全文获取类型
收费全文 | 51371篇 |
免费 | 9030篇 |
国内免费 | 6208篇 |
专业分类
化学 | 36672篇 |
晶体学 | 665篇 |
力学 | 3190篇 |
综合类 | 443篇 |
数学 | 5995篇 |
物理学 | 19644篇 |
出版年
2024年 | 183篇 |
2023年 | 1040篇 |
2022年 | 1737篇 |
2021年 | 1742篇 |
2020年 | 2079篇 |
2019年 | 2076篇 |
2018年 | 1750篇 |
2017年 | 1586篇 |
2016年 | 2484篇 |
2015年 | 2482篇 |
2014年 | 2941篇 |
2013年 | 3662篇 |
2012年 | 4464篇 |
2011年 | 4542篇 |
2010年 | 3178篇 |
2009年 | 3071篇 |
2008年 | 3367篇 |
2007年 | 3010篇 |
2006年 | 2789篇 |
2005年 | 2272篇 |
2004年 | 1858篇 |
2003年 | 1662篇 |
2002年 | 1695篇 |
2001年 | 1429篇 |
2000年 | 1231篇 |
1999年 | 1148篇 |
1998年 | 918篇 |
1997年 | 843篇 |
1996年 | 819篇 |
1995年 | 742篇 |
1994年 | 616篇 |
1993年 | 500篇 |
1992年 | 504篇 |
1991年 | 413篇 |
1990年 | 376篇 |
1989年 | 279篇 |
1988年 | 235篇 |
1987年 | 192篇 |
1986年 | 178篇 |
1985年 | 175篇 |
1984年 | 122篇 |
1983年 | 79篇 |
1982年 | 62篇 |
1981年 | 38篇 |
1980年 | 17篇 |
1979年 | 12篇 |
1977年 | 2篇 |
1959年 | 2篇 |
1957年 | 3篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
Recent breakthrough in synthesizing arbitrary vertical heterostructures of Ruddlesden–Popper (RP) perovskites opens doors to myriad quantum optoelectronic applications. However, it is not clear whether moiré excitons and flat bands can be formed in such heterostructures. Here, we predict from first principles that twisted homobilayers of RP perovskite, MA2PbI4, can host moiré excitons and yield flat energy bands. The moiré excitons exhibit unique and hybridized characteristics with electrons confined in a single layer of a striped distribution while holes localized in both layers. Nearly flat valence bands can be formed in the bilayers with relatively large twist angles, thanks to the presence of hydrogen bonds that strengthen the interlayer coupling. External pressures can further increase the interlayer coupling, yielding more localized moiré excitons and flatter valence bands. Finally, electrostatic gating is predicted to tune the degree of hybridization, energy, position and localization of moiré excitons in twisted MA2PbI4 bilayers.Excitonic states in twisted MA2PbI4 bilayers were calculated by first-principles calculations. 相似文献
992.
993.
994.
On the Criteria of Instability for Electrochemical Systems 总被引:7,自引:0,他引:7
Both cyclic-voltammetry-based and impedance-based experimental criteria that have been developed recently for the oscillatory electrochemical systems are critically appraised with two typical categories of oscillators.Consistent conclusions can be drawn by the two criteria for the category of oscillators that involve the coupling of charge transfer mainly with surface steps(e.g.ad-and desorption)such as in the electrooxidation of C1 organic molecules.Whereas,impedance-based criterion is not applicable to the category of oscillators that involve the coupling of charge transfer mainly with mass transfer(e.g.diffusion and convection) such as in the Fe(CN)6^3- reduction accompanying periodic hydrogen evolution.The reason is that the negative impedance cannot include the feedback information of convection mass transfer induced by the hydrogen evolution.However,both positive and negative nonlinear feedbacks,i.e., the diffusion-limited depletion and convection-enhanced replenishment of the Fe(CN)6^3- surface concentration,that coexist between the bistability,i.e.,Fe(CN)6^3- reduction with and without hydrogen evolution at lower and higher potential sides respectively,are all reflected in the crossed cyclic voltammogram(CCV).It can be concluded that the voltammetry-based criterion(in time domain)is more intuitive,less time-consuming and has a wider range of applications than the impedancebased one (in frequency domain). 相似文献
995.
This paper focuses on the thermal degradation behavior of multi-walled carbon nanotubes (MWNTs)/polyamide 6 (PA6) composites under air and nitrogen atmosphere using thermogravimetric analysis (TGA). The results show that the dispersion of amino-functionalized MWNTs (f-MWNTs) in PA6 is more homogeneous than purified MWNTs (p-MWNTs). The presence of MWNTs improves the thermal stability of PA6 under air obviously, but has little effect on the thermal degradation behavior of PA6 under nitrogen atmosphere. The activation energies for degradation under air, Ea, estimated by Kissinger method, are 153, 165 and 169 kJ/mol for neat PA6, p-MWNTs/PA6 and f-MWNTs/PA6 composites, respectively. The p-MWNTs/PA6 composites show two-step degradation not only under air but also under nitrogen atmosphere, however, neat PA6 and the f-MWNTs/PA6 composites exhibit two-step degradation only under air. 相似文献
996.
将766例厌食患儿发中元素含量与对照组比较,发Zn、Ca、Cu含量明显低于对照组,而Fe、Pb含量婴幼儿明显高于对照组,提示Zn、Ca等营养元素缺乏引起的体内元素代谢紊乱可能是厌食的病因,同时发现喂养不当和不良饮食习惯也是厌食的重要原因,提示学龄前儿童是厌食的好发年龄。 相似文献
997.
高水相W/O型乳化膏体油膜稳定性的研究 总被引:3,自引:0,他引:3
高水相W/O型乳液是指水相体积占74%以上,属于高度不稳定的分散体系[1,2].乳化炸药的问世,使这种高水相W/O型乳液有了新的实际应用.这种炸药是90%~95%重的硝酸铵盐(占水相80%~90%重)水溶液高度分散在5%~10%的油相中构成W/O型乳... 相似文献
998.
Jun Zhao Shu Hong Guan Xiao Bin Chen Wei Wang Min Ye De An Guo 《中国化学快报》2007,18(11):1316-1318
The biotransformation of bufalin by cell suspension cultures of Platycodon grandiflorus was investigated and two new biotransformed products were obtained,which was 3-epi-telocinobufagin and 3-epi-bufalin-3-O-β-D-glucoside. 相似文献
999.
Katritzky AR Xu YJ Vakulenko AV Wilcox AL Bley KR 《The Journal of organic chemistry》2003,68(23):9100-9104
Molecules were prepared with substituted nitrobenzyl groups covalently bonded to N-(4-hydroxy-3-methoxybenzyl)acetamide (2) by ether or carbonate linkages. These compounds decomposed under irradiation at 363 nm. Those with carbonate linkages decomposed at slower rates than those with ether linkages. Molecules with dimethoxy-substituted benzyl groups decomposed more slowly than monomethoxy-substituted benzyl groups due to the electronic characteristics of the benzylic carbon. 相似文献
1000.
含聚醚间隔链的扩链脲改性环氧树脂/双氰双胺固化体系性能研究 总被引:1,自引:0,他引:1
合成了一系列含不同分子量聚环氧丙烷 (PPG)柔性间隔链的扩链脲 ,系统考察了扩链脲改性环氧树脂E 5 1/双氰双胺 (dicy)固化体系的固化反应活性、动态力学行为、冲击性能和断裂面形态结构 ,并对体系的冲击性能、形态结构与动态力学行为之间的关系进行了探讨 .结果表明 ,改性体系固化反应活性明显提高 ,固化反应表观活化能降低 ,固化反应峰顶温度从 190℃降低至 14 0℃ ,固化反应的表观活化能由 14 5 5kJ/mol降至 70~ 80kJ mol;改性体系冲击强度明显提高 ,其中所含PPG柔性链分子量为 10 0 0的扩链脲改性的E 5 1/dicy体系冲击强度较未改性的E 5 1/dicy体系提高了 8倍 ,其冲击试样断裂面的形态具有明显的韧性断裂特征 ,微观两相网络结构的存在导致了改性体系冲击强度显著提高 相似文献