全文获取类型
收费全文 | 19863篇 |
免费 | 3410篇 |
国内免费 | 4269篇 |
专业分类
化学 | 16048篇 |
晶体学 | 421篇 |
力学 | 1119篇 |
综合类 | 300篇 |
数学 | 2319篇 |
物理学 | 7335篇 |
出版年
2024年 | 47篇 |
2023年 | 366篇 |
2022年 | 637篇 |
2021年 | 750篇 |
2020年 | 860篇 |
2019年 | 912篇 |
2018年 | 735篇 |
2017年 | 856篇 |
2016年 | 911篇 |
2015年 | 1025篇 |
2014年 | 1234篇 |
2013年 | 1595篇 |
2012年 | 1735篇 |
2011年 | 1721篇 |
2010年 | 1520篇 |
2009年 | 1432篇 |
2008年 | 1480篇 |
2007年 | 1255篇 |
2006年 | 1214篇 |
2005年 | 1114篇 |
2004年 | 961篇 |
2003年 | 836篇 |
2002年 | 840篇 |
2001年 | 745篇 |
2000年 | 578篇 |
1999年 | 415篇 |
1998年 | 264篇 |
1997年 | 189篇 |
1996年 | 229篇 |
1995年 | 155篇 |
1994年 | 165篇 |
1993年 | 155篇 |
1992年 | 117篇 |
1991年 | 121篇 |
1990年 | 77篇 |
1989年 | 57篇 |
1988年 | 40篇 |
1987年 | 46篇 |
1986年 | 44篇 |
1985年 | 22篇 |
1984年 | 17篇 |
1983年 | 22篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1959年 | 6篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
41.
The gas‐transport properties of poly[2,6‐toluene‐2,2‐bis(3,4‐dicarboxylphenyl)hexafluoropropane diimide] (6FDA‐2,6‐DAT) have been investigated. The sorption behavior of dense 6FDA‐2,6‐DAT membranes is well described by the dual‐mode sorption model and has certain relationships with the critical temperatures of the penetrants. The solubility coefficient decreases with an increase in either the pressure or temperature. The temperature dependence of the diffusivity coefficient increases with an increase in the penetrant size, as the order of the activation energy for the diffusion jump is CH4 > N2 > O2 > CO2. Also, the average diffusion coefficient increases with increasing pressure for all the gases tested. As a combined contribution from sorption and diffusion, permeability decreases with increases in the pressure and the kinetic diameter of the penetrant molecules. Even up to 32.7 atm, no plasticization phenomenon can be observed on flat dense 6FDA‐2,6‐DAT membranes from their permeability–pressure curves. However, just as for other gases, the absolute value of the heat of sorption of CO2 decreases with increasing pressure at a low‐pressure range, but the trend changes when the feed pressure is greater than 10 atm. This implies that CO2‐induced plasticization may occur and reduce the positive enthalpy required to create a site into which a penetrant can be sorbed. Therefore, a better diagnosis of the inherent threshold pressure for the plasticization of a glassy polymer membrane may involve examining the absolute value of the heat of sorption as a function of pressure and identifying the turning point at which the gradient of the absolute value of the heat of sorption against pressure turns from a negative value to a positive one. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 354–364, 2004 相似文献
42.
用量子化学从头算方法在B3LYP/6 311G 的水平上 ,研究了RuH2 和RuN2 可能的电子组态和光谱性质 .结果表明 ,RuH2 的3 B2 和5Σ-态对应于静电作用的物理吸附态 .RuN2 的一重态和三重态的计算结果跟钌单晶面上的实验值相接近 .而RuN2 在C∞v对称性时 ,五重态5Σ-的计算频率比实验值稍低 .在C2v对称性时 ,五重态的计算频率值则更低 ,3 B2 和5A1态不能稳定存在 相似文献
43.
44.
YAN Xiaomin ZHAO Lin SHAO Jianhui TAN Xin SONG Zhengxiao School of Chemical Engineering Technology Tianjin University Tianjin China Slichem Liquid Material Co. Ltd. Shijiazhuang China 《Chinese Journal of Reactive Polymers》2004,(Z1)
1. INTRODUCTION Methionine, namely 2-amido-4-thiomethyl butyric acid with a structure of CH3SCH2CH2CHCOOH, is one of the essential amino acids and has two natural enantionmers, D and L-methionine. The mixture of L- and D-isomers can be used as analeptics or nutritive additives to maintain the equilibrium of amino acids of feed [1,2]. L-methionine can release active methyl and accelerate the synthesis of choline, which further speeds up the conversion of the lipid accumulated in liv… 相似文献
45.
Styrene (STY) is now produced industrially in fairly large quantities by the dehydrogenation of ethylbenzene (EB) using promoted iron oxide catalyst with superheated steam.In this case, small amount of carbon dioxide formed as a by-product was known to inhibit the catalytic activity of commercial catalyst. Recently, there have been some reports which carbon dioxide showed positive effects to promote catalytic activities on the reaction over several catalysts.In this study, we attempted to combine the dehydrogenation of EB to STY with the carbon dioxide shift-reaction. The combine reaction (EB + CO2 → STY + H2O + CO) can be considered as one of the ways of using CO2 resources and can yield simultaneously STY and Carbon oxide.Alumina oxide catalysts such as Al2O3, Na2O/Al2O3 and K2O/Al2O3 were prepared by the usual impregnation method with an aqueous solution of NaNO3 and KNO3, and then calcined at 650℃ for 5 h in a stream of air. The reaction condition is 600℃, flow of CO2 38ml/mon and space velocity (EB) 1.28h-1. 相似文献
46.
FengSHI HongYangLI XiaoJunPENG RongZHANG XiaoQiangCHEN JiangLiFAN LiChengSUN 《中国化学快报》2004,15(12):1407-1410
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied. 相似文献
47.
JianXinCAO YiFengWANG GuoFangLAI ShiDeLUO 《中国化学快报》2004,15(7):797-800
From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis. 相似文献
48.
Two Convergence Problems for Monotone Sequences 总被引:1,自引:0,他引:1
Eight measures of rate of convergence of monotone sequences of real numbers have been proposed and discussed in a paper by Beyer, Ebanks, and Qualls (Acta Appl. Math. 20 (1990), 267–284). These rates arose in discussions of dynamical systems. In the comparisons of these rates, two problems remained. A complete answer is given to one of the problems and a partial answer is given to the other problem. 相似文献
49.
50.
A simple model has been developed to describe the Zeeman patterns of far-infrared laser magnetic resonance spectra of the monobromomethyl radical CH2Br observed at 447.3 and 671.1μm. A satisfactory agreement between the experimental spectra of the radical and their simulation with this simple model has been achieved. This approach can be used to gain further information about the structure and the spectrum of this interesting radical. 相似文献