Enhancing effect of boron trifluoride diethyl etherate electrolytes on capacitance performance of electropolymerized poly[poly(<Emphasis Type="Italic">N</Emphasis>-vinyl-carbazole)] films

In this paper, poly[poly(N-vinyl-carbazole)] (PPVK) films electrodeposited in tetrahydrofuran (THF) containing 12 % boron trifluoride diethyl etherate (BFEE) were studied as electrode active material for supercapacitors. The morphology and thermal property were characterized by SEM, atomic force microscopy (AFM), and thermogravimetry (TG), respectively. The electrochemical capacitive behaviors of the PPVK films were also investigated by cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy. The electrochemical results showed that the specific capacitance of PPVK films in CH₃CN solution was about 126 mF cm^?2 at 1.5 mA cm^?2 and the capacitance retention was only 14.4 % after 1000 cycles. It was exciting to improve the specific capacitance up to 169.3 mF cm^?2 at 1.5 mA cm^?2 and to make the cyclic stability increase to 81.8 % capacitance retention after 5000 cycles when the equivalent BFEE was added into the CH₃CN solution containing 0.05 M Bu₄NBF₄ electrolyte. These results clearly demonstrated that BFEE was an efficient promoter for the enhancement of the capacitance performance of PPVK films. Therefore, with the help of BFEE electrolyte, the PPVK films have potential application as capacitive materials in high-performance energy storage devices.     

Construction of Renewable Superhydrophobic Surfaces via Thermally Induced Phase Separation and Mechanical Peeling

We report a simple preparation method of a renewable superhydrophobic surface by ther-mally induced phase separation (TIPS) and mechanical peeling. Porous polyvinylidene fluo-ride (PVDF) membranes with hierarchical structures were prepared by a TIPS process under different cooling conditions, which were confirmed by scanning electron microscopy and mer-cury intrusion porosimetry. After peeling off the top layer, rough structures with hundreds of nanometers to several microns were obtained. A digital microscopy determines that the surface roughness of peeled PVDF membranes is much higher than that of the original PVDF membrane, which is important to obtain the superhydrophobicity. Water contact angle and sliding angle measurements demonstrate that the peeled membrane surfaces display super-hydrophobicity with a high contact angle (152°) and a low sliding angle (7.2°). Moreover, the superhydrophobicity can be easily recovered for many times by a simple mechanical peel-ing, identical to the original superhydrophobicity. This simple preparation method is low cost, and suitable for large-scale industrialization, which may offer more opportunities for practical applications.     

Recent development of efficient electrocatalysts derived from porous organic polymers for oxygen reduction reaction

Porous organic polymers (POPs) have recently emerged as promising candidates for catalyzing oxygen reduction reaction (ORR). Compared to conventional Pt-based ORR catalysts, these newly developed porous materials, including both non-precious metal based catalysts and metal-free catalysts, are more sustainable and cost-effective. Their porous structures and large surface areas facilitate mass and electron transport and boost the ORR kinetics. This mini-review will give a brief summary of recent development of POPs as electrocatalysts for the ORR. Some design principles, different POP structures, key factors for their ORR catalytic performance, and outlook of POP materials will be discussed.     

一类弱奇性Volterra积分微分方程的级数展开数值解法

本文考察了一类弱奇性积分微分方程的级数展开数值解法,并给出了相应的收敛性分析.理论分析结果表明,若用已知函数的谱配置多项式逼近已知函数,那么方程的数值解以谱精度逼近方程的真解.数值实验数据也验证了这一理论分析结果.     

Non-parametric clustering over user features and latent behavioral functions with dual-view mixture models

We present a dual-view mixture model to cluster users based on their features and latent behavioral functions. Every component of the mixture model represents a probability density over a feature view for observed user attributes and a behavior view for latent behavioral functions that are indirectly observed through user actions or behaviors. Our task is to infer the groups of users as well as their latent behavioral functions. We also propose a non-parametric version based on a Dirichlet Process to automatically infer the number of clusters. We test the properties and performance of the model on a synthetic dataset that represents the participation of users in the threads of an online forum. Experiments show that dual-view models outperform single-view ones when one of the views lacks information.     

一种结构故障的振动诊断法

文章分析了振动参数对结构故障的敏感度，选取对故障比较敏感、又能反映结构动力特性的频响函数，作为诊断故障的参数，采用了最小二乘辨识、卡尔曼滤波、自适应滤波等方法，进行故障诊断、仿真试验的结果表明，本文提出的方法可行，且有一定精度，实物试验结果表明，当局部刚度下降5%时，运用本文方法可诊断出故障。     

提高光电编码器分辨率的位置细分方法的研究

本文提出一种实用可行的光电码盘分辨率的位置细分方法——幅值细分方法，从原理上进行了深入的分析，并设计了硬件电路，同时采用软件算法解决了细分中存在的随机干扰和非线性补偿问题。这种方法具有实时、细分数高且任意可调的特点。     

SYNTHESIS AND CHARACTERIZATION OF SURFACE-HYPERBRANCHED MAGNETITE NANOPARTICLE FOR BOVINE SERUM ALBUMIN IMMOBILIZATION

A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency. The amount of immobilized bovine serum albumin (BSA) on the surface-hyperbranched magnetite nanoparticle was up to 2.5 times as much as that of magnetite nanoparticle modified with only amino silane.     

核电工程地质（二）

核电工程地质（二）古迅（中国科学院地质研究所北京100029）3能动断层及其调查与评价3.1关于活动断层断层活动是现代地壳活动最为强烈的一种构造作用,因此,活动断层作为说明地壳的现代活动性的一个重要的地质标志。     

结构形状优化设计数值方法的研究和应用

本文论述了连续体结构形状优化设计数值方法的研究和应用进展,讨论了结构模型化、灵敏度分析、优化方法改进、优化实用软件开发以及同CAD技术相结合等问题,介绍了在结构优化设计软件MCADS中采用的方法,并通过工程实例说明了结构形状优化设计的应用及其价值。