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991.
When a particle is bounded in a central force field, the only nonvanishing component of the mean value for current density
is along the azimuthal direction; and the total current can therefore be defined. It is found that the total current is in
fact a mean value of a newly defined total current operator in the quantum mechanical state. Not only the total current operator
itself but also the mean total current has exact classical correspondence. 相似文献
992.
Using Co2O3 as the Co source, doped cerium oxide thin films with the composition of Ce0.97C00.03O2-δ (CCO) are deposited on Si(111) and glass substrates by pulse laser deposition technique. X-ray diffraction reveals that CCO films with (111) preferential orientation are grown on Si, while the fihn on glass is polycrystalline with nanocrystal. X-ray photoelectron spectroscopy shows that the (Jo displaces the (;e atom and exists in high spin state rather than low spin state, which contributes to the room-temperature ferromagnetism confirmed by vibration sample magnetometer. I~ilms on Si and glass are different in ferromagnetism, which is believed to be induced by different film microstructures. Based on these results, the possible ferromagnetism in this insulating film is discussed. Anyway, successful fabrication of CCO films with room-temperature ferromagnetism on Si substrates is of great importance in both technological and theoretical aspects. 相似文献
993.
L.H. Nguyen T.V. Phi P.Q. Phan H.N. Vu C. Nguyen-Duc F. Fossard 《Physica E: Low-dimensional Systems and Nanostructures》2007,37(1-2):54
It has been recently demonstrated that carbon nanotubes (CNTs) represent a new type of chemical sensor capable of detecting a small concentration of molecules such as CO, NO2, NH3.In this work, CNTs were synthesized by chemical vapor deposition (CVD) on the SiO2/Si substrate by decomposition of acetylene (C2H2) on sputtered Ni catalyst nanoparticles. Their structural properties are studied by atomic force microscopy, high-resolution scanning electron microscopy (HRSEM) and Raman spectroscopy. The CNTs grown at 700 °C exhibit a low dispersion in size, are about 1 μm long and their average diameter varies in the range 25–60 nm as a function of the deposition time. We have shown that their diameter can be reduced either by annealing in oxygen environment or by growing at lower temperature (less than 600 °C).We developed a test device with interdigital Pt electrodes on an Al2O3 substrate in order to evaluate the CNTs-based gas sensor capabilities. We performed room temperature current–voltage measurements for various gas concentrations. The CNT films are found to exhibit a fast response and a high sensitivity to NH3 gas. 相似文献
994.
Ce3+-doped silica was synthesized by sol-gel technique. The absorption band at 252 nm of Ce3+-doped silica is close to the main absorption band of Ce(NO3)3 solution. Three different luminescence bands were observed in the samples annealed at temperatures from 100 to 1200 °C, and the intensity of these luminescence bands changed with the alteration of the heat-treating temperatures. In addition to two well-known main luminescence bands of 4f-5d transition of Ce3+ with the wavelength at 357 and 450 nm, a rarely reported luminescent band with the wavelength at 344 nm was also observed, which was attributed to some kind of oxygen-related defects of silica. 相似文献
995.
Potential PDP phosphors with strong absorption around 172 nm: Rare earth doped NaLaP2O7 and NaGdP2O7
Jun Lin Yuan Jiao Wang Ding Bang Xiong Jing Tai Zhao Yi Bing Fu Chao Shu Shi 《Journal of luminescence》2007,126(2):717-722
NaLaP2O7 and NaGdP2O7 powder samples are prepared by solid-state reactions at 750 and 600 °C, respectively, and the VUV-excited luminescence properties of Ln3+ (Ln=Ce, Pr, Tb, Tm, Eu) in both diphosphates are studied. Ln3+ ions in both hosts show analogous luminescence. For Ce3+-doped samples, the five Ce3+ 5d levels can be clearly identified. As for Pr3+ and Tb3+-doped samples, strong 4f-5d absorption band around 172 nm is observed, which matches well with Xe-He excimer in plasma display panel (PDP) devices. As a result, Pr3+ can be utilized as sensitizer to absorb 172 nm VUV photon and transfer energy to appropriate activators, and Tb3+-doped NaREP2O7(RE=La, Gd) are potential 172 nm excited green PDP phosphors. For Tm3+ and Eu3+-doped samples, the Tm3+-O2− charge transfer band (CTB) is observed to be at 177 nm, but the CTB of Eu3+ is observed at abnormally low energy position, which might originate from multi-position of Eu3+ ions. The similarity in luminescence properties of Ln3+ in both hosts indicates certain structural resemblance of coordination environment of Ln3+ in the two sodium rare earth diphosphates. 相似文献
996.
Zhi-hua Xiong 《Journal of Physics and Chemistry of Solids》2007,68(8):1500-1503
We perform first-principles spin polarized calculations of the electronic structure of Ti-doped in ZnO. Ferromagnetism in Ti-doped ZnO is identified, which is in agreement with recent experimental and calculated results. A net magnetic moment of 0.715μB is found per Ti. At a Ti concentration of 12.5%, total energy calculations show that the ferromagnetic state is 68 meV lower than the antiferromagnetic state. The electronic states near Fermi energy are dominated by strong hybridization between O 2p and Ti 3d, which is just the origin of impurity band in Ti-doped ZnO and also implies that the Ti-O bond is quite covalent instead of purely ionic. Since there is no magnetic element in this compound, Ti-doped ZnO appears to be an unambiguous dilute magnetic semiconductor. 相似文献
997.
998.
Extensive computer simulations of multicomponent ion exchange processes in fixed beds are reported. The simulations are based on the local equilibrium theory developed by Helfferich and Klein. The simulations illustrate through computer graphics how the various ions separate and migrate in a column. Detailed concentration profiles as a function of time are shown for cyclic chromatographic operations such as elution, displacement, and selective displacement processes. The simulations elucidate the main features of the interference phenomena as a result of solute competition for the sorbent sites. These simulations also provide important guidelines for designing bulk separation processes, for example, the strategies of recovery, the choices of cyclic operations, feed size, presaturant, eluant, and displacer. 相似文献
999.
M. Q. Ling A. Yili H. A. Aisa Z. Bo O. N. Veshkurova Sh. I. Salikhov 《Chemistry of Natural Compounds》2011,46(6):932-934
A new peptide that had anti-oxidant activity and molecular weight 5,000.5 Da according to PAAG data and mass spectrometry
was isolated from celery seed using chromatographic methods. 相似文献
1000.