首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   685篇
  免费   67篇
  国内免费   53篇
化学   472篇
晶体学   13篇
力学   50篇
综合类   2篇
数学   84篇
物理学   184篇
  2024年   13篇
  2023年   42篇
  2022年   78篇
  2021年   60篇
  2020年   45篇
  2019年   53篇
  2018年   28篇
  2017年   42篇
  2016年   42篇
  2015年   31篇
  2014年   27篇
  2013年   31篇
  2012年   25篇
  2011年   35篇
  2010年   36篇
  2009年   42篇
  2008年   16篇
  2007年   27篇
  2006年   25篇
  2005年   16篇
  2004年   18篇
  2003年   10篇
  2002年   8篇
  2001年   5篇
  2000年   9篇
  1999年   6篇
  1998年   10篇
  1997年   7篇
  1996年   8篇
  1995年   3篇
  1994年   2篇
  1992年   1篇
  1990年   1篇
  1986年   1篇
  1979年   1篇
  1957年   1篇
排序方式: 共有805条查询结果,搜索用时 15 毫秒
81.
In this paper, the dynamical behavior of a delayed viral infection model with immune impairment is studied. It is shown that if the basic reproductive number of the virus is less than one, then the uninfected equilibrium is globally asymptotically stable for both ODE and DDE model. And the effect of time delay on stabilities of the equilibria of the DDE model has been studied. By theoretical analysis and numerical simulations, we show that the immune impairment rate has no effect on the stability of the ODE model, while it has a dramatic effect on the infected equilibrium of the DDE model.  相似文献   
82.
Liu X  Mwangi M  Li X  O'Brien M  Whitesides GM 《Lab on a chip》2011,11(13):2189-2196
This paper describes the development of MEMS force sensors constructed using paper as the structural material. The working principle on which these paper-based sensors are based is the piezoresistive effect generated by conductive materials patterned on a paper substrate. The device is inexpensive (~$0.04 per device for materials), simple to fabricate, lightweight, and disposable. Paper can be readily folded into three-dimensional structures to increase the stiffness of the sensor while keeping it light in weight. The entire fabrication process can be completed within one hour without expensive cleanroom facilities using simple tools (e.g., a paper cutter and a painting knife). We demonstrated that the paper-based sensor can measure forces with moderate performance (i.e., resolution: 120 μN, measurement range: ±16 mN, and sensitivity: 0.84 mV mN(-1)). We applied this sensor to characterizing the mechanical properties of a soft material. Leveraging the same sensing concept, we also developed a paper-based balance with a measurement range of 15 g, and a resolution of 0.39 g.  相似文献   
83.
Wang  Xia  Tao  Youde  Song  Xinyu 《Nonlinear dynamics》2011,66(4):825-830
In this paper, the global stability of virus dynamics model with Beddington–DeAngelis infection rate and CTL immune response is studied by constructing Lyapunov functions. We derive the basic reproduction number R 0 and the immune response reproduction number R 0 for the virus infection model, and establish that the global dynamics are completely determined by the values of R 0. We obtain the global stabilities of the disease-free equilibrium E 0, immune-free equilibrium E 1 and endemic equilibrium E when R 0≤1, R 0>1, R 0>1, respectively.  相似文献   
84.
煤层坚硬顶板采用水力压裂技术进行定向弱化可有效控制来压步距,降低事故风险。基于黏聚力模型,利用有限元二次开发建立了压裂前后煤层开采数值计算模型,模拟分析了顶板垮落规律及影响因素,优化裂缝间距设计。结果表明:来压跨距与顶板厚度、强度呈正相关性,与埋深呈负相关性。预制裂缝在拉应力集中区可促进起裂扩展,应全面勘测各岩层位地质参数,利用计算出的应力集中区位置设计裂缝间距,实现经济有效地控制来压步距。  相似文献   
85.
<正>A 128×128 elements cylindrical liquid crystal(LC) lens array with electrically controllable focal length is proposed.The cylindrical LC lens array uses transparent indium tin oxide(ITO) films as electrode,avoiding to affect the optical path operating in the voltage-off status.As the top electrode of the cylindrical LC lens array contacts with LC,the operation voltage root-mean-square(RMS) amplitude can be as low as 1.4 V and the response time is about 20-30 ms.The special optical focusing feature of the cylindrical LC lens array is got.And the focal length of this array is about 60-450μm.  相似文献   
86.
A reliable method for adsorption systems in equilibrium is established to derive coverage-dependent kinetics and thermodynamics from the volumetric data obtained during the static microcalorimetric measurement of heats of adsorption. The Wigner-Polanyi equation is applied to analyze the pressure change as a function of time during stepwise dosing of the adsorptive until thermodynamic adsorption-desorption equilibrium is established. For carbon monoxide adsorption on a hydrogen-reduced Cu/ZnO/Al2O3 catalyst, the adsorption rate constant (ka) is found to be in the range from 10(-6) to 10(-4) Pa(-1) s(-1), and the desorption rate constant (kd) from 10(-4) to 10(-2) s(-1), both increasing with fractional coverage theta. The kinetically derived equilibrium constant Ktheta is in good agreement with Ktheta obtained from the adsorption isotherm. RT ln(Kp0) and the differential heat of adsorption (qdiff) were found to decrease in parallel, reflecting a normal Temkin-type heterogeneity.  相似文献   
87.
We report the first experimental observation of strong suppression of matter-wave superradiance using blue-detuned pump light and demonstrate a pump-laser detuning asymmetry in the collective atomic recoil motion. In contrast to all previous theoretical frameworks, which predict that the process should be symmetric with respect to the sign of the detuning of the pump laser from the one-photon resonance, we find that for condensates the symmetry is broken. With high condensate densities and red-detuned pump light the distinctive multiorder, matter-wave scattering pattern is clearly visible, whereas with blue-detuned pump light superradiance is strongly suppressed. However, in the limit of a dilute atomic gas symmetry is restored.  相似文献   
88.
In this article, we establish a mathematical model of two species with stage structure and the relation of predator-prey, obtain the necessary and sufficient condition for the permanence of two species and the extinction of one species or two species. We also obtain the optimal harvesting and the threshold of harvesting for the sustainable development and increasing delays can cause a bifurcation into periodic solutions. Finally, we give some numerical results and graphs.  相似文献   
89.
Indoles are essential heterocycles in medicinal chemistry, and therefore, novel and efficient approaches to their synthesis are in high demand. Among indoles, 2‐aryl indoles have been described as privileged scaffolds. Advanced herein is a straightforward, practical, and transition‐metal‐free assembly of 2‐aryl indoles. Simply combining readily available 2‐fluorotoluenes, nitriles, LiN(SiMe3)2, and CsF enables the generation of a diverse array of indoles (38 examples, 48–92 % yield). A range of substituents can be introduced into each position of the indole backbone (C4 to C7, and aryl groups at C2), providing handles for further elaboration.  相似文献   
90.
2D transition metal carbides and nitrides (MXenes), a class of emerging nanomaterials with intriguing properties, have attracted significant attention in recent years. However, owing to the highly hydrophilic nature of MXene nanosheets, assembly strategies of MXene at liquid–liquid interfaces have been very limited and challenging. Herein, through the cooperative assembly of MXene and amine‐functionalized polyhedral oligomeric silsesquioxane at the oil–water interface, we report the formation, assembly, and jamming of a new type MXene‐based Janus‐like nanoparticle surfactants, termed MXene‐surfactants (MXSs), which can significantly enhance the interfacial activity of MXene nanosheets. More importantly, this simple assembly strategy opens a new platform for the fabrication of functional MXene assemblies from mesoscale (e.g., structured liquids) to macroscale (e.g., aerogels), that can be used for a range of applications, including nanocomposites, electronic devices, and all‐liquid microfluidic devices.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号