全文获取类型
收费全文 | 66032篇 |
免费 | 12970篇 |
国内免费 | 6378篇 |
专业分类
化学 | 62334篇 |
晶体学 | 831篇 |
力学 | 2496篇 |
综合类 | 360篇 |
数学 | 5386篇 |
物理学 | 13973篇 |
出版年
2024年 | 123篇 |
2023年 | 654篇 |
2022年 | 1203篇 |
2021年 | 1414篇 |
2020年 | 2462篇 |
2019年 | 3775篇 |
2018年 | 2100篇 |
2017年 | 1818篇 |
2016年 | 4662篇 |
2015年 | 4855篇 |
2014年 | 5138篇 |
2013年 | 6178篇 |
2012年 | 5563篇 |
2011年 | 4808篇 |
2010年 | 4759篇 |
2009年 | 4571篇 |
2008年 | 4241篇 |
2007年 | 3464篇 |
2006年 | 3161篇 |
2005年 | 3053篇 |
2004年 | 2573篇 |
2003年 | 2273篇 |
2002年 | 3042篇 |
2001年 | 2300篇 |
2000年 | 1938篇 |
1999年 | 1038篇 |
1998年 | 557篇 |
1997年 | 464篇 |
1996年 | 490篇 |
1995年 | 368篇 |
1994年 | 342篇 |
1993年 | 279篇 |
1992年 | 249篇 |
1991年 | 254篇 |
1990年 | 187篇 |
1989年 | 160篇 |
1988年 | 109篇 |
1987年 | 95篇 |
1986年 | 104篇 |
1985年 | 77篇 |
1984年 | 66篇 |
1983年 | 59篇 |
1982年 | 34篇 |
1981年 | 34篇 |
1980年 | 33篇 |
1979年 | 21篇 |
1978年 | 24篇 |
1977年 | 25篇 |
1976年 | 23篇 |
1973年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
91.
The implementation of a nonzero-order joint transform correlator using the double port Mach-Zehnder interferometric technique is proposed and demonstrated. This approach provides on-line processing for directly removing the zero-order components of a joint power spectrum in one step and performs the nonzero-order optical correlation. Experimental results are presented and discussed. 相似文献
92.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
93.
This study investigates a holographic recording effect of biphotonic polarization gratings (BPGs) written on dye-doped liquid crystal (DDLC) films. One linearly polarized green light (λG = 514.5 nm) and a polarization-modulated interference pattern formed by two mutually coherent orthogonal (±45° with respect to the polarization of the green light) polarized red lights simultaneously excite the DDLC films to generate a BPG. The formation of BPGs depends primarily on the dichroism of the dye molecules and a sequence of mechanisms: photoisomerization, anisotropic adsorption and inhibition of dye adsorption. The cis-isomer absorbance-modulated distribution associated with the red polarization-modulation pattern induces the dye adsorption-modulated pattern, in turn, yielding the permanent BPG which generates a modulated twisted nematic (TN) structure pattern in the sample. It is found that each BPG is verified to be electrically switchable and thermally erasable. The switching time is in the order of milliseconds. Additionally, the recording time to form a BPG decreases with increasing intensity of the green pump beam. 相似文献
94.
Jian‐guo Tang 《Mathematical Methods in the Applied Sciences》2006,29(11):1327-1338
An implicit iterative method is applied to solving linear ill‐posed problems with perturbed operators. It is proved that the optimal convergence rate can be obtained after choosing suitable number of iterations. A generalized Morozov's discrepancy principle is proposed for the problems, and then the optimal convergence rate can also be obtained by an a posteriori strategy. The convergence results show that the algorithm is a robust regularization method. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
95.
This paper is devoted to the proof of almost global existence results for Klein‐Gordon equations on Zoll manifolds (e.g., spheres of arbitrary dimension) with Hamiltonian nonlinearities, when the Cauchy data are smooth and small. The proof relies on Birkhoff normal form methods and on the specific distribution of eigenvalues of the Laplacian perturbed by a potential on Zoll manifolds. © 2007 Wiley Periodicals, Inc. 相似文献
96.
97.
In the present paper, a Lotka–Volterra type mutualism system with several delays is studied. Some new and interesting sufficient conditions are obtained for the global existence of positive periodic solutions of the mutualism system. Our method is based on Mawhin’s coincidence degree and novel estimation techniques for the a priori bounds of unknown solutions. Our results are different from the existing ones such as those in of Yang et al. [F. Yang, D. Jiang, A. Ying, Existence of positive solution of multidelays facultative mutualism system, J. Eng. Math. 3 (2002) 64–68] and Chen et al. [F. Chen, J. Shi, X. Chen, Periodicity in a Lotka–Volterra facultative mutualism system with several delays, J. Eng. Math. 21 (3) (2004) 403–409]. 相似文献
98.
R. Jayakumar Y.‐S. Lee S. Nanjundan 《Journal of polymer science. Part A, Polymer chemistry》2003,41(18):2865-2878
The calcium salt of mono(hydroxyethoxyethyl)phthalate [Ca(HEEP)2] was synthesized by the reaction of diethylene glycol, phthalic anhydride, and calcium acetate. Calcium‐containing poly(urethane ether)s (PUEs) were synthesized by the reaction of hexamethylene diisocyanate (HMDI) or tolylene 2,4‐diisocyanate (TDI) with a mixture of Ca(HEEP)2 and poly(ethylene glycol) (PEG300 or PEG400) with di‐n‐butyltin dilaurate as a catalyst. A series of calcium‐containing PUEs of different compositions were synthesized with Ca(HEEP)2/PEG300 (or PEG400)/diisocyanate (HMDI or TDI) molar ratios of 2:2:4, 3:1:4, and 1:3:4 so that the coating properties of the PUEs could be studied. Blank PUEs without calcium‐containing ionic diols were also prepared by the reaction of PEG300 or PEG400 with HMDI or TDI. The PUEs were well characterized by Fourier transform infrared, 1H and 13C NMR, solid‐state cross‐polarity/magic‐angle‐spinning 13C NMR, viscosity, solubility, and X‐ray diffraction studies. The thermal properties of the polymers were also studied with thermogravimetric analysis and differential scanning calorimetry. The PUEs were applied as top coats on acrylic‐coated leather, and their physicomechanical properties were also studied. The coating properties of PUEs, such as the tensile strength, elongation at break, tear strength, water vapor permeability, flexing endurance, cold crack resistance, abrasion resistance, color fastness, and adhesive strength, were better than the standard values. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2865–2878, 2003 相似文献
99.
Large deviations for random walks in a mixing random environment and other (non‐Markov) random walks
F. Rassoul‐Agha 《纯数学与应用数学通讯》2004,57(9):1178-1196
We extend a recent work by S. R. S. Varadhan [8] on large deviations for random walks in a product random environment to include more general random walks on the lattice. In particular, some reinforced random walks and several classes of random walks in Gibbs fields are included. © 2004 Wiley Periodicals, Inc. 相似文献
100.
Franck D'Agosto Marie‐Thrse Charreyre Christian Pichot Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1188-1195
A method is described for synthesizing latex particles with anchored hairs by the grafting of hydrophilic chains, synthesized by reversible addition–fragmentation chain transfer, onto functionalized latex particles. These have the potential to bind biologically active species. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1188–1195, 2003 相似文献