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121.
Guo-Yu Lan Yang-Wei Lin Zong-Hong Lin Huan-Tsung Chang 《Journal of nanoparticle research》2010,12(4):1377-1388
This article describes the synthesis of highly water-soluble Zn
x
Hg1−x
Se
y
S1−y
quantum dots (QDs) in aqueous solution through a simple photo-assisted reaction between ZnSe QDs and mercury(I) nitrate dihydrate
[Hg2(NO3)2·2H2O]. In order to deduce the optimal synthesis conditions, we varied several parameters, including the concentrations of mercaptosuccinic
acid (MSA) and Hg2(NO3)2·2H2O, the illumination time, and the reaction temperature. When irradiated at temperatures below 80 °C, the ZnSe QDs reacted
with the S2− ions formed rapidly from MSA and the Hg2+ ions formed from Hg2
2+ ions to form Zn
x
Hg1−x
Se
y
S1−y
QDs through a process of photo-etching and surface combination. Under different conditions, we prepared a series of Zn
x
Hg1−x
Se
y
S1−y
QDs that emit fluorescence at the maximum wavelengths ranging from 405 to 760 nm. Inductively coupled plasma-mass spectrometry
and transmission electron microscopy/energy dispersive spectrometry revealed that the content of Hg in the Zn
x
Hg1−x
Se
y
S1−y
QDs was greater when the synthesis was conducted at higher temperature. The Zn0.88Hg0.12Se0.44S0.56 QDs exhibit improved photostability than crude ZnSe QDs and possess long lifetimes (τ1 ~ 38 ns and τ2 ~ 158 ns). 相似文献
122.
Coexistence of magnetism and superconductivity in the hole doped FeAs-based superconducting compound
T.P. Lu C.C. Wu W.H. Chou M.D. Lan 《Physica C: Superconductivity and its Applications》2010,470(5-6):357-359
The magnetic and superconducting properties of the Sm-doped FeAs-based superconducting compound were investigated under wide ranges of temperature and magnetic field. After the systematical magnetic ion substitution, the superconducting transition temperature decreases with increasing magnetic moment. The hysteresis loop of the La0.87?xSmxSr0.13FeAsO sample shows a superconducting hysteresis and a paramagnetic background signal. The paramagnetic signal is mainly attributed to the Sm moments. The experiment demonstrates that the coexistence of magnetism and superconductivity in the hole doped FeAs-based superconducting compounds is possible. Unlike the electron doped FeAs-based superconducting compounds SmFeAsOF, the hole doped superconductivity is degraded by the substitution of La by Sm. The hole-doped and electron-doped sides are not symmetric. 相似文献
123.
In this paper, we consider one-dimensional compressible isentropic Navier-Stokes equations with the viscosity depending on density and with the free boundary. The viscosity coefficient μ is proportional to ρθ with θ>0, where ρ is the density. The existence, uniqueness, regularity of global weak solutions in H1([0,1]) have been established by Xin and Yao in [Z. Xin, Z. Yao, The existence, uniqueness and regularity for one-dimensional compressible Navier-Stokes equations, preprint]. Furthermore, under certain assumptions imposed on the initial data, we improve the regularity result obtained in [Z. Xin, Z. Yao, The existence, uniqueness and regularity for one-dimensional compressible Navier-Stokes equations, preprint] by driving some new a priori estimates. 相似文献
124.
介绍了一种获得准等时性储存环的方案,即调节Lattice参数,在色散段引入负色散函数从而降低线性滑相因子,获得短束团。根据此方案设计了用于相干太赫兹光源的准等时性储存环,结果给出了线形光学函数曲线以及粒子的动力学孔径,表明了通过调节四极铁参数可以达到降低束团长度获得准等时性储存环的目的。还设计了用于准等时性储存环弯铁处的真空室的3维模型,并对其类腔体部分的本征模进行了计算,得到特性阻抗与品质因数的比值在10-3量级以下,表明类腔体部分对束流的影响很小。 相似文献
125.
本文提出一种半径和周期双重扰动的非均匀圆波导TE0n模式变换器. 通过耦合波理论(CWT)和数值优化方法对该模式变换器进行研究, 计算结果与电磁仿真软件基本一致. 与传统的均匀结构半径微扰模式变换器比较, 非均匀扰动结构TE0n模式变换器可以在更少的波纹周期内实现高于均匀结构的模式转换效率, 95%功率转换绝对带宽增加150%, 器件长度减小接近一半. 本文的研究工作为设计轴向尺寸短、工作带宽大、 转换效率高的高功率回旋管外接模式变换器提供了重要参考. 相似文献
126.
We prove the global solvability and weakly asymptotic stability for a semilinear fractional differential inclusion subject to impulsive effects by analyzing behavior of its solutions on the half-line. Our analysis is based on a fixed point principle for condensing multi-valued maps, which is employed for solution operator acting on the space of piecewise continuous functions. The obtained results will be applied to a lattice fractional differential system. 相似文献
127.
Haijing Liang Lixia Ma Changwei Li Qiang Peng Zhaoyan Wang Zhan-xin Zhang Lan Yu Huanxiang Liu Fengli An Weihua Xue 《Tetrahedron letters》2019,60(1):84-87
Glycosylation reactions are significant as they provide access to model compounds that are useful for elucidating biochemical pathways. Herein, we describe the development of glycosyl ortho-alkynylbenzoates as novel, bench-top stable, and readily available glycosyl donors. Glycosylation is promoted by inexpensive trimethylsilyl triflate (TMSOTf) in combination with N-iodosuccinimide (NIS) under mild reaction conditions; hence, the novel glycosyl donors are promising reagents for the synthesis of glycosides. 相似文献
128.
Yue Hu Wei Sun Tao Zhang Nuo Xu Jianeng Xu Yu Lan Chao Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(44):15960-15965
An unprecedented stereoselective synthesis of trisubstituted vinylboronates is reported to proceed by direct borylation of lithium ketone enolates under transition‐metal‐free conditions. The stereospecific C?O borylation of lithium enolates was triggered by a carbonyl‐induced 1,3‐metalate rearrangement via a C‐bound boron enolate. DFT calculations and control experiments revealed that the stereoselectivity is controlled by sterics. A variety of stereospecific trisubstituted vinylboronates, together with several tetrasubstituted vinylboronates, were conveniently synthesized with the newly developed methodology. Based on the transformation of stereospecific vinylboronate, a single isomer of Dienestrol was efficiently obtained. 相似文献
129.
130.
Dong‐E Wang Feng Wang Xiang‐Gao Meng Yu Ding Li‐Li Wen Dr. Dong‐Feng Li Prof. Dr. She‐Ming Lan 《无机化学与普通化学杂志》2008,634(14):2643-2648
Three inorganic‐organic hybrid frameworks [Mn(HIMDC)(4,4′‐bipyo)0.5(H2O)]n (1) , [Cd(H2IMDC)2(2,2′‐bipyo)] (2) and [Ca(HIMDC)(H2O)2·H2O]n (3) (H3IMDC = 4,5‐imidazoledicarboxylate; 4,4′‐bipyo = 4,4′‐bipyridine‐N,N′‐dioxide; 2,2′‐bipyo= 2,2′‐bipyridine‐N,N′‐dioxide) have been hydrothermally synthesized and characterized by the elemental analyses, IR spectra, TG analysis and the single crystal diffraction. Both compounds 1 and 3 exhibit 2D layers while 2 is a monomer. It is noteworthy that compound 2 exhibits strong fluorescent emission in the solid state at room temperature. 相似文献