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61.
Styrene (STY) is now produced industrially in fairly large quantities by the dehydrogenation of ethylbenzene (EB) using promoted iron oxide catalyst with superheated steam.In this case, small amount of carbon dioxide formed as a by-product was known to inhibit the catalytic activity of commercial catalyst. Recently, there have been some reports which carbon dioxide showed positive effects to promote catalytic activities on the reaction over several catalysts.In this study, we attempted to combine the dehydrogenation of EB to STY with the carbon dioxide shift-reaction. The combine reaction (EB + CO2 → STY + H2O + CO) can be considered as one of the ways of using CO2 resources and can yield simultaneously STY and Carbon oxide.Alumina oxide catalysts such as Al2O3, Na2O/Al2O3 and K2O/Al2O3 were prepared by the usual impregnation method with an aqueous solution of NaNO3 and KNO3, and then calcined at 650℃ for 5 h in a stream of air. The reaction condition is 600℃, flow of CO2 38ml/mon and space velocity (EB) 1.28h-1. 相似文献
62.
Zhong Hong YAN Chun Hao YANG Xi Han WU Yu Yuan XIEDivision of Chemistry Shanghai Second Medical University Shanghai Sate Key Laboratory of Drug Research Shanghai Institute of Materia Medica Shanghai Institutesfor Biological Sciences Shanghai 《中国化学快报》2004,(4)
The first and facile synthesis of (±)syringaresinol was described. 相似文献
63.
JianXinCAO YiFengWANG GuoFangLAI ShiDeLUO 《中国化学快报》2004,15(7):797-800
From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis. 相似文献
64.
65.
A simple model has been developed to describe the Zeeman patterns of far-infrared laser magnetic resonance spectra of the monobromomethyl radical CH2Br observed at 447.3 and 671.1μm. A satisfactory agreement between the experimental spectra of the radical and their simulation with this simple model has been achieved. This approach can be used to gain further information about the structure and the spectrum of this interesting radical. 相似文献
66.
本文提出了一类特殊的n人合作对策模型─—弱1—凸对策,研究了弱1—凸对策的解的性质,并证明弱1—凸对策的解满足所有常见的公理化特征. 相似文献
68.
A Pair of Dimeric Stilbene Epimers from Gnetum Montanum 总被引:1,自引:0,他引:1
GnetummontanumofgnetaceaisdistributedinsouthernChina.AsaChinesefOlkmedicine,itslianasareusedtotreatbronchitisandarthritis'.Previousinvestigationofthisspeciesledtotheisolationofsomealkaloidsanddibenzyletherde,i.ati.es2.lnourstudies,tenknowncomponentsincludingresveratrol,isohapontigenin,daucosterol,6-sitosterol,stearicacid,gnetifolinE,gnetol,isorhapontigenin-3-O-6-glucopyra(-)E-viniferinandgnetifolinCwereisolatedfromthesameresource.Atthesametime,apairoftraceepimerswereobtained.Thisisthefirste… 相似文献
69.
[1]M.Alford,K.Rajagopal,and F.Wilczek,Phys.Lett.B 422 (1998) 247; Nucl.Phys.B 537 (1999) 443.
[2]M.Gyulassy and L.McLerran,arXiv:nucl-th/0405013;E.V.Shuryak,arXiv:hep-ph/0405066.
[3]K.Rajagopal and F.Wilczek,hep-ph/0011333.
[4]M.Alford,Chris Kouvaris,and K.Rajagopal,hepph/0406137.
[5]Y.Nambu and G.Jona-Lasinio,Phys.Rev.122 (1961)345.
[6]R.T.Cahill and C.D.Roberts,Phys.Rev.D 32 (1985)2419.
[7]R.T.Cahill and Susan M.Ganner,hep-ph/9812491.
[8]A.W.Steiner,S.Reddy,and M.Prakash,Phys.Rev.D 66 (2002) 094007.
[9]P.Amore,M.C.Birse,J.A.McGovern,and N.R.Walet,Phys.Rev.D 65 (2002) 074005.
[10]M.Alford and K.Rajagopal,JHEP 0206 (2002) 031.
[11]Xiao-Fu Li,Yu-Xin Liu,Hong-Shi Zong,and En-GuangZhao,Phys.Rev.C 58 (1998) 1195.
[12]H.Reinhardt,Phys.Lett.B 244 (1990) 2.
[13]Steven Weinberg,The Quantum Theory of Fields,Vol.2,Cambridge University Press,Cambridge (1996) p.348. 相似文献
70.
Based on the effective-field theory with self-spin correlations and the differential operator technique,physical properties of the spin-2 system with biaxial crystal field on the simple cubic, body-centered cubic, as well as faced-centered lattice have been studied. The influences of the external longitudinal magnetic field on the magnetization,internal energy, specific heat, and susceptibility have been discussed in detail. The phenomenon that the magnetization in the ground state shows quantum effects produced by the biaxial transverse crystal field has been found. 相似文献