Two types of diffusions at the cathode/electrolyte interface in IT-SOFCs

Analytical transmission electron microscopy, in particular with the combination of energy dispersive X-ray spectroscopy (EDX) and electron energy-loss spectroscopy (EELS), has been performed to investigate the microstructure and microchemistry of the interfacial region between the cathode (La_0.6Sr_0.4Co_0.8Fe_0.2O₃, LSCF) and the electrolyte (Gd-doped ceria, GDC). Two types of diffusions, mutual diffusion between cathode and electrolyte as well as the diffusion along grain boundaries, have been clarified. These diffusions suggest that the chemical stability of LSCF and GDC are not as good as previously reported. The results are more noteworthy if we take into consideration the fact that such interdiffusions occur even during the sintering process of cell preparation.     

簇间连接方式不同的簇网络的同步过程研究

本文对簇间连接方式不同的三类簇网络的同步能力和同步过程进行研究. 构成簇网络的两个子网均为BA无标度网络, 当簇间连接方式是双向耦合时, 称其为TWD网络模型, 当簇间连接是大子网驱动小子网时, 称其为BDS网络模型, 当簇间连接是小子网驱动大子网时, 称其为SDB网络模型. 研究表明, 当小子网和大子网节点数目的比值大于某一临界值时, TWD网络模型的同步能力大于BDS网络模型的同步能力, 当该比值小于某一临界值时, TWD网络模型的同步能力小于BDS网络模型的同步能力, SDB网络模型的同步能力是三种网络结构中最差的. 对于簇间连接具有方向性的单向驱动网络, 簇网络的整体同步能力与被驱动子网的节点数和簇间连接数有关, 与驱动网络自身节点数无关. 增加簇间连接数在开始时会降低各子网的同步速度, 但最终各子网到达完全同步的时间减少, 网络的整体同步能力增强. 文中以Kuramoto相振子作为网络节点, 研究了不同情况下三种簇网络的同步过程, 证明了所得结论的正确性. 关键词： 簇网络 有向连接 同步能力 Kuramoto振子     

用于POF的高性能共振腔发光二极管

提出用AlGaAs材料为n型下DBR,AlGaInP材料为p型上DBR,GaInP/AlGaInP多量子阱为有源区来制备650nm波长的共振腔发光二极管（RCLED）.用传输矩阵法对器件的结构进行了理论设计,并制备了RCLED和普通LED两种结构.测试结果表明,RCLED有更高的发光效率,是普通LED的近1.3倍,当注入电流从3mA增加到30mA时,RCLED的峰值波长只变化了1nm,而普通LED的波长则变化了7nm,且RCLED的光谱半宽窄,远场发散角小. 关键词： 发光二极管 共振腔 金属有机物化学气相淀积     

金纳米球壳对的局域表面等离激元共振特性分析

应用有限元方法, 研究金纳米球壳对的几何结构参数及物理参量对其表面等离激元共振的散射及消光光谱的影响, 并根据等离激元杂化理论进行了理论分析. 结果表明, 随着金壳厚度的增加, 金纳米球壳对的散射及消光共振峰先发生蓝移而后红移, 而随着金纳米球壳间隙的减小, 或者随着金纳米球壳的内核尺寸或内核介质折射率的增大, 散射及消光共振峰均发生红移; 随着金壳厚度或内核尺寸减小, 或者随着内核介质折射率增大, 金纳米球壳对的散射与消光共振强度减弱, 而随着金壳间隙的减小, 金纳米球壳对的散射共振强度先增强后减弱, 而消光共振强度逐渐增强, 数值模拟与理论分析一致.     

四氯苯醌与嘧啶类核酸碱基的光化学氢抽取和电子转移反应

采用纳秒时间分辨的激光闪光光解实验技术,研究了四氯苯醌(TCBQ)分子与两种嘧啶核酸碱基(胸腺嘧啶和尿嘧啶)分子在355nm激发下的光化学反应动力学. 355 nm将TCBQ分子布居到激发三重态³TCBQ^*,高反应活性的³TCBQ^*与碱基分子发生两个平行的反应,氢抽取反应和电子转移反应,分别对应生成瞬态光谱上观测到的两个光反应产物TCBQH·和TCBQ·^-. 这两个反应同时生成的碱基自由基和碱基阳     

Room-temperature ferromagnetism in pure ZnO nanoflowers

ZnO nanoflowers are synthesized by hydrothermal method. The morphology of ZnO is captured by SEM, TEM and HRTEM, which is composed of closely packed nanorods of about 100 nm in diameter and 1 μm in length. The ZFC/FC curves show superparamagnetic features. The abnormal increase in magnetization curves below 14 K comes from the isolated vacancy clusters with no interaction. The magnetic hysteresis at 300 K displays saturation state and confirms room-temperature ferromagnetism. While the magnetic hysteresis at 5 K shows nonsaturation state due to the enhanced effects of vacancy clusters. The O 1s XPS results can be fitted to three Gaussian peaks. The existence of medium-binding energy located at 531.16 eV confirms the deficiency of O ions at the surface of ZnO nanoflowers.     

Electroluminescent block copolymers containing oxadiazole and thiophene via ATRP

Block copolymers containing thiophene units in one block and oxadiazole (OXD) units in the other were prepared. Atom transfer radical polymerization method was used to obtain the thiophene‐containing mesogen‐jacketed polymers, and the kinetic study indicated that the polymerization was controllable and the polymers could be used to initiate the polymerization of the OXD‐containing monomers. Photoluminescent spectra indicated that the fluorescence quantum yields of the polymers increased with increasing content of OXD. And, more OXD domains, that is, more interfaces between the hole‐transport parts and electron‐transport parts, resulting in the higher probability of exciplex formation. The electroluminescent devices containing the block copolymer with 64 mol % OXD as the emissive layer had a maximum brightness of 127 cd/m² and an extremely low onset voltage of 7.7 V, which indicated that the injection and transport of charge carriers were facilitated and the number of charge carriers was sufficiently high in early time after the voltage was turned on. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010