Formation of rectangular packing and one-dimensional lines of C60 on 11-phenoxyundecanethiol self-assembled monolayers on Au(111)

The behavior of C(60) molecules deposited onto 11-phenoxyundecanethiol (phenoxy) self-assembled monolayers (SAMs) is studied using ultrahigh vacuum scanning tunneling microscopy (UHV-STM) and spectroscopy. We observe that after thermally annealing between 350 and 400 K in vacuum a combination of hexagonally close-packed islands, rectangularly packed islands, and isolated single lines of C(60) is observed when the C(60) is initially deposited on an unannealed phenoxy SAM. However, only rectangularly packed islands are found when they are deposited on a preannealed phenoxy SAM. We determine the rectangular packing to have a (2√3 × 4) rectangular unit cell with respect to the underlying Au(111) substrate. This type of C(60) structure has not been observed previously for multicomponent self-assemblies on a surface. We discuss the possible causes for the formation of this structure as well as the differences between starting on an unannealed SAM and an annealed one. This study demonstrates the capability of functionalized alkanethiol SAMs to control the growth and structure of C(60) islands during annealing depending on the structural changes of the SAM itself; by preannealing the SAM, the motion of the C(60) can be confined and unique structures resulting from interactions between the SAM molecules and C(60) can be produced.     

六味地黄丸三维同步荧光光谱特性的研究

应用英国Edinburgh公司FLS920P荧光光谱仪,实验测定了六味地黄丸组分中熟地黄、山茱萸、山药、泽泻、茯苓、牡丹皮等六味中药的三维同步荧光光谱,并提取荧光特征参数,发现六味中药均为荧光物质,谱图线形各不相同,具有指纹特性,且与药理相吻合。进一步,实验测定六味地黄丸的标准水煎剂及非标准水煎剂的三维同步荧光光谱,发现两者差异明显,可用于区分不同组方的中成药水煎剂。实验与理论均表明：将三维荧光光谱分析方法与同步荧光光谱分析方法相结合,可以进一步提高荧光光谱技术的灵敏度和选择性,在多组分复杂混合物的荧光光谱分析中有明显的优势。因此,本文的工作为建立完整信息中药材指纹图谱提供了一种方便快捷可靠的方法,也可为中成药的品质鉴别和成分分析提供帮助。     

嵌入式三色光变器

为了提升现有导模共振防伪光变器件的性能,设计了一种基于ZnS覆盖膜的一维单周期矩形结构三色光变器.当自然光入射角为45°时,可在0°,58°,90°方位角分别获得相应的蓝、绿、红三色反射峰,对研究结果进行了物理解释.分析并提出了该器件周期、槽深、膜厚以及入射角变化对反射峰的影响规律,对器件的设计、制作和测试有重要指导作用.三色光变器基于简单结构实现方位角调节的自然光三色光变效果,可运用传统激光全息产业的模压和蒸镀工艺进行制作,在光变图像防伪领域有重要应用.     

K-Shell Spectra from CH-Tamped Aluminum Layers Irradiated with Intense Femtosecond Laser Pulses

X-ray spectra of H-like and He-like aluminum ions from aluminum buried in CH layers irradiated with 30fs, 200 TW laser are measured. The electron temperature and density are derived from line ratios of the He-α resonance line to its satellite lines. Typical temperatures of 490-646 eV and electron densities up to 7 × 10^20 cm-3 are obtained. The results show that the electron density increases and temperature decreases with the increasing CH thickness.     

New pyrazinoquinazoline alkaloids Isolated from a culture of Stenotrophomonas maltophilia QB-77

Two new pyrazinoquinazoline alkaloids, epi-fiscalin D (1) and epi-fiscalin E (2), as well as three known analogues, norquinadoline A (3), quinadoline A (4), and fiscalin C (5), were isolated from ethyl acetate extract of the fermentation broth of Stentrophomonas maltophilia QB-77. The structures of new compounds were elucidated on the basis of extensive spectroscopic data analysis including UV, HRESIMS, and 1D and 2D NMR experiments. All the isolated compounds were tested for their in vitro cytotoxicity against five human cancer cell lines (SMMC-7721, MCF-7, HL-60, SW480, and A-549) and antibacterial activities against Bacillus subtilis, Escherichia coli, and Staphylococcus aureus.     

半透明介质中辐射传递方程的反演计算及数值模拟

本文介绍了一侧为半透明、另一侧为非透明界面时一维半透明介质的辐射强度计算式。采用辐射与导热复合换热模型计算半透明介质内温度场。利用已知的温度场求半透明介质的辐射强度一正问题计算。将此辐射强度代入辐射反问题计算模型，引入测量误差，采用Ｃｈａｈｉｎｅ方法及演半透明介质内温度场一反问题计算。数值模拟表明，本文所采用的辐射反演法具有较高的精度及稳定性。     

应用导数荧光光谱和概率神经网络鉴别合成色素

实验测量了食品色素胭脂红、苋菜红、诱惑红和工业色素苏丹红Ⅳ溶液分别在波长为300,400,440和380 nm的光激发下产生的荧光光谱.对这4种红色素的各8个溶液样本选取60个发射波长值所对应的荧光强度作为网络特征参数,训练、建立概率神经网络.据此,对32个色素溶液样本进行种类识别.为解决原始荧光光谱重叠造成识别准确率不高的问题,应用导数荧光光谱,将二阶导数光谱数据作为网络特征参数,建立网络,进行识别,识别准确率达100%.由此,提出了应用二阶导数荧光光谱结合概率神经网络对合成色素方便、快捷、准确地进行种     

温度对碳球形貌及超级电容性能的影响

以三氯乙烷和二氯乙烷为原料, 金属钠为还原剂, 在溶剂热条件(100~150 ℃)下使氯代乙烷中的碳氯键和碳氢键发生断裂制备了碳纳米球, 并对制备的碳纳米球进行了表征. X射线衍射结果表明, 样品为类石墨结构, 衍射信号宽且弱, 表明样品的结晶性较差; 拉曼光谱分析结果也表明样品具有较高的无序度. 样品的SEM与TEM分析结果表明, 在较高的反应温度下, 碳球具有更好的单分散性, 碳球的粒径随温度的升高而增大; 选区电子衍射结果表明碳球内部为无定形的类石墨结构. 以碳纳米球为负极材料的锂离子电池测试结果表明, 50周循环后比容量为941 mA·h/g, 库仑效率接近100%, 放电容量保持率为103.7%, 具有良好的循环稳定性. 测试了不同温度下制备样品的超级电容器性能, 发现120 ℃下制备的碳纳米球具有较高的比电容和较低的内阻值, 比电容高达130 F/g, 经过1000周循环充放电后比电容衰减比例低于14%, 具有较高的稳定性.     

三(三甲基硅烷)亚磷酸酯添加剂改善高镍三元正极材料的高电压循环性能

研究了三(三甲基硅烷)亚磷酸酯(TMSP)添加剂对高镍三元正极材料Li Ni_(0.83)Mn_(0.05)Co_(0.12)O_2(LNMC811)高电压循环性能的影响。结合电化学表征、理论计算、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线光电子能谱(XPS)、X射线衍射(XRD)等方法研究发现,在高电位(4.5 Vvs Li/Li~+)下,TMSP添加剂能够在LNMC811正极表面被氧化分解,生成一层富含导锂离子性能好的硅酸盐和电化学稳定的无机碳酸锂,且电解液主要分解产物(有机碳酸锂和氟化锂)含量较少的正极固体电解质界面(CEI)膜;分析表明覆盖在正极表面的薄而均匀的CEI膜,能够很好的降低充放电过程的极化电压,隔离电解液和正极的接触,减少电解液的分解,抑制金属离子的溶出,稳定正极晶体结构,使LNMC811材料能够在4.5 V(vs Li/Li~+)高电压循环时仍然保持良好的循环性能和倍率性能。     

Controlled release of antibiotics from poly‐ε‐caprolactone/polyethylene glycol wound dressing fabricated by direct‐writing melt electrospinning

Wound dressing, which can release anti‐infectives in a controlled way, is taking an important role in the treatment and recovery of the open wound. An adequate release of antibiotics can prevent infections from microorganisms effectively. Among the new candidates of fabricating base materials for wound dressing, electrospinning fiber mats are attracting numerous attentions for their excellent performance in controlled drug delivery. The drug release behavior of electrospinning fiber mats can be tuned by changing the chemical components and the geometric structures of the mats. In this study, fiber mats with different geometric structures, which composed of poly‐ε‐caprolactone (PCL), polyethylene glycol (PEG), and ciprofloxacin (Cip) with different blending ratios, were successfully fabricated by direct‐writing melt electrospinning, and the release behavior of Cip were subsequently investigated in vitro. The results showed that the addition of PEG improved the hydrophilicity of the mats, which in turn affected the manner of drug release. The presence of PEG changed the releasing mechanism from a non‐Fickian diffusion into Fickian diffusion, which indicated that the diffusion of Cip from the composite fiber mats became the main factor of drug release instead of polymer degradation. Besides, with the same composition but different geometric structures, the drug release behavior is of significant difference. Therefore, all the Cip‐loaded composite fiber mats showed antibacterial activities but with different efficiency. In summary, the release of the drug could be controlled by adding PEG and changing the geometric structures according to the different requirement of wound dressings.