新型脱硅剂水合碳铁酸钙合成过程的光谱学研究

亚熔盐溶出一水硬铝石型铝土矿过程中需在高浓介质条件下脱除二氧化硅杂质,研究采用合成水合碳铁酸钙做为脱硅剂;因水合碳铁酸钙合成过程中会有碳酸钙、氢氧化钙、铁酸钙等副产物,故合成条件对水合碳铁酸钙含量及脱硅效果有重要影响。为了探讨反应机理并优化合成参数, 研究采用傅里叶变换红外光谱(FTIR)、电感耦合等离子发射光谱(ICP-AES)分析对合成过程产物进行了物相分析和脱硅实验。FTIR和脱硅过程元素分析表明水合碳铁酸钙在水溶液中为介稳物质,反应温度和反应时间对水合碳铁酸钙的合成具有重要影响,随时间和温度增加水合碳铁酸钙含量先增加后减少;单因素条件下最优的合成条件为, 反应温度30 ℃,反应时间16 h,反应液固比20,搅拌强度500 r·min-1;对最优条件下合成水合碳铁酸钙的物相结构进行了研究,表明水合碳铁酸钙为斜方六面体晶体结构,其中存在结晶水、羟基、Fe—O特征峰。     

相对论性力学系统的Birkhoff对称性与守恒量

提出了相对论性力学系统的一种新的对称性,并给出了此对称性导致的守恒量.提出了相对论性力学系统的Birkhoff对称性,即对应于相对论性力学系统的一组Birkhoff动力学函数的运动微分方程的解都满足从另一组Birkhoff动力学函数得到的运动微分方程.证明了与两组Birkhoff动力学函数分别给出的相对论性Birkhoff方程相关联的系数矩阵的各次幂的迹是系统的一个守恒量,从而将Currie和Saletan提出的力学系统的等效Lagrange函数定理拓展到了相对论性Birkhoff动力学系统.给出了两个例子以说明结果的正确性.     

Zig-Zag板条泵浦的2.12μm激光器

 为了实现窄脉宽、高峰值功率2.12 μm激光的稳定输出,设计了基于侧面泵浦Zig-Zag 板条产生1.06 μm基频光,进而泵浦KTP晶体通过II类相位匹配产生2.12 μm激光的光参量振荡实验。对外腔及内腔进行了实验研究,分别获得了1.53%和2.86%的电光转换效率。在20 Hz频率下内腔2.12 μm输出能量达到70 mJ以上,脉宽7 ns~9 ns。其中内腔实验中能量输出稳定度接近8%。     

基于低阶矩阵最大特征值的复杂网络牵制混沌同步

虽已对复杂网络牵制同步需要牵制结点数量及牵制结点数量与耦合强度的关系进行了研究,然而快速计算牵制结点数量仍是大规模复杂网络面临的一个重要问题.研究发现了复杂网络耦合矩阵主子阵最大值递减规律,由此提出了快速计算复杂网络牵制结点数量的方法,揭示了不同的牵制策略与牵制结点数量之间的关系.数值仿真显示了在无标度网络和小世界网络上三种不同的牵制策略下,牵制结点数与主子阵最大特征值的变化规律;最后给出了一个在无标度网络上采用随机选择结点策略的牵制同步实例.     

大气湍流光学参数分析

利用两种不同大气湍流结构常数模型,讨论了不同高度的湍流对大气湍流光学参数的影响。通过理论计算得出:相干长度和对数振幅起伏方差主要由低层大气湍流决定,而等晕角、倾斜等晕角、格林伍德频率和泰勒频率由对流层顶附近的高层湍流决定。分析了垂直高度30 km以下的3部分大气湍流对等晕角的贡献比例,在给定的不同强度湍流下,对流层顶附近的高层大气湍流贡献比例都大于25％,而低层大气湍流的贡献比例都小于3%。     

应用于ICF实验的软X射线平面镜反射率

在北京同步辐射装置上,通过对应用于惯性约束聚变（ICF）实验的平面镜反射率的进一步研究,提高了辐射温度的测量精度。进行了对软X射线平面镜反射率的测量、反射镜的清洗、反射率的模拟计算,证明影响反射率变化的主要因素是平面镜的安装角度和沾污。实验结果表明:平面镜的沾污主要来源于ICF实验中的油沾污,采用射频辉光放电清洗非常有效。     

Electric field control of nonvolatile four-state magnetization at room temperature

We find the realization of large converse magnetoelectric (ME) effects at room temperature in a magnetoelectric hexaferrite Ba0.52Sr2.48Co2Fe24O41 single crystal, in which rapid change of electric polarization in low magnetic fields (about 5 mT) is coined to a large ME susceptibility of 3200 ps/m. The modulation of magnetization then reaches up to 0.62μ(B)/f.u. in an electric field of 1.14 MV/m. We find further that four ME states induced by different ME poling exhibit unique, nonvolatile magnetization versus electric field curves, which can be approximately described by an effective free energy with a distinct set of ME coefficients.     

Tunable self-shifting Bloch modes in anisotropic hexagonal photonic lattices

We study controllable self-shifting Bloch modes in anisotropic hexagonal photonic lattices. The shifting results from a deformed band structure due to deformation of the index distribution in each unit cell. By reconfiguration of the index profile of the unit cell, the direction in which the Bloch modes move can be controlled. Our theoretical predictions are experimentally demonstrated in hexagonal lattices optically induced in an anisotropic nonlinear crystal.     

火花通道长度对激光触发开关特性的影响

利用超高速相机,在曝光时间100 ns时,对不同能量下激光在氮气气体开关中形成的火花通道进行拍照,得到了不同焦距下激光波长266 nm时激光火花通道长度与激光能量的关系。开展了激光触发气体火花开关的实验研究,激光触发开关延时、抖动随激光能量的增加而减小。将火花通道长度与激光触发开关的特性进行了分析,气体开关的抖动随着激光火花通道长度的增加而减小,当火花通道沿电极间轴向长度达到开关电极间距40%时,开关的抖动为亚ns量级。     

A facile strategy to synthesize bimetallic Au/Ag nanocomposite film by layer-by-layer assembly technique

A facile strategy has been developed for the preparation of bimetallic gold–silver (Au–Ag) nanocomposite films by alternating absorption of poly-(ethyleneimine)–silver ions and Au onto substrates and subsequent reduction of the silver ions. The composition, micro-structure and properties of the {PEI–Ag/Au}_n nanocomposite films were characterized by ultraviolet visible spectroscopy (UV–vis), transmisson electron microscopy (TEM), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), surface enhanced Raman scattering (SERS) and cyclic voltammetry (CV). The UV–vis characteristic absorbances of {PEI–Ag/Au}_n nanocomposite thin film increase almost linear with the number of bilayers, which indicates a process of uniform assembling. Appearance of a double plasmon bands in the visible region and the lack of apparent core–shell structures in the TEM images confirm the formation of bimetallic Au–Ag nanoparticles. The result of XPS also demonstrates the existence of Ag and Au nanoparticles in the nanocomposite films. TEM and FESEM images show that these Ag and Au nanoparticles in the films possess sphere structure with the size of 20–25 nm. The resulting {PEI–Ag/Au}_n films inherit the properties from both the metal Ag and Au, which exhibits a unique performance in SERS and electrocatalytic activities to the oxidation of dopamine. As a result, the {PEI–Ag/Au}_n films are more attractive compared to {PEI–Ag/PSS}_n and {PEI/Au}_n films.