全文获取类型
收费全文 | 10757篇 |
免费 | 1550篇 |
国内免费 | 1332篇 |
专业分类
化学 | 7702篇 |
晶体学 | 119篇 |
力学 | 726篇 |
综合类 | 78篇 |
数学 | 1332篇 |
物理学 | 3682篇 |
出版年
2024年 | 44篇 |
2023年 | 253篇 |
2022年 | 346篇 |
2021年 | 377篇 |
2020年 | 434篇 |
2019年 | 450篇 |
2018年 | 383篇 |
2017年 | 369篇 |
2016年 | 515篇 |
2015年 | 515篇 |
2014年 | 580篇 |
2013年 | 802篇 |
2012年 | 879篇 |
2011年 | 953篇 |
2010年 | 671篇 |
2009年 | 603篇 |
2008年 | 736篇 |
2007年 | 624篇 |
2006年 | 556篇 |
2005年 | 416篇 |
2004年 | 380篇 |
2003年 | 285篇 |
2002年 | 318篇 |
2001年 | 220篇 |
2000年 | 216篇 |
1999年 | 269篇 |
1998年 | 192篇 |
1997年 | 141篇 |
1996年 | 147篇 |
1995年 | 143篇 |
1994年 | 107篇 |
1993年 | 120篇 |
1992年 | 97篇 |
1991年 | 96篇 |
1990年 | 88篇 |
1989年 | 64篇 |
1988年 | 51篇 |
1987年 | 53篇 |
1986年 | 33篇 |
1985年 | 33篇 |
1984年 | 21篇 |
1983年 | 14篇 |
1982年 | 12篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
111.
A simply fabricated microfluidic device using a green organic light emitting diode (OLED) and thin film interference filter as integrated excitation source is presented and applied to fluorescence detection of proteins. A layer-by-layer compact system consisting of glass/PDMS microchip, pinhole, excitation filter and OLED is designed and equipped with a coaxial optical fiber and for fluorescence detection a 300 microm thick excitation filter is employed for eliminating nearly 80% of the unwanted light emitted by OLEDs which has overlaped with the fluorescence spectrum of the dyes. The distance between OLED illuminant and microchannels is limited to approximately 1 mm for sensitive detection. The achieved fluorescence signal of 300 microM Rhodamine 6G is about 13 times as high as that without the excitation filter and 3.5 times the result of a perpendicular detection structure. This system has been used for fluorescence detection of Rhodamine 6G, Alexa 532 and BSA conjugates in 4% linear polyacrymide (LPA) buffer (in 1 x TBE, pH 8.3) and 1.4 fmol and 35 fmol mass detection limits at 0.7 nl injection volume for Alexa and Rhodamine dye have been obtained, respectively. 相似文献
112.
Hung‐Chuan Cheng Li‐Tang Wang Ashraf Taha Khalil Yao‐To Chang Yu‐Chi Lin Ya‐Ching Shen 《中国化学会会志》2004,51(2):431-435
Phytochemical investigation of the stem bark of Calophyllum inophyllum resulted in the isolation of a new dipyrenoxanthone, calophinone ( 1 ), together with four related xanthones ( 2–5 ). Identification of the isolated compounds was achieved through intensive studies of their spectral data, especially 2D NMR. 相似文献
113.
In order to achieve "postponement of school without suspension of learning" during the prevention and control of new coronavirus pneumonia, the online teaching strategy was constructed based on Enterprise WeChat and Integrated Online Education Platform for the online teaching of Separation Science and Technology. The student-centered teaching methods were applied in online teaching process. 相似文献
114.
Bao Liu Ling Huang Juntao Liu Yao Zhong Xingshu Li Albert S.C. Chan 《Tetrahedron: Asymmetry》2007,18(24):2901-2904
Chiral tridentate N-tosylated aminoimine ligands were used in the Cu(II)-catalyzed enantioselective addition of phenylacetylene to N-aryl arylimines, affording products up to 92% ee. 相似文献
115.
116.
117.
J. Hatta M. Okada S. Matuoka H. Yao 《Journal of Thermal Analysis and Calorimetry》1992,38(8):1775-1783
Using an ac calorimetric method, detailed behaviour of the heat capacity in dipalmitoyl-phosphatidylcholine-cholesterol system was studied in the cholesterol concentration less than 5 mol%. It was revealed that the heat capacity near the main transition was composed of at least four anomalies, i.e., multipeak took place in the heat capacity. This fact indicates that a simple theory explaining coexistence of two phases in two component systems does not work in the multipeak region. Then, relation between the multipeak heat capacity and the change of the ripple structure with the cholesterol concentration should be taken into account, when we consider thermodynamical behaviour of the systems.
Zusammenfassung Mittels AC-Kalorimetrie wurde bei Cholesterol-Konzentrationen von weniger als 5 mol% das Verhalten der Wärmekapazität im System Dipalmitoylphosphatidylcholin-Cholesterol untersucht. Es wurde gezeigt, daß sich die Wärmekapazität in der Nähe der Hauptumwandlung aus mindestens vier Anomalien zusammensetzt, d.h. bei der Wärmekapazität kann ein Multipeak beobachtet werden. Diese Tatsache zeigt, daß eine einfache Theorie, welche die Koexistenz zweier Phasen in einem Zweikomponenten-System erklärt, für die Multipeakregion nicht geeignet ist. Weiterhin sollte bei Überlegungen zum thermodynamischen Verhalten von Systemen eine Beziehung zwischen der Multipeak-Wärmekapazität bzw. der Welligkeitsstruktur und der Cholesterol-Konzentration berücksichtigt werden.相似文献
118.
A series of pyrazolo[3,4‐b]pyridines was synthesized by the reaction of 5‐aminopyrazole with benzylidenemalononitrile in aqueous media. The structures were characterized by IR, 1H NMR, and elemental analysis and were further confirmed by X‐ray diffraction analysis. 相似文献
119.
Ning Li Chunhui Deng Ning Yao Xizhong Shen Xiangmin Zhang 《Analytica chimica acta》2005,540(2):317-323
In the study, we developed a simple, rapid, sensitive, and inexpensive method for determination of the disease biomarkers of acetone, hexanal and heptanal in human blood. For the first time, derivatization of carbonyls with O-2,3,4,5,6-(pentafluorobenzyl)hydroxylamine (PFBHA) was combined with headspace single-drop microextractin (HS-SDME) and gas chromatography-mass spectrometry (GC–MS) and applied to the analysis of acetone, hexanal, and heptanal in human blood. At first, acetone, hexanal and heptanal in blood were derivatized with PFBHA and formed oximes in several seconds. Sequentially, the oximes were headspace extracted and concentrated by a microdrop solvent. Finally, the extracted oximes were analyzed by GC–MS. HS-SDME conditions and method validations were studied. Due to needing of only 2 μl organic solvent, short extraction time of 8 min, and simple operation, derivatization-HS-SDME was shown to be a rapid, simple, and inexpensive technique for analysis of acetone, hexanal, and heptanal in human blood. Moreover, it had low detection limit values from 0.24 to 0.62 nM, and good reproducibility (R.S.D. less than 12%). 相似文献
120.
水溶性含C_(60)聚电解质的制备及其与重氮树脂自组装膜AFMFFM的初步研究 总被引:4,自引:0,他引:4
通过BPO引发的溶液聚合 ,合成了水溶性的星状C6 0 苯乙烯 苯乙烯磺酸钠的三元共聚物 [Star shapedC6 0 poly(St SS) ],运用自组装技术 ,在水溶液中 ,含C6 0 的三元共聚物与重氮树脂 (Diazoresin)通过正负离子间的吸附力在云母基片上交替一层一层有序地组装成固体膜 .自组装膜经紫外光幅照反应 ,通过重氮基的分解 ,层间连接的离子键转变成共价键 ,从而增加薄膜的稳定性和堆砌密度 .用原子力显微镜 摩擦力显微镜(AFM FFM)考察了C6 0 在膜中的承载作用及比较不同链结构、不同链长、不同层数自组装膜的表面形貌和微摩擦性能 .初步的研究结果显示了聚合物薄膜的微摩擦性能与聚合物的化学结构、链长和膜的层数有密切关系 相似文献