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41.
42.
Yaochen Zheng Jian Liu Yan Guo Qian Zhang Xuan Gao Zhengguo Gao Tao He Qingfu Ban 《Journal of polymer science. Part A, Polymer chemistry》2020,58(12):1664-1674
Cationic compounds often serve as antibacterial materials for a wide range of applications. However, the relationship of topology−antibacterial activity has been rarely revealed. Herein, three cationic polythioethers (CPTEs) with hyperbranched topologies are well designed and facilely synthesized via an all-click chemistry strategy (including thiol-ene and epoxy-amine additions). These as-prepared CPTEs were found to exhibited outstanding antibacterial activity against Escherichia coli and Staphylococcus aureus with minimum inhibitory concentrations against E. coli of 7.3, 14.6, and 14.6 μg ml−1, and against S. aureus of 14.6, 29.2, and 29.2 μg ml−1, respectively. The antibacterial activity is coincident with their degree of branching (DB, their DB values of 0.81, 0.48, and 0.27), which is mainly attributed to the inherent three-dimensional structure. The present strategy reveals the relationship of polymer topology and antibacterial activity, providing a novel possibility for designing and/or synthesis of high-efficiency antibacterial agents. 相似文献
43.
Copper(I) catalyzed radical benzylation and cyclization reaction of tertiary enamides was investigated and 3,3-disubstituted N-Alkyl isoindolin-1-ones were obtained in moderate to good yields. In this reaction, two new C–C bonds were formed in one step with high atom economy. Possible reaction pathway for the formation of the products was also discussed in this paper. 相似文献
44.
Rotational viscosity of a liquid crystal mixture: a fully atomistic molecular dynamics study 下载免费PDF全文
Fully atomistic molecular dynamics (MD) simulations at 293, 303 and
313~K have been performed for the four-component liquid crystal
mixture, E7, using the software package Material Studio. Order
parameters and orientational time correlation functions (TCFs) were
calculated from MD trajectories. The rotational viscosity
coefficients (RVCs) of the mixture were calculated using the
Nemtsov--Zakharov and Fialkowski methods based on
statistical-mechanical approaches. Temperature dependences of RVC
and density were discussed in detail. Reasonable agreement between
the simulated and experimental values was found. 相似文献
45.
Xuan Chuan Cao 《International Journal of Theoretical Physics》1997,36(6):1465-1474
It is shown that, starting from an exactly solvable potential and making use of the theory of a system of coupled differential
equations, it is possible to construct a new type of second-generation potential which is also exactly solvable. 相似文献
46.
Shangqing Li Jinglong Ma Xiaojun Wu Baolong Zhang Chen Ouyang Tianze Wang Dan Wang Xuan Wang Yutong Li 《中国光学快报(英文版)》2021,(5):60-64
We propose a spatial diffraction diagnostic method via inserting a millimeter-gap double slit into the collimated terahertz beam to monitor the minute variation of the terahertz beam in strong-field terahertz sources, which is difficult to be resolved in conventional terahertz imaging systems. To verify the method, we intentionally fabricate tiny variations of the terahertz beam through tuning the iris for the infrared pumping beam before the tilted-pulse-front pumping setups.The phenomena can be well explained by the theory based on the tilted-pulse-front technique and terahertz diffraction. 相似文献
47.
甲状腺内^(131)I放射性活度与辐射探测结果的比例关系与甲状腺几何尺寸、探测距离等因素相关,是估算甲状腺内^(131)I含量与其可能造成的辐照损伤的关键参数。基于MCPT辐射输运数值模拟算法器库开发了用于开展NaI探测器伽马辐射测量模拟的应用程序,进而建立了多组具有不同容积的甲状腺型容器和不同探测距离的物理模型,最终通过蒙特卡罗数值计算得到了不同测量状态下探测器的探测效率。在甲状腺型容器与探测器距离较远时,数值模拟给出的结果与理论计算结果一致,证明此应用程序可用于定量分析NaI的探测效率。数值模拟结果表明,小距离模型的结果受甲状腺样容器的大小和距离的显著影响,模拟给出的探测效率表为开展深入细致的实验研究奠定了基础。 相似文献
48.
We are concerned with the Cauchy problem of the quantum Landau equation in the whole space. The existence of local in time nearby quantum Maxwellian solutions is proved by the iteration method and generalized maximum principle. Based on Kawashima?s compensating function and nonlinear energy estimates, the global existence and the optimal time decay rate of those solutions are obtained under some conditions on initial data. 相似文献
49.
Zhiguo Wang Zhixing Wang Wenjie Peng Huajun Guo Xinhai Li Jiexi Wang Ai Qi 《Ionics》2014,20(11):1525-1534
LiCoO2 sample prepared by high-temperature solid state calcination shows a typical hexagonal structure with a single phase and fine particle size distribution. The high-voltage electrolyte with additive fluoroethylene carbonate (FEC) has been used. Electrochemical results show that the initial discharge capacities of the prepared LiCoO2 cathode are 157.7, 169.5, 191.0, and 217.5 mAh g?1 in the voltage ranges of 3.0–4.3, 3.0–4.4, 3.0–4.5, and 3.0–4.6 V, respectively. The capacity increases, while the initial coulombic efficiency and capacity retention decrease with increasing the charge cutoff voltage. The capacity retention is only 10.4 % after 200 cycles at 1C rate in the voltage range of 3.0–4.6 V. X-ray diffraction measurements confirm structural changes of the layered material in the different voltage ranges. A phase transition from the O3 to the H1-3 phase can be observed when LiCoO2 is charged above 4.5 V. The AC impedance analysis indicates that the resistances (R (sf+b), R ct) of the prepared LiCoO2 rapidly increase when the cell is charged to higher voltage. The amount of dissolved Co into the electrolyte also greatly increases with increasing the charge cutoff voltage. 相似文献
50.
Nanocrystalline cobalt ferrites were synthesized by a simple, general, one-step sol–gel auto-combustion method. An interpretation based on the measurement of the adiabatic flame temperature and the amounts of gas evolved during reaction had been proposed for the nature of combustion. The influence of annealing temperatures on the magnetic properties was investigated. The microstructure was characterized by means of X-ray diffractometer (XRD) and transmission electron microscopy (TEM). It was found that the particle size and magnetic properties of the as-prepared ferrite samples showed strong dependence on the annealing temperature. The coercivity initially increased and then decreased with increasing annealing temperature whereas the particle size and saturation magnetization continuously increased. 相似文献