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911.
912.
Jingquan Sha Lin Huang Jun Peng Haijun Pang Aixiang Tian Pengpeng Zhang Yuan Chen Min Zhu 《Solid State Sciences》2009,11(2):417-421
Two novel polyoxometalate(POM)-templated coordination polymers: [Cu2(phnz)3][M6O19] (M = Mo for 1, W for 2; phnz = phenazine), have been hydrothermally synthesized and characterized by routine physical methods and single crystal X-ray diffraction. In the compounds, Lindqvist POMs as templates induce the [Cu2(phnz)3] complexes to 2D hexagonal metal-organic framework (MOF), which represents 63 topologies of dimensions ca. 13.515 × 13.515 × 13.515 Å. Furthermore, the 2D sheets are held together by Lindqvist POMs into 3D supramolecular networks with 1D channel, and Lindqvist POMs site in the channels. The successful syntheses and isolation of two compounds provide a novel example of the utility of POM clusters as templates for self-assembly extended framework with cavities. 相似文献
913.
In this work Bi(SbxNbyTaz)O4 (x + y + z = 1) samples are prepared using mixed-oxide method. A pseudo-ternary phase diagram of Bi(Sb,Nb,Ta)O4 system is given below the melting point. It is composed of a monoclinic phase region, an orthorhombic phase region and a monoclinic–orthorhombic co-existing phase region. In the orthorhombic phase region, the transformation from orthorhombic to triclinic phase is found to be sensitive to the composition and sintering temperature. Both the transformation from monoclinic to orthorhombic structure and the transformation from orthorhombic to triclinic structure have been studied by the cell parameters. 相似文献
914.
Li WY Chen XF Xuan CS 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,71(5):1769-1775
A spectrofluorimetric method was discussed for the determination of three antibacterial quinolone derivatives, ofloxacin (OFL), norfloxacin (NOR) and ciprofloxacin (CIP) through charge-transfer complexation (CTC) with 2,3,5,6-tetrabromo-1,4-benzoquinone (bromanil, TBBQ). The method was based on the reaction of these drugs as n-electron donors with the pi-acceptor TBBQ. TBBQ was found to react with these drugs to produce a kind of yellow complexes and the fluorescence intensities of the complexes were enhanced by 29-36 times more than those of the corresponding monomers. UV-vis, (1)H NMR and XPS techniques were used to study the complexes formed. The various experimental parameters affecting the fluorescence intensity were studied and optimized. Under optimal reaction conditions, the rectilinear calibration graphs were obtained in the concentration range of 0.021-2.42 microg mL(-1), 0.017-2.63 microg mL(-1) and 0.019-2.14 microg mL(-1) for OFL, NOR and CIP, respectively. The methods developed were applied successfully to the determination of the subject drugs in their pharmaceutical dosage forms with good precision and accuracy compared to official and reported methods as revealed by t- and F-tests. 相似文献
915.
Bin Liu Xiaolong Wang Lei Lin Qiwen Dong Xuan Wang 《Computational Biology and Chemistry》2009,33(4):303-311
Predicting the binding sites between two interacting proteins provides important clues to the function of a protein. In this study, we present a building block of proteins called order profiles to use the evolutionary information of the protein sequence frequency profiles and apply this building block to produce a class of propensities called order profile interface propensities. For comparisons, we revisit the usage of residue interface propensities and binary profile interface propensities for protein binding site prediction. Each kind of propensities combined with sequence profiles and accessible surface areas are inputted into SVM. When tested on four types of complexes (hetero-permanent complexes, hetero-transient complexes, homo-permanent complexes and homo-transient complexes), experimental results show that the order profile interface propensities are better than residue interface propensities and binary profile interface propensities. Therefore, order profile is a suitable profile-level building block of the protein sequences and can be widely used in many tasks of computational biology, such as the sequence alignment, the prediction of domain boundary, the designation of knowledge-based potentials and the protein remote homology detection. 相似文献
916.
本文基于两个非线性逼近逆的非线性Uzawa方法,给出了一种新的修正非线性Uzawa方法,并对其收敛性进行了分析以及与已有算法的收敛性进行了比较.最后由数值试验说明了算法的正确性和有效性. 相似文献
917.
We establish many-server heavy-traffic limits for G/M/n+M queueing models, allowing customer abandonment (the +M), subject to exogenous regenerative service interruptions. With unscaled service interruption times, we obtain a FWLLN for the queue-length process, where the limit is an ordinary differential equation in a two-state random environment. With asymptotically negligible service interruptions, we obtain a FCLT for the queue-length process, where the limit is characterized as the pathwise unique solution to a stochastic integral equation with jumps. When the arrivals are renewal and the interruption cycle time is exponential, the limit is a Markov process, being a jump-diffusion process in the QED regime and an O–U process driven by a Levy process in the ED regime (and for infinite-server queues). A stochastic-decomposition property of the steady-state distribution of the limit process in the ED regime (and for infinite-server queues) is obtained. 相似文献
918.
919.
920.
为了求解随机整数规划问题,提出了随机整数规划期望值模型的概念,分析了利用DNA遗传算法求解此类问题的优点,并设计了求解算法,最后通过报童问题,验证了算法的可行性和有效性. 相似文献