真空中A-B-A绝缘结构的电场分析

提出了一种变插入层电导率和介电常数的三层(A-B-A)绝缘结构。分析了插入层(A)电导率和介电常数对三层绝缘结构真空-绝缘子-阴极三结合点处和真空-插入层绝缘子(A)-主绝缘子(B)三结合点处电场的影响,结果发现通过控制插入层电导率和介电常数可以有效降低真空-绝缘子-阴极三结合点处的电场又不至于使真空-插入层绝缘子-主绝缘子三结合点处电场过高。考虑了介质表面带电的情况,分析插入层介质表面带不同极性电荷对真空-绝缘子-阴极和真空-插入层绝缘子-主绝缘子两个三结合点电场分布的影响。估计了三层绝缘结构真空沿面闪络电压的变化趋势,发现在插入层电导率或介电常数不断增大时,真空沿面闪络电压会呈现先上升后下降,最后趋于稳定。     

色散和非线性效应对高斯脉冲综合影响的理论分析

从光孤子传输所满足的非线性薛定谔方程出发,采用单独分析和综合分析对比,分析了影响高斯脉冲传输的色散、非线性等因素,结果表明:二阶色散参量只会影响脉冲的幅值,对脉冲形状影响不大,而输入脉冲的啁啾则是使脉冲发生形变的主要原因;在啁啾、三阶色散和五阶非线性的共同作用下,它们对脉冲都会产生较大的影响,且存在相互影响和制约作用,在某一临界值,对脉冲存在着较高的压缩增益效应和"整形"作用.从理论上提出了改善高斯光脉冲在光纤中传输特性的解决方案,这对光纤孤子通信的实践过程具有一定的理论借鉴意义.     

Synthesis of Cr2O3/TNTs nanocomposite and its photocatalytic hydrogen generation under visible light irradiation

A novel Cr₂O₃/TNTs nanocomposite was prepared by loaded suitable amount of amorphous Cr₂O₃ on titanate nanotubes (TNTs) via hydrothermal reaction and impregnation process. XRD, SEM and TEM results demonstrated that the amorphous Cr₂O₃ nanoparticles were homogeneously dispersed on the surface of TNTs. The diffuse reflectance UV–visible absorption spectra exhibited that the spectral response of TNTs was extended to visible light region by coupled with Cr₂O₃. The 2.5Cr₂O₃/TNTs nanocomposite showed the highest activity of hydrogen generation by photocatalytic water-splitting under visible light irradiation (λ > 400 nm). The high activity of H₂ evolution for Cr₂O₃/TNTs nanocomposites was associated with the donor level in the forbidden band of TNTs semiconductor provided by dopant Cr³⁺ and a probably photocatalytic mechanism was proposed.     

具有蜂窝内壁的遮光罩杂散光抑制特性分析

将具有蜂窝内壁结构的遮光罩内的杂散光传播分解为蜂窝结构的散射、内壁等效面传播两个层次的行为。通过建立蜂窝结构的等效面各向异性反射模型,采用蒙特卡罗法模拟获得内壁等效面的双向反射分布函数(BRDF)。以此为基础,再次采用蒙特卡罗法模拟遮光罩内壁等效面的杂散光传播过程,分析了该类遮光罩的杂散光抑制特性,并讨论了蜂窝高度和涂层反射率的影响。结果表明,遮光罩内壁蜂窝结构有很好的杂散光抑制作用;蜂窝高度与边长之比δ≥1时,遮光罩的抑制能力不再变化,降低涂层反射率能够有效地增强抑制效果。     

斑头雁脂肪酸的气相色谱-质谱分析

采用冷冻干燥和改进的Bligh-Dyer方法提取脂肪酸,用GC-MS测定了斑头雁腿肌、胸肌组织和卵的脂肪酸组成情况,含有脂肪酸27种,均为长链脂肪酸(C14.0以上).其中饱和脂肪酸19种,占总含量的80.577％-87.701 ％;不饱和脂肪酸8种,占脂肪酸总含量的12.298％-19.423％.在斑头雁的腿肌、胸肌和卵组织中,脂肪酸组成差异不大(P＜0.05).肌肉中含有的脂肪酸种类要多于卵组织中含有的脂肪酸种类.在斑头雁组织含有10种带有甲氧基的脂肪酸,分别占腿肌脂肪酸总量的36.175％,胸肌脂肪酸的10.401％,卵脂肪酸的45.339％.     

Raspberry-like composite polymer particles by self-assemble heterocoagulation based on a charge compensation process

Nano-sized poly(ethylene glycol dimethacrylate-co-acylic acid) (poly(EGDMA-co-AA)) were effectively self-assembled on poly(divinylbenzene-co-styryl methylpyridinium chloride) (poly(DVB-co-StMPyCl)) surfaces to form the raspberry-like composite by a charge compensation mechanism through the affinity complex between carboxylic group and pyridinium group. The effects of pH and salt electrolyte on the morphology of the self-assembled polymer composites were investigated. The resulting heterocoagulates were highly stable in water and acid solution. These heterocoagulates were reversible through the self-assembly in acidic or neutral media and the dissociation in the basic medium due to the charge compensation through the strong affinity complex between hydroxide anion and pyridinium group cation. The resulting heterocoagulates were characterized with scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM) and Fourier transform infrared spectroscopy (FTIR). As a result, a new method for tuning the structure of a charge compensation directed polymer composite was developed.     

Xanthan Sulfuric Acid as an Efficient Biodegradable and Recyclable Catalyst for the One‐Pot Synthesis of α‐Amino Phosphonates

A convenient and efficient procedure for the synthesis of α‐amino phosphonates by a one‐pot, three‐component condensation of aldehydes, amine, and diethyl phosphite in the presence of xanthan sulfuric acid as a bio‐supported catalyst under solvent‐free conditions has been developed. A wide range of α‐amino phosphonates have been obtained in high to excellent yields. Furthermore, the catalyst can be recovered simply and reused several times in subsequent reactions.     

超支化聚负离子/超支化聚正离子自组装膜的制备及反应

自1991年以来,静电吸附自组装已发展成为制备具有特定纳米微结构聚电介质多层超薄膜的有效技术。近年来,由于树枝状聚合物和超支化聚合物独特的物理化学性质,文献中已将它们与线性聚电解质一起用于静电吸附自组装过程,但完全基于超支化聚合物分子间的自组装过程还鲜见报道,超支化聚合物所具有的大量末端和内部（如叔胺基）官能团,不仅可以用于调节自组装行为及组装膜的表面形貌,