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991.
Stir-heating is a common method to process Gardenia jasminoides Ellis. The processing of the G. jasminoides Ellis which do not meet the regulated requirements can result in the unqualified products, finally decreasing the efficacy of the drug. To guarantee the quality of the stir-baked G. jasminoides Ellis, a rapid and efficient method to discriminate the qualified stir-baked G. jasminoides Ellis from the unqualified was developed based on the middle level data fusion. 61 batches of qualified and unqualified stir-baked G. jasminoides Ellis were collected and analyzed using colorimeter and near-infrared spectroscopy, separately. L*, A*, and B* were apparent features that quantitatively described the characteristics of samples. The latent variables of partial least squares discriminant analysis model were extracted as the features of near-infrared spectroscopy. The extracted features from colorimeter and near-infrared spectroscopy were fused and a discriminant model was built using partial least squares discriminant analysis method. Accuracy, sensitivity, and specificity were used to evaluate the ability of classification. As a result, the accuracy, sensitivity, and specificity of the optimal partial least squares discriminant analysis model based on fused data were all equal to 1. It demonstrated that the developed method can be capable of discriminating the qualified stir-baked G. jasminoides Ellis from the unqualified. Compared with classification model results using color parameters or near infrared data alone, this data fusion strategy greatly improved the accuracy of classification. 相似文献
992.
Highly oriented self-reinforced 80/20 blends of polylactide (PLA)/thermoplastic polyurethane elastomer (TPU) were successfully fabricated through solid hot stretching technology. Different from the isotropic sample, stress rose rapidly in a low strain region, and exhibited strain hardening for the drawn samples of the PLA/TPU blend. Superior mechanical properties of the blend, with the notched Charpy impact strength 150 KJ/m2, and tensile strength 197 MPa, were achieved. With increasing hot stretch ratio, the storage modulus increased, the glass transition temperatures of the PLA-rich phase and TPU-rich phase in the blends moved to higher temperatures, and the melting temperature and crystallinity of the blend increased, indicating the stress-induced crystallization of the blend during drawing. The longitudinal fracture surfaces of the blends at different stretch ratios exhibited orderly arranged fibrillar bundle structure, which contributed to the significantly higher strength and toughness of the blend. 相似文献
993.
In this paper, we present two higher-order compact finite difference schemes for solving one-dimensional (1D) heat conduction equations with Dirichlet and Neumann boundary conditions, respectively. In particular, we delicately adjust the location of the interior grid point that is next to the boundary so that the Dirichlet or Neumann boundary condition can be applied directly without discretization, and at the same time, the fifth or sixth-order compact finite difference approximations at the grid point can be obtained. On the other hand, an eighth-order compact finite difference approximation is employed for the spatial derivative at other interior grid points. Combined with the Crank–Nicholson finite difference method and Richardson extrapolation, the overall scheme can be unconditionally stable and provides much more accurate numerical solutions. Numerical errors and convergence rates of these two schemes are tested by two examples. 相似文献
994.
The Hölder continuity of the solution X t (x) to a nonlinear stochastic partial differential equation (see (1.2) below) arising from one dimensional superprocesses is obtained. It is proved that the Hölder exponent in time variable is arbitrarily close to 1/4, improving the result of 1/10 in Li et al. (to appear on Probab. Theory Relat. Fields.). The method is to use the Malliavin calculus. The Hölder continuity in spatial variable x of exponent 1/2 is also obtained by using this new approach. This Hölder continuity result is sharp since the corresponding linear heat equation has the same Hölder continuity. 相似文献
995.
Infeasible interior point methods have been very popular and effective. In this paper, we propose a predictor–corrector infeasible interior point algorithm for convex quadratic programming, and we prove its convergence and analyze its complexity. The algorithm has the polynomial numerical complexity with O(nL)-iteration. 相似文献
996.
The surface tension driven‐flow in BaB2O4 (BBO) melt‐solution is visualized by differential interference microscope coupled with Schlieren technique, and the streamline of the steady thermocapillary convection is found to be in form of an axially symmetric pattern. Based on the observation of BBO crystal rotation caused by the convective vortex, the widths of interfacial concentration, heat and momentum boundary layer are calculated. The effect of thermocapillary convection on boundary layer thickness is also investigated. Results show that the width of boundary layer decreases linearly with the increasing of dimensionless Marangoni number. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
997.
A series of novel [3]ferrocenophane-derived N/B frustrated Lewis pairs (FLPs) were synthesized and successfully applied to the catalytic hydrogenation of imines in 71–93% yields. This approach could be easily conducted on gram scale and provided versatile synthetic route for the key intermediate of sertraline hydrochloride without heavy metal residues. 相似文献
998.
An efficient method has been developed for the synthesis of 1-(arylimino)naphthalen-2(1H)-ones through the cascade reaction of anilines and 2-naphthols promoted by NaBr/K2S2O8/Ce(NH4)2(NO3)6. Using this protocol, a series of 1-(arylimino)naphthalen-2(1H)-ones was obtained in good to excellent yields (17 examples, 70–92% yields). The reactions may proceed through the following steps: bromination of 2-naphthols by in-situ-generated bromine from NaBr and K2S2O8 to afford 1-bromonaphthalen-2-ols, coupling of 1-bromonaphthalen-2-ols with anilines to afford the corresponding amines, and subsequent oxidation of the amines into the products by Ce(NH4)2(NO3)6. These newly obtained α-imine ketones have great potentials for synthesis of special optical materials bearing naphthalene moiety. 相似文献
999.
A series of fluorenone-carbazole based regioisomers (1–4) have been synthesized and applied as host materials for red OLEDs to investigate the effect of different connection configuration on the optoelectronic properties, charge transport capability and device performance. The optoelectronic properties, thermal stability, redox behaviors and charge transport characteristics of these four compounds were fully characterized. These four hosts demonstrated high thermal stability, bipolar charge transport properties and good EL performance. Although these four compounds demonstrated similar HOMO and LUMO energy levels, the twisted structure of 1 led to the smallest singlet-triplet energy gap, which could account in part for the observation of its better EL performance. 相似文献
1000.
Ziquan Zhao Yan Sun Lilin Wang Xuan Chen Yanpei Sun Long Lin Yulin Tang Fei Li Dongyin Chen 《Tetrahedron letters》2019,60(11):800-804
Organic base DBN has been identified as an efficient reagent for promoting the dehydrogenative/decarboxylative aromatization of tetrahydro-β-carbolines under air atmosphere, to access the corresponding β-carbolines in moderate to good yields. The utility of this protocol for the gram-scale synthesis of β-carboline alkaloids eudistomin U (7) and harmane (10) has also been demonstrated. 相似文献