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861.
862.
使用Gaussian03程序包中的“对称性匹配簇-组态相互作用”方法、在0.13—2.0nm的核间距范围内利用6-311 G(d,p)基组对7Li2(23Πu)分子的势能曲线进行了计算,同时使用最小二乘法将计算结果拟合成了解析势能函数.利用拟合出的解析势能函数并结合Rydberg-Klein-Rees方法,计算了该态的谐振频率,进而计算了该态的其他光谱常数,分别为Te=3.6701eV,De=1.0764eV,Re=0.3000nm,ωe=285.69cm-1,ωeχe=1.8351cm-1,αe=0.00942cm-1和Be=0.5340cm-1,其中光谱常数Te,De,Re和ωe的值与文献值相符很好.以得到的解析势能函数为基础,通过求解双原子分子核运动的径向Schr dinger方程,发现J=0时7Li2(23Πu)分子存在67个振动态,求出了相应于每一振动态的振动能级、振动经典转折点及转动惯量. 相似文献
863.
J. C. Li J. Zhu Z. J. Peng 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,45(2):325-330
We study analytically and numerically the properties of one-dimensional
chain of cold ions placed in a periodic potential of optical lattice
and global harmonic potential of a trap.
In close similarity with the Frenkel-Kontorova model, a transition from
sliding to pinned phase takes place with the increase of
the optical lattice potential for the density of ions
incommensurate with the lattice period. We show that at zero temperature the quantum
fluctuations lead to a quantum phase transition
and melting of pinned instanton glass phase at large values of dimensional Planck constant.
After melting the ion chain can slide in an optical lattice.
The obtained results are also relevant for a Wigner crystal placed
in a periodic potential. 相似文献
864.
Z. Zhu J. Li A. Brenier G. Jia Z. You X. Lu B. Wu C. Tu 《Applied physics. B, Lasers and optics》2007,86(1):71-75
Yb3+:GdAl3(BO3)4 (hereafter Yb3+:GAB) crystals with large sizes and good optical quality have been grown by the top-seed solution growth (TSSG) method. The polarized absorption and emission spectra have been investigated at room temperature. For the σ-polarization, the intensities of both absorption and emission spectra are stronger than those for the π-polarization, the σ-absorption cross section of Yb3+ in GAB being 3.43×10-20 cm2 at 977 nm, and the σ-emission cross section being 0.98×10-20 cm2 at 1045 nm. The fluorescence lifetime of the 2
F
5/2→2
F
7/2 transition was measured to be 800 μs in the 5% doped sample used for our laser experiments, 993 μs in a 10% doped sample and 569 μs in a 0.5% doped sample. The laser parameters were estimated as: βmin=0.022, Isat=10.4 kW/cm2 and Imin=0.23 kW/cm2. About 0.4 W laseroutput at the wavelength of 1043 nm was achieved when the Yb3+:GAB crystal was pumped by a 974 nm laser diode, with 27.4% slope efficiency. PACS 42.55.-f; 42.70.Hj; 78.20.-e; 81.10.Dn 相似文献
865.
Electroluminescence efficiency in bilayer organic light-emitting devices with LiF/Al cathode 总被引:2,自引:0,他引:2
LI HongJian ZHU RuHui YAN LingLing & ZHANG HaiYan School of Physics Science Technology Central South University Changsha China 《中国科学G辑(英文版)》2007,50(1):31-40
An analytical model to calculate electroluminescence (EL) efficiency of bilayer organic light-emitting devices, considering the influence of introducing LiF insulating buffer layer at metal/organic interface on the barrier height for electron injection, was presented. The relations of EL efficiency versus the applied voltage and injection barrier or internal interfacial barrier or the thickness of organic layer were discussed. The results indicate that: (1) when δ e/δ h < 2, metal/organic (M/O) interface is ohmic contact; when δ e/δ h > 2, M/O becomes contact limited; and when δ e/δ h = 2 (Φ h ~ 0.2 eV, Φ e ~ 0.3 eV), there is a transition from ohmic contact to contact limited; (2) η EL decreases with the increase of δ′e / δ′h; however, when δ′e / δ′h > 2.5 (H ′h~ 0.2 eV, H ′e~ 0.4 eV), the changes of η EL are very small, which shows that η EL is dominated by the carrier’s injection; (3) when increasing Lh/L, η R has a descending trend at low voltage and a rising one at higher voltage. For a given Lh/L, η EL first increases and then decreases with the increasing applied voltage, and as Lh/L further increases, the variation tendency of η EL is more obvious. These conclusions are in agreement with the reported theoretic and experimental results. 相似文献
866.
强外加电场与大调制度下光折变动力学光栅形成研究 总被引:1,自引:0,他引:1
强外加电场与大调制度在光折变效应的研究中已经得到了广泛应用。采用PDECOL算法,严格求解光折变带输运方程,得到外加电场时不同调制度下光折变晶体中随时间变化的空间电荷场、载流子浓度,并讨论了外加电场对它们的影响。通过将物质方程与耦合波方程联立数值求解,可得到光折变光栅形成过程中两波耦合增益系数以及光束条纹相位的变化。模拟结果表明,在强外加电场作用下,两束记录光之间的光强与相位耦合都得到了增强,而原有的解析式忽视了强外加电场与大调制度对空间电荷场相位耦合的影响,此时不再适用。同时发现折射率光栅与记录光束条纹均发生弯曲,并不再保持平行。 相似文献
867.
大气到海洋激光通信信道仿真 总被引:5,自引:0,他引:5
详细分析了蓝绿激光穿过大气海洋信道的信道效应和物理特性,利用理论分析和蒙特卡罗模拟方法完成对光信道仿真。介绍了大气海洋激光通信蒙特卡罗模拟方法及计算步骤。研究了不同厚度云层对光束投影面积的展宽,和光脉冲穿过不同深度海水后的空间分布和时域信号波形,讨论了其不同的展宽机理,并对信道的噪声分布进行了分析。发现云层对光脉冲展宽作用在云层厚度500 m时达到饱和,信号能量的随机起伏随海水深度的增加而增大,但能量分布的半峰全宽并不增加,大气海洋的综合信道效应可以用时延滤波器进行建模。 相似文献
868.
869.
Ab initio calculations on the spectroscopic constants, vibrational levels and classical turning points for the 21∏u state of dimer 7Li2 下载免费PDF全文
The accurate dissociation energy and harmonic frequency for the highly excited 2^1Пu state of dimer ^7Li2 have been calculated using a symmetry-adapted-cluster configuration-interaction method in complete active space. The calculated results are in excellent agreement with experimental measurements. The potential energy curves at numerous basis sets for this state are obtained over a wide internuclear separation range from about 2.4a0 to 37.0a0. And the conclusion is gained that the basis set 6-311++G(d,p) is a most suitable one. The calculated spectroscopic constants De, Re, ωe, ωeχe, ae and Be at 6-311++G(d,p) are 0.9670 eV, 0.3125 nm, 238.6 cm^-1, 1.3705 cm^-1, 0.0039 cm^-1 and 0.4921 cm^-1, respectively. The vibrational levels are calculated by solving the radial SchrSdinger equation of nuclear motion. A total of 53 vibrational levels are found and reported for the first time. The classical turning points have been computed. Comparing with the measurements, in which only the first nine vibrational levels have been obtained so far, the present calculations are very encouraging. A careful comparison of the present results of the parameters De and We with those obtained from previous theories clearly shows that the present calculations are much closer to the measurements than previous theoretical results, thus representing an improvement on the accuracy of the ab initio calculations of the potentials for this state. 相似文献
870.
J.-H. Huang S.-Y. Zhu 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(3):557-575
The normalized second-order
correlation of the emission fields from a driven four-level atomic
ensemble is investigated theoretically by using the state vector
method. The violation of Cauchy-Schwarz inequality, which indicates
the establishment of non-classical correlation between two emission
fields, has been found. The effects of various decays and time delay
on the correlation are discussed in detail, which are helpful in
finding the ways to obtain high non-classical correlation. This
technique for the generation of non-classical light is operable
based on the current experimental technology and will lead to some
potential applications in quantum information science. 相似文献