allowed the revision of absolute configurations of the biflavanoids GB‐1 and GB‐2, and the configurational assignment of GB‐3.     

在PowerPoint演示文稿中轻松插入Flash动画

用PowerPoint制作出的幻灯片简洁明快、条理清晰,而且PowerPoint简单易用,非常适合教师上课使用,成为教师制作多媒体课件的工具之一(在我校大部分教师采用PowerPoint制作多媒体课件).在制作多媒体课件过程中,结合适当的媒体技术(动画、声音、文字)不仅能提高课件的直观生动性,激发学生学习兴趣,同时有助于学生对课堂知识的当堂消化和理解,加深记忆.通过我校开展多媒体教学多年的实践发现:对医科学生的基础课、专业基础课和专业课教学中广泛涉及的机能性、原理性的知识适当采用动画其教学效果是传统教学方法无法比拟的.在众多的动画媒体中(avi、mov、mpg、swf、gif、ram等),Flash动画(swf文件)以其作品容量小(单个swf文件通常不到100 K)、质量高和丰富的交互性,特别是近年推出的Flash5同时能结合视频和音频,成为目前最为流行的二维动画.不仅为网页制作增添了活力,同时也为多媒体制作提供了有效的手段,既精巧又实用,素有"闪客"、"动画精灵"之美誉,越来越受到人们的青睐.如果要把Flash制作好的动画插入到PowerPoint制作的课件中,将会使PowerPoint单调的动画增色不少,使课件更具魅力.为此,我校专门开展了一系列Flash动画制作讲座,广大教师都能结合本专业制作Flash动画.如何将Flash动画加入到PowerPoint中,不少教师都是直接通过"超级连接"导入Flash课件,放映时总会出现讨厌的警告信息和警告声音提示,点击确定后打开Flash课件,有时打开的Flash课件窗口还要重新调整,使用十分不便.如何才能更恰当地引入Flash动画呢?不少杂志刊物和网上发表过类似文章,但大都比较复杂,而且在使用中特别是在PowerPoint中放映Flash动画偶尔会出现这样和那样的问题,这也是我们教学工作中经常遇到的问题,具有一定的普遍性.经过与教师们的众多交流和笔者平时反复摸索,找到了较为简便有效的方法,写出来与大家分享.     

Facile modifications of a polyimide via chloromethylation. I. Novel synthesis of a new photosensitive polyimide

A soluble aromatic polyimide was chloromethylated via a reaction with chloromethyl methyl ether in the presence of tin(IV) chloride to produce a new starting material for the modification of aromatic polyimides. The chemical structure of the resulting polymer was confirmed by ¹H NMR and Fourier transform infrared spectroscopy. The maximum number of chloromethyl groups per repeat unit was 1.81. The chloromethylated polyimide was stable up to 250 °C and soluble in both chloroform and tetrahydrofuran. So that its utilization for further modification could be demonstrated, cinnamic acid was reacted with the formed polyimide, and it produced a new photosensitive polyimide with a cinnamoyl side chain. The photosensitivity of the resulting polyimide was investigated with ultraviolet spectroscopic methods. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 22–29, 2003     

Cauchy problems for linear thermoelastic systems of type III in one space variable

The goal of the paper is to analyse properties of solutions for linear thermoelastic systems of type III in one space variable. Our approach does not use energy methods, it bases on a special diagonalization procedure which is different in different parts of the phase space. This procedure allows to derive explicit representations of solutions. These representations help to prove results for well‐posedness of the Cauchy problem, L^P–L^q decay estimates on the conjugate line and results for propagation of singularities. Copyright © 2005 John Wiley & Sons, Ltd.     

D. Liu and X. Zhu,Erratum to: “Fractional chromatic number and circular chromatic number for distance graphs with large clique size”. Journal of Graph Theory47(2) 2004, 129–146

The original article to which this Erratum refers was published in Journal of Graph Theory 47:129–146,2004 .     

Computations of two passing‐by high‐speed trains by a relaxation overset‐grid algorithm

This paper presents a relaxation algorithm, which is based on the overset grid technology, an unsteady three‐dimensional Navier–Stokes flow solver, and an inner‐ and outer‐relaxation method, for simulation of the unsteady flows of moving high‐speed trains. The flow solutions on the overlapped grids can be accurately updated by introducing a grid tracking technique and the inner‐ and outer‐relaxation method. To evaluate the capability and solution accuracy of the present algorithm, the computational static pressure distribution of a single stationary TGV high‐speed train inside a long tunnel is investigated numerically, and is compared with the experimental data from low‐speed wind tunnel test. Further, the unsteady flows of two TGV high‐speed trains passing by each other inside a long tunnel and at the tunnel entrance are simulated. A series of time histories of pressure distributions and aerodynamic loads acting on the train and tunnel surfaces are depicted for detailed discussions. Copyright © 2004 John Wiley & Sons, Ltd.     

Least‐squares meshfree method for incompressible Navier–Stokes problems

A least‐squares meshfree method based on the first‐order velocity–pressure–vorticity formulation for two‐dimensional incompressible Navier–Stokes problem is presented. The convective term is linearized by successive substitution or Newton's method. The discretization of all governing equations is implemented by the least‐squares method. Equal‐order moving least‐squares approximation is employed with Gauss quadrature in the background cells. The boundary conditions are enforced by the penalty method. The matrix‐free element‐by‐element Jacobi preconditioned conjugate method is applied to solve the discretized linear systems. Cavity flow for steady Navier–Stokes problem and the flow over a square obstacle for time‐dependent Navier–Stokes problem are investigated for the presented least‐squares meshfree method. The effects of inaccurate integration on the accuracy of the solution are investigated. Copyright © 2004 John Wiley & Sons, Ltd.