全文获取类型
收费全文 | 20558篇 |
免费 | 3525篇 |
国内免费 | 2478篇 |
专业分类
化学 | 14537篇 |
晶体学 | 185篇 |
力学 | 1180篇 |
综合类 | 139篇 |
数学 | 2835篇 |
物理学 | 7685篇 |
出版年
2024年 | 92篇 |
2023年 | 453篇 |
2022年 | 680篇 |
2021年 | 723篇 |
2020年 | 900篇 |
2019年 | 828篇 |
2018年 | 736篇 |
2017年 | 690篇 |
2016年 | 1049篇 |
2015年 | 1027篇 |
2014年 | 1156篇 |
2013年 | 1559篇 |
2012年 | 1778篇 |
2011年 | 1859篇 |
2010年 | 1298篇 |
2009年 | 1163篇 |
2008年 | 1322篇 |
2007年 | 1163篇 |
2006年 | 1029篇 |
2005年 | 921篇 |
2004年 | 728篇 |
2003年 | 636篇 |
2002年 | 704篇 |
2001年 | 553篇 |
2000年 | 456篇 |
1999年 | 441篇 |
1998年 | 356篇 |
1997年 | 326篇 |
1996年 | 343篇 |
1995年 | 300篇 |
1994年 | 238篇 |
1993年 | 171篇 |
1992年 | 168篇 |
1991年 | 164篇 |
1990年 | 124篇 |
1989年 | 96篇 |
1988年 | 55篇 |
1987年 | 56篇 |
1986年 | 71篇 |
1985年 | 47篇 |
1984年 | 34篇 |
1983年 | 27篇 |
1982年 | 16篇 |
1981年 | 11篇 |
1980年 | 4篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
781.
782.
783.
This paper investigates the nonlinear control problem for flexible air-breathing hypersonic vehicles (FAHVs). The coupling dynamics between flexible and rigid-body parts of FAHVs may cause degradation of control performance or high-frequency oscillations of control input and flexible state. In this paper, the flexible effects produced by the coupling are modeled as a kind of unknown disturbance and included in the new control-design model, for which a coupling observer is constructed to estimate these effects. Thus, a novel nonlinear composite control strategy, which combines a coupling-observer-based feedforward compensator and a dynamic-inversion-based feedback controller, is proposed to reject the flexible effects on pitch rate and track desired trajectories of velocity and flight-path angle. The stability of composite closed-loop system is analyzed by using the Lyapunov theory. Simulation results on a full nonlinear model of FAHVs demonstrate that the presented controller is more effective by comparison with the previous scheme. 相似文献
784.
In this paper, we introduce a novel salient region detection algorithm by using background priors. Because of the fact that superpixel is perceptually more meaningful than pixel, and which can reduce the complexity of image processing, we use the superpixel algorithm to reprocess original images. In addition, we hold the point that the colors in the image boundary could mainly represent all background colors, hence we compute the color contrast between the intern colors and the boundary colors. Since the nearer the patches are close to center, the more they affect other patches, we propose a new distribution-based model. Finally, experimental results demonstrate that the proposed method outperforms the state-of-the-art approaches. 相似文献
785.
Applied Mathematics and Mechanics - The recently developed hard-magnetic soft (HMS) materials can play a significant role in the actuation and control of medical devices, soft robots, flexible... 相似文献
786.
Yi Liu Jiaqi Wang Shiguo Han Dr. Xitao Liu Maofan Li Zhiyun Xu Wuqian Guo Prof. Maochun Hong Prof. Junhua Luo Prof. Zhihua Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(16):3494-3498
3D perovskite CsPbBr3 has recently taken a blooming position for optoelectronic applications. However, due to the lack of natural anisotropy of optical attributes, it is a great challenge to fulfil polarization-sensitive photodetection. Here, for the first time, we exploited dimensionality reduction of CsPbBr3 to tailor a 2D-multilayered hybrid perovskite, (TRA)2CsPb2Br7 ( 1 , in which TRA is (carboxy)cyclohexylmethylammonium), serving as a potential polarized-light detecting candidate. Its unique quantum-confined 2D structure results in intrinsic anisotropy of electrical conductivity, optical absorbance, and polarization-dependent responses. Particularly, it exhibits remarkable dichroism with the photocurrent ratio (Ipc/Ipa) of ≈2.1, being much higher than that of the isotropic CsPbBr3 crystal and reported CH3NH3PbI3 nanowire (≈1.3), which reveals its great potentials for polarization-sensitive photodetection. Further, crystal-based detectors of 1 show fascinating responses to the polarized light, including high detectivity (>1010 Jones), fast responding time (≈300 μs), and sizeable on/off current ratios (>104). To our best knowledge, this is the first study on 2D Cs-based hybrid perovskite exhibiting strong polarization-sensitivity. The work highlights an effective pathway to explore new polarization sensitive candidates for hybrid perovskites and promotes their future electronic applications. 相似文献
787.
Dr. Yongqi Yao Dr. Qifu Lin Dr. Wen Yang Prof. Dr. Weitao Yang Prof. Dr. Fenglong Gu Prof. Dr. Wei Guo Prof. Dr. Dingqiao Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(25):5607-5610
A cobalt(II)-catalyzed [4+2] annulation of picolinamides with alkynes via C−H bond activation has been developed. The operationally simple annulation reaction allows for the synthesis of acyl-substituted 1H-benzoquinoline bearing multiple aromatic rings (up to 96 % yield) without co-oxidant or other oxidation factors under mild conditions. Several control experiments were carried out. This practical [4+2] annulation provides an efficient route to access highly functionalized compounds. 相似文献
788.
Yujia Xu Weijing Zhang Tonglai Zhang Wei Guo Yongjun Lü 《Journal of computational chemistry》2020,41(10):1026-1033
Metal azides have attracted increasing attention as precursors for synthesizing polymeric nitrogen. In this article, we report the amorphous polymerization of nitrogen by compressing cupric azide. The ab initio molecular dynamics simulations show that crystalline cupric azide transforms into a disordered network composed of singly bonded nitrogen at a hydrostatic pressure of 40 GPa and room temperature. The transformation manifests the formation of a π delocalization along the disordered Cu-N network, thus resulting in a semiconductor–metal transition. The estimated heat of formation of the amorphous polymeric nitrogen system is comparable to conventional high-energy-density materials. The amorphization provides an alternative route to the polymerization of nitrogen under moderate conditions. 相似文献
789.
Marie-Claire Giel Dr. Christopher J. Smedley Emily R. R. Mackie Taijie Guo Prof. Dr. Jiajia Dong Dr. Tatiana P. Soares da Costa Prof. Dr. John E. Moses 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(3):1197-1202
The boom in growth of 1,4-disubstituted triazole products, in particular, since the early 2000’s, can be largely attributed to the birth of click chemistry and the discovery of the CuI-catalyzed azide–alkyne cycloaddition (CuAAC). Yet the synthesis of relatively simple, albeit important, 1-substituted-1,2,3-triazoles has been surprisingly more challenging. Reported here is a straightforward and scalable click-inspired protocol for the synthesis of 1-substituted-1,2,3-triazoles from organic azides and the bench stable acetylene surrogate ethenesulfonyl fluoride (ESF). The new transformation tolerates a wide selection of substrates and proceeds smoothly under metal-free conditions to give the products in excellent yield. Under controlled acidic conditions, the 1-substituted-1,2,3-triazole products undergo a Michael addition reaction with a second equivalent of ESF to give the unprecedented 1-substituted triazolium sulfonyl fluoride salts. 相似文献
790.
Mechanics of Composite Materials - In this study, the geometry of open-cell foams is simulated using a model based on Voronoi tessellations. The fracture toughness of open-cell foams with Voronoi... 相似文献