全文获取类型
收费全文 | 30965篇 |
免费 | 564篇 |
国内免费 | 699篇 |
专业分类
化学 | 12150篇 |
晶体学 | 317篇 |
力学 | 1490篇 |
综合类 | 45篇 |
数学 | 9277篇 |
物理学 | 8949篇 |
出版年
2023年 | 88篇 |
2022年 | 126篇 |
2021年 | 138篇 |
2020年 | 178篇 |
2019年 | 192篇 |
2018年 | 1321篇 |
2017年 | 1541篇 |
2016年 | 836篇 |
2015年 | 697篇 |
2014年 | 627篇 |
2013年 | 844篇 |
2012年 | 3342篇 |
2011年 | 2472篇 |
2010年 | 1936篇 |
2009年 | 1682篇 |
2008年 | 692篇 |
2007年 | 715篇 |
2006年 | 699篇 |
2005年 | 4508篇 |
2004年 | 3966篇 |
2003年 | 2355篇 |
2002年 | 548篇 |
2001年 | 341篇 |
2000年 | 141篇 |
1999年 | 196篇 |
1998年 | 128篇 |
1997年 | 76篇 |
1996年 | 59篇 |
1995年 | 54篇 |
1994年 | 50篇 |
1992年 | 178篇 |
1991年 | 159篇 |
1990年 | 142篇 |
1989年 | 113篇 |
1988年 | 106篇 |
1987年 | 66篇 |
1986年 | 50篇 |
1985年 | 41篇 |
1984年 | 33篇 |
1983年 | 31篇 |
1979年 | 35篇 |
1976年 | 83篇 |
1975年 | 37篇 |
1974年 | 41篇 |
1973年 | 48篇 |
1972年 | 40篇 |
1970年 | 34篇 |
1969年 | 38篇 |
1968年 | 35篇 |
1966年 | 37篇 |
排序方式: 共有10000条查询结果,搜索用时 250 毫秒
101.
102.
Xiu‐Li Wang Ke‐Ke Yang Yu‐Zhong Wang Zhi‐Xuan Zhou Yong‐Dong Jin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(14):3417-3422
A new biodegradable starch graft copolymer, starch‐g‐poly(1,4‐dioxan‐2‐one), was synthesized through the ring‐opening graft polymerization of 1,4‐dioxan‐2‐one onto a starch backbone. The grafting reactions were conducted with various 1,4‐dioxan‐2‐one/starch feed ratios to obtain starch‐g‐poly(1,4‐dioxan‐2‐one) copolymers with various poly(1,4‐dioxan‐2‐one) graft structures. The microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was characterized in detail with one‐ and two‐dimensional NMR spectroscopy. The effect of the feed composition on the resulting microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was investigated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3417–3422, 2004 相似文献
103.
Katalin E. Kövér Dušan Uhr?&#x;n Victor J. Hruby 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,130(2):162-168
A pulsed field gradient version of the sensitivity-enhanced 2D TOCSY experiment is proposed which yields high-quality spectra with improved sensitivity and a minimum of two scans pert1increment. For rapid acquisition of 1D TOCSY spectra, the 1D DPFGSE–TOCSY experiment was modified to include phase-encoded multiple-selective excitation followed by a simple spectral editing. Combination of these two building blocks is used in a sensitivity-enhanced 2D analog of the 3D TOCSY–TOCSY experiment which provides an efficient tool for resolving severely overlapped signals of oligomers in short experimental time. 相似文献
104.
超重元素(新核素)合成研究进展情况分析和展望 总被引:2,自引:0,他引:2
本文在介绍和分析国际、国内在超重元素(新核素)合成实验研究与理论研究进展情况的基础上对我国今后如何从理论与实验的结合上开展超重元素(核)合成研究工作提出一些看法和建议,提供讨论。 相似文献
105.
商标数据库存储模式及其检索算法研究 总被引:6,自引:0,他引:6
依据商标专家的先验知识和基于内容的图像检索技术,提出了一种新的商标库存储结构,并依据该存储结构设计了以三级检索算法为核心的实用商标登记注册管理系统,对于检索算法,一级检索采用人工确认,二级检索采用傅立叶描述子作为边缘特征向量,三级检索采用hu不变矩组作为矩特征向量,从而达到提高商标申请注册中的检索速度和查准率。 相似文献
106.
Olga Ordeig Craig E Banks Trevor J Davies F Javier del Campo Francesc Xavier Mu?oz Richard G Compton 《Analytical sciences》2006,22(5):679-683
Gold ultra-microelectrode arrays are used to explore the electrochemical oxidation of hydroxide ions and are shown to be analytical useful. Two types of ultra-microelectrode arrays are used; the first consist of 256 individual electrodes of 5 microm in radius, 170 of which are electrochemically active in a cubic arrangement which are separated from their nearest neighbour by a distance of 100 microm. The second array compromises 2597 electrodes of 2.5 microm in radius and of which 1550 of which are electrochemically active in a hexagonal arrangement separated by the nearest neighbour by 55 microm. Well defined voltammetric waves are found with peak currents proportional to the concentration of hydroxide ions in the range 50 microM to 1 mM. Detection limits of 20 microM using the 170 ultra-microelectrode and 10 microM with the 1550 ultra-microelectrode array are shown to be possible but with a higher sensitivity of 4 mA M(-1) observed using the 1550 ultra-microelectrode array compared to 1.2 mA M(-1) with the 170 ultra-microelectrode array. 相似文献
107.
Ivan Gutman Sabina Gojak Niko Radulovi? Boris Furtula 《Monatshefte für Chemie / Chemical Monthly》2006,46(2):277-284
In a recent work it was demonstrated that in linear hexagonal chains the distribution of π-electrons into rings (as computed
by means of the Randić–Balaban method) is uniform, irrespective of the nature of the terminal fragments. We now establish that an analogous, yet somewhat
more complex, uniformity in the π-electron distribution exists also in double linear hexagonal chains, as well as in some
other benzenoid systems. 相似文献
108.
Thin films of silicon oxynitride have largely replaced pure silicon oxide films as gate and tunnel oxide films in modern technology due to their superior properties in terms of efficiency as boron barrier, resistance to electrical stress and high dielectric strength. A single chamber system for plasma enhanced chemical vapor deposition was employed to deposit different films of SiOxNyHz with 0.85 < x < 1.91. All films were previously characterized by Rutherford back-scattering and infrared spectroscopy to determine the stoichiometry and the presence of various bonding configurations of constituent atoms. We used X-ray reflectivity to determine the electron density profile across the depth, and we showed that the top layer is densified. Moreover, grazing incidence small-angle X-ray scattering was used to study inhomogeneities (clustering) in the films, and it is shown that plate-like inhomogeneities exist in the top and sphere-like particles at the bottom part of the film. Their shape and size depend on the stoichiometry of the films. 相似文献
109.
Zhi-Hui Su Munehiro Okamoto Osamu Tominaga Katsumi Akita Noboru Kashiwai Y?ki Imura Tooru Ojika Yoshiyuki Nagahata Syozo Osawa 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2006,82(7):232-250
An approach to deduce the mechanism of stabilization of the hybrid-derived populations in the Ohomopterus ground beetles has been made by comparative studies on the phylogenetic trees of the mitochondrial and nuclear DNA. A phylogenetic tree based on the internal transcribed spacer (ITS) of nuclear ribosomal gene roughly reflects the relations of morphological species group, while mitochondrial NADH dehydrogenase subunit 5 (ND5) gene shows a considerable different topology on the tree; there exist several geographically-linked lineages, most of which consist of more than one species. These results suggest that the replacement of mitochondria has occurred widely in the Ohomopterus species. In most cases, hybridization is unidirectional, i.e., the species A (♂) hybridized with another species B (♀) and not vice versa, with accompanied replacement of mitochondria of A by those of B. The results also suggest that partial or complete occupation of the distribution territory by a hybrid-derived morphological species. The morphological appearance of the resultant hybrid-derivatives are recognized as that of the original species A. Emergence of a morphological new species from a hybrid-derived population has been exemplified. 相似文献
110.
Xiao-jing Cai Quan-sen Jiu Chun-yan Xue 《应用数学学报(英文版)》2007,23(4):637-650
In this paper,the Dirichlet problem of Stokes approximate of non-homogeneous incompressibleNavier-Stokes equations is studied.It is shown that there exist global weak solutions as well as global andunique strong solution for this problem,under the assumption that initial density ρ_0(x)is bounded away from0 and other appropriate assumptions(see Theorem 1 and Theorem 2).The semi-Galerkin method is applied toconstruct the approximate solutions and a prior estimates are made to elaborate upon the compactness of theapproximate solutions. 相似文献