镉-向红菲啰啉体系吸附伏安法测定镉

在pH＝4.1的0．03mol／L邻苯二甲酸氢钾介质中，Cd（Ⅱ）-向红菲啉络合物于悬汞电极上在-0．65V（vs．SCE）电位处产生一灵敏的吸附还原峰，利用1．5次微分技术进行测定，络合物波峰峰值epp与Cd（Ⅱ）浓度在1．0×10－9～1．0×10－7mol／L范围内呈良好的线性关系，检出下限为7×10－10mol／LCd（Ⅱ），本文详细研究了测定镉的最佳条件，对络合物在汞电极上的电化学行为进行了初步探讨。方法用于环境水样中微量镉的测定，结果令人满意。     

A convenient synthesis of 2‐(1H‐1,2,4‐triazol‐1‐yl)‐2H‐1,4‐benzothiazine derivatives

A series of 2‐(1H‐1,2,4‐triazol‐1‐yl)‐2H‐1,4‐benzothiazines were designed and synthesized by condensation of 1,2,4‐triazole‐substituted ω‐bromoacetophenones and o‐aminothiophenols with the aid of K₂CO₃ under mild conditions with moderate to high yields. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:332–336, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20434     

有初应力钢管混凝土压弯扭构件非线性有限元分析

钢管初应力是钢管混凝土在大跨度桥梁,高层超高层建筑应用中广大工程技术人员关心的问题.本文在钢材随动强化模型和混凝土边界面模型的基础上编制了计算有初应力的钢管混凝土压弯扭构件全过程曲线的非线性有限元程序,无论在本构关系的选取还是有限元模式的确定,非线性问题的求解都有自己的特色,不仅大大节省了计算时间,也较好地解决了这一工程实际问题.     

荧光光谱法研究碳纳米管与牛血清白蛋白间相互作用

作为一类新型的纳米材料,碳纳米管(CNTs)所具有的独特结构、强细胞穿透能力和低免疫原性等特性引发了生物医学领域的广泛关注,并有望作为一类新型的药物和基因转运载体。因此,研究碳纳米管与生物大分子间的相互作用对其在体内的进一步应用具有极其重要的意义。本文运用荧光猝灭法、同步荧光法以及红边激发荧光位移法(REES法)研究了生理条件下碳纳米管与牛血清白蛋白(BSA)间的相互作用。结果表明,碳纳米管可引起BSA内源性荧光的静态猝灭,但同步荧光和REES的研究结果表明碳纳米管对BSA的构象基本没有影响。同时,通过对碳纳米管与BSA相互作用的机制的探讨,我们推测碳纳米管主要通过非特异性吸附的方式与BSA相互作用。     

Cyclopalladated ferrocenylimines: efficient catalysts for homocoupling and Sonogashira reaction of terminal alkynes

A novel pathway for homocoupling of terminal alkynes has been described using cyclopalladated ferrocenylimine 1 or 2/CuI as catalyst in the air. This catalytic system could tolerate several functional groups. The palladacycle 2 in the presence of n-Bu₄NBr as an additive could be applied to Sonogashira cross-coupling reaction of aryl iodides, aryl bromides, and some activated aryl chlorides with terminal alkynes under amine- and copper-free conditions, mostly to give moderate to excellent yields.     

Conservative compact difference schemes for the coupled nonlinear schrödinger system

In this article, some conservative compact difference schemes are explored for the strongly coupled nonlinear schrödinger system. After transforming the scheme into matrix form, we prove the existence and uniqueness, convergence and stability of the difference solutions for one nonlinear scheme in the norm by using some techniques of matrix theory. Numerical results show that one nonlinear scheme is the most efficient of all the compact schemes constructed here. It allows much larger time steps than the others. The second most efficient compact scheme is a linear one. We then give numerical simulations to two soliton interactions for the two most efficient compact schemes. © 2013 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 30: 749–772, 2014     

Topology of toroidal helical fields in non-circular cross-sectional tokamaks

The ordinary differential magnetic field line equations are solved numerically; the tokamak magnetic structure is studied on Hefei Tokamak-7 Upgrade （HT-TU） when the equilibrium field with a monotonic q-profile is perturbed by a helical magnetic field. We find that a single mode （m, n） helical perturbation can cause the formation of islands on rational surfaces with q=m/n and q=（m±1,±2,±3,...）/n due to the toroidicity and plasma shape （i.e. elongation and triangularity）, while there are many undestroyed magnetic surfaces called Kolmogorov-Arnold-Moser （KAM） barriers on irrational surfaces. The islands on the same rational surface do not have the same size. When the ratio between the perturbing magnetic field Br（r） and the toroidal magnetic field amplitude Bφ0 is large enough, the magnetic island chains on different rational surfaces will overlap and chaotic orbits appear in the overlapping area, and the magnetic field becomes stochastic. It is remarkable that the stochastic layer appears first in the plasma edge region.     

Facile preparation and electrochemical properties of cubic-phase Li4Mn5O12 nanowires

Single crystalline Li4Mn5O12 nanowires with cubic phase were prepared in a large scale by a simple molten salt route without using any surfactant as template; the nanowires exhibited high storage capacity and coulombic efficiency as cathode materials for lithium-ion batteries.     

微波实验在工科物理实验中的应用及意义

本文分析了微波实验在工科物理实验中的现状；提出一些有关测量微波基本特性的实验方案：大功率及小功率微波功率测量、驻波系数的测量、波长和阻抗的测量等；介绍了两个新开展的微波检测实验：微波衰减湿度检测和用反射法进行微波湿度检测，可以使学生了解微波的一些基本特性和应用．