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71.
Celik Tarimci Anda? Karamustafa Kutalmi? Güven Mehmet Kabak Akgül Ye?ilada 《Analytical sciences》2003,19(9):1347-1348
The crystal structure of 1-[3-(3,4-dimethoxyphenyl)-2-propenoyl]pyrrolidine (C15H19NO3) (I) has been determined by X-ray analysis. It crystallizes orthorhombic space group Pbca with a = 24.295(3), b = 15.086(3), c = 7.552(3)A, V = 2768(1)A3, Z = 8, Dcalc = 1.254 g/cm3, mu = (Mo K(alpha)) = 0.87 cm(-1). The title compound has analgesic activity of cycloaliphatic amine part. The molecule is deviated from planar configuration. 相似文献
72.
强色指数的一个新的上界 总被引:1,自引:0,他引:1
给出了图的强色指数的一个新的上界,并指出几类恰好达到该上界的图,从而改进了Erodoes和Nesetri的强色指数猜想,在某种意义上证明了这个猜想。 相似文献
73.
为了更好地理解和应用样本分位数的极限分布,利用Slutsky定理,推导了样本分位数的极限分布. 相似文献
74.
薛儒英 《浙江大学学报(理学版)》1991,(2)
本文讨论了半线性椭圆方程△u+f(u)=0在三种边界条件下正解的存在性和唯一性,给出了正解存在和唯一的一些条件. 相似文献
75.
We introduce and investigate the properties of Hochschild cohomology of algebras in an abelian monoidal category M. We show that the second Hochschild cohomology group of an algebra in M classifies extensions of A up to an equivalence. We characterize algebras of Hochschild dimension 0 (separable algebras), and of Hochschild dimension ≤1 (formally smooth algebras). Several particular cases and applications are included in the last section of the paper. 相似文献
76.
Weimin Xue 《中国科学A辑(英文版)》1997,40(7):673-679
A ringR is left co-semihereditary (strongly left co-semihereditary) if every finitely cogenerated factor of a finitely cogenerated
(arbitrary) injective leftR-module is injective. A left co-semihereditary ring, which is not strongly left co-semihereditary, is given to answer a question
of Miller and Tumidge in the negative. If
R
U
S
defines a Morita duality,R is proved to be left co-semihereditary (left semihereditmy) if and only ifS is right semihereditary (right co-semihereditary). Assuming thatS⩾R is an almost excellent extension,S is shown to be (strongly) right co-semihereditary if and only ifR is (strongly) right co-semihereditary.
Project supported by the National Natural Science Foundation of China. 相似文献
77.
Protein Conformation of a Lattice Model Using Tabu Search 总被引:1,自引:0,他引:1
We apply tabu search techniques to the problem of determining the optimal configuration of a chain of protein sequences on a cubic lattice. The problem under study is difficult to solve because of the large number of possible conformations and enormous amount of computations required. Tabu search is an iterative heuristic procedure which has been shown to be a remarkably effective method for solving combinatorial optimization problems. In this paper, an algorithm is designed for the cubic lattice model using tabu search. The algorithm has been tested on a chain of 27 monomers. Computational results show that our method outperforms previously reported approaches for the same model. 相似文献
78.
C. B?uerle Yu M. Bunkov S. N. Fisher H. Godfrin G. R. Pickett 《Czechoslovak Journal of Physics》1996,46(Z1):5-6
During studies of the impact of single neutrons on superfluid3He at around 100μK we have measured the thermal energy released in the superfluid following the nuclear reaction, n+3He→p+3H+764keV. However, we find that the measured energy deposited in the quasiparticle system shortly after this reaction is substantially
less than what we expect. We believe that this energy deficit represents that energy which has gone into the creation of vortices,
in analogy to the creation of cosmic strings in the early universe via the Kibble mechanism. Furthermore, from the magnitude
of the deficit, we can infer the vortex density which compares favorably with that predicted in Zurek’s scenairo. 相似文献
79.
P E S?rensen R A McClelland R D Gandour 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(6):558-566
The ring-chain tautomerism in aqueous solution of some aryl-substituted morpholinium salts (bromides), has been studied and equilibrium constants are reported. In the crystals the substrates exist entirely in their cyclic forms as hemiacetals, but in aqueous solution NMR measurements reveal that an equilibrium is established between the cyclic (hemiacetal) and the noncyclic (ketone) form, the degree of ring-opening being more pronounced with electron-donating aryl substituents at the carbonyl carbon. The kinetics of the ring-chain interconversion in water has been investigated spectrophotometrically by a 'pH jump' stopped-flow technique. General base catalysis is observed with a Br?nsted beta value apparently independent of substituent and equal to 0.60. The Hammett rho values for various base catalysts are close to those for very similar intermolecular reactions involving hemiacetal breakdown, leading to the suggestion of a 'normal' class n mechanism for base catalysis. For acid catalysis, however, a quite different situation is encountered, since no general acid but only (weak) catalysis by the hydronium ion can be detected. We believe this deviation from 'normal' general acid catalysis is caused by an electrostatic interaction, and we suggest that it might result from a change in the usual class e mechanism for general acid catalysis by a situation in which rate-limiting concerted proton transfer is replaced by rate-limiting preprotonation. This is supported by the observed drastic change in Hammett rho value for catalysis by the hydronium ion, compared with the 'normal' case. An interesting case is encountered for the 4-aminophenyl-substituted substrate, in which the amino group becomes protonated in acid solution, thus representing a new substituent. Despite this complication, the various equilibrium and rate constants may also be evaluated experimentally for this substrate. 相似文献
80.
P Nürnberg I Barth E Fuhrmann C Lenzner T Losanova C Peters H P?che G Thiel 《Electrophoresis》1991,12(2-3):186-192
Germline and somatic instability of the human genome was studied, using synthetic oligonucleotides specific for simple repeat motifs. The following probes were used: (GTG)5, (GACA)4, (GATA)4, (CT)8, (TTAGGG)3, (GT)8, (GAA)6 and (GGAT)4. Each of them is unique with respect to the target regions recognized in the genome. Thus compilation of the various fingerprint data provides a complex map of the genome (and its deviations). While the fingerprints of differentiated somatic tissues never showed any alterations, in tumor tissues (namely gliomas) many changes could be detected. Most of the latter reflect secondary karyological aberrations. In nearly one third of the gliomas, drastically amplified and apparently monomorphic DNA fragments were identified. This marker should make it possible to deal with causal pathogenetic mechanisms as well as novel diagnostic strategies. 相似文献