非线性光学晶体多功能测试系统

采用现代激光技术和光电子技术,根据晶体光学原理与非线性光学晶体的习性,设计了非线性光学晶体多功能测试系统.本系统具有结构紧凑,稳定可靠,一机多能的测试功能.     

高功率激光器喷雾冷却的实验研究

以水为冷却介质,采用Spray公司的TG0.3机械雾化实心圆锥喷嘴,在体积通量为0.044,0.049和0.053 m3/(m2·s)情况下,对刻有不同微结构槽道冷却面的无沸腾区换热性能进行实验研究。结果表明：刻有微结构的表面可明显增强换热效果;壁面刻有高为0.2 mm的微结构槽道且壁面温度为52 ℃时,体积通量为0.044 m3/(m2·s则热流可达260 W/cm2,通量为0.053 m3/(m2·s则散热功率高达376 W/cm2,完全可以满足当前高功率激光器的散热需求。对于光滑面以及槽肋高为0.1和0.2 mm的换热面,其换热能力随着体积通量的增加而增强;换热面高度为0.4 mm时,通量对换热的影响变得较微弱。微结构槽道不仅增加了换热面积,还有利于液膜扩散,减小液膜厚度,增强换热。在三种不同的流量通量下,高度为0.2 mm的微结构槽道换热性能最佳。     

Calculation of the vibrationally non-relaxed photo-induced electron transfer rate constant in dye-sensitized solar cells

In this paper we shall show how to calculate the single vibronic-level electron-transfer rate constant, which will be compared with the thermal averaged one. To apply the theoretical results to the dye-sensitized solar cells, we use a simple model to describe how we model the final state of the electron-transfer process. Numerical calculations will be performed to demonstrate the theoretical results.     

A series of dithienobenzodithiophene based small molecules for highly efficient organic solar cells

Three acceptor-donor-acceptor (A-D-A) small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene as the central building block, octyl cyanoacetate, 3-octylrhodanine and thiobarbituric acid as the end groups were designed and synthesized as donor materials in solution-processed photovoltaic cells (OPVs). The impacts of these different electron withdrawing end groups on the photophysical properties, energy levels, charge carrier mobility, morphologies of blend films, and their photovoltaic properties have been systematically investigated. OPVs device based on DRDTBDT gave the best power conversion efficiency (PCE) of 8.34%, which was significantly higher than that based on DCAODTBDT (4.83%) or DTBDTBDT (3.39%). These results indicate that rather dedicated and balanced consideration of absorption, energy levels, morphology, mobility, etc. for the design of small-molecule-based OPVs (SM-OPVs) and systematic investigations are highly needed to achieve high performance for SM-OPVs.     

Analytical study of charged boson stars with large scalar self-couplings

We give good approximate analytic solutions for spherical charged boson stars in the large scalar-self-coupling limit in general relativity. We show that if the charge e and mass m of the scalar field nearly satisfy the critical relation \(e^2\approx Gm^2\) (where G is the Newton constant), our analytic expressions for stable solutions agree well with the numerical solutions.     

Giant molecular shape amphiphiles based on polystyrene-hydrophilic [60]fullerene conjugates: click synthesis, solution self-assembly, and phase behavior

This paper reports a comprehensive study on the synthesis and self-assembly of two model series of molecular shape amphiphiles, namely, hydrophilic [60]fullerene (AC(60)) tethered with one or two polystyrene (PS) chain(s) at one junction point (PS(n)-AC(60) and 2PS(n)-AC(60)). The synthesis highlighted the regiospecific multiaddition reaction for C(60) surface functionalization and the Huisgen 1,3-dipolar cycloaddition between alkyne functionalized C(60) and azide functionalized polymer to give rise to shape amphiphiles with precisely defined surface chemistry and molecular topology. When 1,4-dioxane/DMF mixture was used as the common solvent and water as the selective solvent, these shape amphiphiles exhibited versatile self-assembled micellar morphologies which can be tuned by changing various parameters, such as molecular topology, polymer tail length, and initial molecular concentration, as revealed by transmission electron microscopy and light scattering experiments. In the low molecular concentration range of equal or less than 0.25 (wt) %, micellar morphology of the series of PS(n)-AC(60) studied was always spheres, while the series of 2PS(n)-AC(60) formed vesicles. Particularly, PS(44)-AC(60) and 2PS(23)-AC(60) are synthesized as a topological isomer pair of these shape amphiphiles. PS(44)-AC(60) formed spherical micelles while 2PS(23)-AC(60) generated bilayer vesicles under identical conditions. The difference in the self-assembly of PS(n)-AC(60) and 2PS(n)-AC(60) was understood by the molecular shape aspect ratio. The stretching ratio of PS tails decreased with increasing PS tail length in the spherical micelles of PS(n)-AC(60), indicating a micellar behavior that changes from small molecular surfactant-like to amphiphilic block copolymer-like. For the series of PS(n)-AC(60) in the high molecular concentration range [>0.25 (wt) %], their micellar morphological formation of spheres, cylinders, and vesicles was critically dependent upon both the initial molecular concentration and the PS tail length. On the other hand, the series of 2PS(n)-AC(60) remained in the state of bilayer vesicles in the same concentration range. Combining both of the experimental results obtained in the low and high molecular concentrations, a systematic morphological phase diagram was constructed for the series of PS(n)-AC(60) with different PS tail lengths. The versatile and concentration-sensitive phase behaviors of these molecular shape amphiphiles are unique and have not been systematically explored in the traditional surfactants and block copolymers systems.     

Complete Fusion Excitation Function for the 16O+natS Reaction

The complete fusion excitation function for the ¹⁶O+^natS reaction has been measured in the range of 50-75 MeV with a step of 1.0MeV by using 1a position sensitive △E-E telescope system. The model parameters have been extracted from data analysis.The striking gross structure of the excitation function has been observed. The energies of peaks are at ECM=38,43 and 48 MeV respectively.     

C12A7-Mg催化剂水蒸汽重整生物油、石脑油和CH4制氢

Hydrogen production by catalytic steam reforming of the bio-oil, naphtha, and CH4 was investigated over anovel metal-doped catalyst of (Ca24Al28O64)4+￠4O-/Mg (C12A7-Mg). The catalytic steam reforming wasinvestigated from 250 to 850 ±C in the ˉxed-bed continuous °ow reactor. For the reforming of bio-oil, theyield of hydrogen of 80% was obtained at 750 ±C, and the maximum carbon conversion is nearly close to95% under the optimum steam reforming condition. For the reforming of naphtha and CH4, the hydrogenyield and carbon conversion are lower than that of bio-oil at the same temperature. The characteristics ofcatalyst were also investigated by XPS. The catalyst deactivation was mainly caused by the deposition ofcarbon in the catalytic steam reforming process.     

垒下熔合裂变中观察到的异常

测量了¹⁶O+²³²Th、²³⁸U和¹⁹F+²³²Th近垒和垒下熔合裂变截面以及碎片角分布.包含靶核静态形变的耦合道理论解释了垒下熔合截面增强,预言了复合核系统自旋分布展宽.而实验上观察到的碎片角分布各向异性明显与裂变统计理论的预言不一致.     

Efficient Dynamic Nuclear Polarization at 800 MHz/527 GHz with Trityl‐Nitroxide Biradicals

Cross‐effect (CE) dynamic nuclear polarization (DNP) is a rapidly developing technique that enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE DNP experiments at 211, 600, and 800 MHz using a new series of biradical polarizing agents referred to as TEMTriPols, in which a nitroxide (TEMPO) and a trityl radical are chemically tethered. The TEMTriPol molecule with the optimal performance yields a record ¹H NMR signal enhancement of 65 at 800 MHz at a concentration of 10 mM in a glycerol/water solvent matrix. The CE DNP enhancement for the TEMTriPol biradicals does not decrease as the magnetic field is increased in the manner usually observed for bis‐nitroxides. Instead, the relatively strong exchange interaction between the trityl and nitroxide moieties determines the magnetic field at which the optimum enhancement is observed.